Micromechanical Model Prediction Overall Young Modulus Nanocomposites Polymer-Clay-Silica by Self Consistent Approach

Article Preview

Abstract:

In order to address the problem of stiffness and mechanical properties, a micromechanical approach for the prediction of the overall modulus of nanocomposites (Nylon-6/nanoclay/silica) using a self-consistent scheme based on the double-inclusion model and taking into account the different morphologies exfoliated or intercalated of the nanoparticles. Self-consistent approach that is used in our calculations was explained after reviewing the inclusion of Eshelby, in particular the double inclusion and while considering also the effect of constrained region, modeled as an interphase around reinforcements. Namely, polyamide 6 reinforced with clay platelets and silica particles. Several parameters on the Young's modulus of the composite were studied to see the effect of having mixed two or three reinforcements in polymer matrix. Finally, we demonstrated the process undertaken for the calculation of elastic constants of the material studied.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

152-156

Citation:

Online since:

June 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] A. Usuki, M. Kawasumi, Y. Kojima, A. Okada, T. Kurauchi, O. Kamigaito, Swelling behavior ot montmorillonite cation exchanged for u-amino acid bi e-caprolactam. J. Mater. Res. 8 (1993) 1174–1178.

DOI: 10.1557/jmr.1993.1174

Google Scholar

[2] Y. Kojima, A. Usuki, M. Kawasumi, A. Okada, Y. Fukushima, T. Kurauchi, O. Kamigaito, Mechanical properties of nylon-6-clay hybrid. J. Mater. Res. 6 (1993) 1185–1189.

DOI: 10.1557/jmr.1993.1185

Google Scholar

[3] M. Alexandre, P. Dubois, Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials. Mat. Sci. Eng. 28 (2000) 1–63.

DOI: 10.1016/s0927-796x(00)00012-7

Google Scholar

[4] T.D. Fornes, D.R. Paul, Modelling properties of nylon6/clay nanocomposites using composite theories. Polymer 44 (2003) 4993–5013.

DOI: 10.1016/s0032-3861(03)00471-3

Google Scholar

[5] A. Mesbah, F. Zaïri, S. Boutaleb, J. M. Gloaguen, M. Naït-Abdelaziz, Experimental characterization and modeling stiffness of polymer/clay nanocomposites within a hierarchical multiscale framework, J Appl Polym Sci. 114 (2009) 3274–3291.

DOI: 10.1002/app.30547

Google Scholar

[6] S. Boutaleb, F. Zaïri, A. Mesbah, M. Naït-Abdelaziz, J. M. Gloaguen, T. Boukharouba, Micromechanics-based modelling of stiffness and yield stress for silica/polymer nanocomposites, Int J Solids Struct. 46 (2009) 1716–1726.

DOI: 10.1016/j.ijsolstr.2008.12.011

Google Scholar

[7] K. Anoukou, F. Zaïri, M. Naït-Abdelaziz, A. Zaoui, T. Messager, J. M. Gloaguen, On the overall elastic moduli of polymer–clay nanocomposite materials using a self-consistent approach, Part I: Theory, Composites Science and Technology. 71 (2011).

DOI: 10.1016/j.compscitech.2010.11.018

Google Scholar