Influence of pH on the Sorption Capacity of Transcarpathian Bentonite from the Ilnytsky Deposit

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The object of this study was bentonite clay from the Ilnytskyi deposit in the Transcarpathian region. The clay was enriched in montmorillonite by sedimentation to remove the coarse-dispersed phase. Complex thermal, X-ray diffractometric, and energy-dispersive spectral analyses showed that the enriched bentonite consists mainly of Ca, Mg-montmorillonite. The sorption of methylene blue dye by the enriched bentonite was found to occur through an ion-exchange mechanism. Modeling of the experimental sorption isotherm data using the Langmuir equation revealed the influence of medium pH on the sorption characteristics of bentonite. The spent sorbent is recommended for application in sorption technologies for landfill reclamation and land restoration.

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April 2026

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[1] V. Kochubei, S. Yaholnyk, M. Malovanyy, N. Buchaichuk, Study of the influence of dispersion and conditions of thermal activation on the sorption properties of Transcarpathian clinoptilolite and prospects for its application in environmental technologies, Environ. Probl. 9 (4) (2024) 218–226.

DOI: 10.23939/ep2024.04.218

Google Scholar

[2] V.K. Gaur, P. Sharma, R. Sirohi, M.K. Awasthi, C.-G. Dussap, A. Pandey, Assessing the impact of industrial waste on environment and mitigation strategies: A comprehensive review, J. Hazard. Mater. 398 (2020) 123019.

DOI: 10.1016/j.jhazmat.2020.123019

Google Scholar

[3] V. Sabadash, O. Konovalov, A. Nowik-Zając. Study of the process of adsorption of petroleum products methods of multivariate cluster analysis. Environ. Probl 8 (3) (2023) 185–191.

DOI: 10.23939/ep2023.03.185

Google Scholar

[4] A. Tkaczyk, K. Mitrowska, A. Posyniak, Synthetic organic dyes as contaminants of aquatic environment and their implications for ecosystems: A review, Sci. Total Environ. 717 (2020) 137.

DOI: 10.1016/j.scitotenv.2020.137222

Google Scholar

[5] S. Samsami, M. Mohamadi, M.H. Sarrafzadeh, E.R. Rene, M. Firoozbahr, Recent advances in dye-containing wastewater treatment, Process Saf. Environ. Prot. 143 (2020) 138–163.

DOI: 10.1016/j.psep.2020.05.034

Google Scholar

[6] D.A. Bopape, B. Ntsendwana, F.D. Mabasa, Photocatalysis as a pre-discharge treatment to improve the effect of textile dyes on human health: A critical review, Heliyon. 10 (20) (2024) e39316.

DOI: 10.1016/j.heliyon.2024.e39316

Google Scholar

[7] M.B. Hoque, T.H. Oyshi, M.A. Hannan, P. Haque, M.M. Rahman, M.A. Shahid, S.Z. Sheikh, Unraveling ecological footprint of textile dyes: A growing environmental concern, Pollut. Study. 5 (2) (2024) 3014.

DOI: 10.54517/ps.v5i2.3014

Google Scholar

[8] S. Shakiba, M. Mohamadi, M.H. Sarrafzadeh, E.R. Rene, M. Firoozbahr, Recent advances in the treatment of dye-containing wastewater from textile industries: Overview and perspectives, Process Saf. Environ. Prot. 143 (2020) 138–163.

DOI: 10.1016/j.psep.2020.05.034

Google Scholar

[9] M.A. Mohammed, A. Shitu, A. Ibrahim, Removal of methylene blue using low cost adsorbent: A review, Res. J. Chem. Sci. 4 (1) (2014) 91–102.

Google Scholar

[10] J. Gumnitsky, V. Sabadash, O. Matsuska, O. Lyuta, A. Hyvlud, L. Venger, Dynamics of adsorption of copper ions in fixed-bed column and mathematical interpretation of the first stage of the process, Chem. Chem. Technol. 16 (2) (2022) 267–273.

DOI: 10.23939/chcht16.02.267

Google Scholar

[11] A. Azari, R. Nabizadeh, S. Nasseri, A.H. Mahvi, A.R. Mesdaghinia, Comprehensive systematic review and meta-analysis of dyes adsorption by carbon-based adsorbent materials: Classification and analysis of last decade studies, Chemosphere 250 (2020) 126238.

DOI: 10.1016/j.chemosphere.2020.126238

Google Scholar

[12] S. Pyshyev, D. Miroshnichenko, I. Malik, A.B. Contreras, N. Hassan, A.A. El Rasoul, State of the art in the production of charcoal: A review, Chem. Chem. Technol. 15 (1) (2021) 61–73.

Google Scholar

[13] O. Popovych, M. Havryshko, H. Yaremko, Ye. Makovskiy Study of the anaerobic process of industrial water purification in combination with sorption methods. Environ. Probl, 8 (2) (2023) 117–125.

DOI: 10.23939/ep2023.02.117

Google Scholar

[14] V. Sabadash, A. Nowik-Zając, J. Gumnitsky, Adsorption of Pb²⁺ and Zn²⁺ ions from aqueous solutions with natural zeolite, Environ. Probl. 10(2) (2025) 191–196.

