Synthesis and Characterization of Copper(II) Complexes with Long Chain Dithiocarbamates

Nayely Torres-Gomez; Alfredo R. Vilchis-Nestor; Rosa Maria Gomez-Espinosa; Ivan Garcia-Orozco

doi:10.4028/www.scientific.net/AMR.976.164

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Study of Cantilever Structures Based on Piezoelectric Materials for Energy Harvesting at Low Frequency of Vibration
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Synthesis and Characterization of Copper(II) Complexes with Long Chain Dithiocarbamates
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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 976Synthesis and Characterization of Copper(II)...

Synthesis and Characterization of Copper(II) Complexes with Long Chain Dithiocarbamates

Abstract:

Copper complexes of dithiocarbamates ligands were obtained from RNH₂ (R = C₆H₁₃-, C₁₂H₂₅- y C₁₈H₃₇-) and an excess of CS₂ in the presence of NaOH. Sodium hexyldithiocarbamate is not possible to isolate from solution but the other two were obtained and characterizedby infrared spectroscopy, UV-vis and powder X-ray diffraction. Copper complexes were obtained in situ from ligand solution as greenish powders. All the complexes were characterized by infrared spectroscopy, UV-vis, powder X-ray diffraction and Scanning Electron Microscopy. The complexes show an amorphous phase in the case of DCu12 and nanocrystalline structure for DCu18, as observed in XRD.

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Advanced Materials Research (Volume 976)

Pages:

164-168

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https://doi.org/10.4028/www.scientific.net/AMR.976.164

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Online since:

June 2014

Authors:

Nayely Torres-Gomez, Alfredo R. Vilchis-Nestor, Rosa Maria Gomez-Espinosa, Ivan Garcia-Orozco*

Keywords:

Copper Complexes, Dithiocarbamates

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