DOI: 10.23939/ep2025.02.191

Google Scholar

[15] V. Kochubei, S. Yaholnyk, S. Kniaz, L. Parashchuk, M. Malovanyy, Research into the influence of activation conditions of Transcarpathian clinoptilolite on its adsorption capacity, Voprosy Khim. Khim. Tekhnol. 4 (2020) 80–87.

DOI: 10.32434/0321-4095-2020-131-4-80-87

Google Scholar

[16] V. Kochubei, Ya. Yaremchuk, S. Yaholnyk, H. Krusir, Sorption Capacity of Activated Clinoptilolite, Key Eng. Mat, 1027, (2025) 75–84

DOI: 10.4028/p-wsck4j

Google Scholar

[17] V. Kochubei, S. Yaholnyk, M. Bets, M. Malovanyy, Use of activated clinoptilolite for direct dye-contained wastewater treatment, Chem. Chem. Technol. 14 (3) (2020) 386–393.

DOI: 10.23939/chcht14.03.386

Google Scholar

[18] V. Ptashnyk, I. Bordun, M. Malovanyy, P. Chabecki, T. Pieshkov, The change of structural parameters of nanoporous activated carbons under the influence of ultrasonic radiation, Appl. Nanosci. 10 (12) (2020) 4891–4899.

DOI: 10.1007/s13204-020-01393-z

Google Scholar

[19] Ch. Soloviy, M. Malovanyy, I. Bordun, F. Ivashchyshyn, A. Borysiuk, Y. Kulyk, Structural, magnetic and adsorption characteristics of magnetically susceptible carbon sorbents based on natural raw materials, J. Water Land Dev. 47 (2020) 160–168.

DOI: 10.24425/jwld.2020.135043

Google Scholar

[20] V. Kochubei, Ya. Yaremchuk, S. Yaholnyk, M., Malovany, Study of influence ultrasonic waves on the sorption capacity of enriched bentonite of cherkasy deposit in relation to copper ions, Chem. Chem. Technol. 19(3), (2025) 425–433

DOI: 10.23939/chcht19.03.425

Google Scholar

[21] V. Kochubei, Ya. Yaremchuk, S. Yaholnyk, M.-O. Danyliak, Sorption capacity of ultrasound-activated natural bentonite regarding copper ions, Fiz.-Khim. Mekh. Mater. 60 (1) (2024) 119–127.

DOI: 10.1007/s11003-024-00858-8

Google Scholar

[22] M.F. Brigatti, E. Galan, B.K.G. Theng, Structures and mineralogy of clay minerals, in: F. Bergaya, B.K.G. Theng, G. Lagaly (Eds.), Handbook of Clay Science, Elsevier, Amsterdam, 2013, p.21–81.

DOI: 10.1016/b978-0-08-098258-8.00002-x

Google Scholar

[23] O. Andreeva, M. Kurylo, The use of modern classifications and resources in the assessment of domestic deposits of bentonite clays, Bull. Kyiv Natl. Univ. Geol. 60 (2013) 56–58.

Google Scholar

[24] G. Lagaly, M. Ogawa, I. Dekany, Clay mineral organic interactions, in: F. Bergaya, B.K.G. Theng, G. Lagaly (Eds.), Handbook of Clay Science, Elsevier, Amsterdam, 2013, p.435–505.

DOI: 10.1016/b978-0-08-098258-8.00015-8

Google Scholar

[25] M. Okumura, S. Kerisit, I.C. Bourg, L.N. Lammers, T. Ikeda, M. Sassi, K.M. Rosso, M. Machida, Radiocesium interaction with clay minerals: Theory and simulation advances post-Fukushima, J. Environ. Radioact. 189 (2018) 135–145.

DOI: 10.1016/j.jenvrad.2018.03.011

Google Scholar

[26] A.I. Vezentsev, D.M. Thuy, L.F. Goldovskaya-Peristaya, N.A. Glukhareva, Adsorption of methylene blue on the composite sorbent based on bentonite-like clay and hydroxyapatite, Indones. J. Chem. 18 (4) (2018) 733–741.

DOI: 10.22146/ijc.37050

Google Scholar

[27] C. Chen, H. Liu, T. Chen, D. Chen, R.L. Frost, An insight into the removal of Pb(II), Cu(II), Co(II), Cd(II), Zn(II), Ag(I), Hg(I), Cr(VI) by Na(I)-montmorillonite and Ca(II)-montmorillonite, Appl. Clay Sci. 118 (2015) 239–247.

DOI: 10.1016/j.clay.2015.09.004

Google Scholar

[28] Z. Taibi, K. Bentaleb, Z. Bouberka, C. Pierlot, M. Vandewalle, C. Volkringer, P. Supiot, U. Maschke, Adsorption of Orange G dye on hydrophobic activated bentonite from aqueous solution, Crystals. 13 (2023) 211.

DOI: 10.3390/cryst13020211

Google Scholar

[29] S.F.A. Shattar, K.Y. Foo, Sodium salt assisted low temperature activation of bentonite for the adsorptive removal of methylene blue, Sci. Rep. 12 (2022) 2534.

DOI: 10.1038/s41598-022-06254-z

Google Scholar

[30] V. Kochubei, Ya. Yaremchuk, M. Malovanyy, S. Yaholnyk, A. Slyuzar, Perspectives of treatment of water environments from pollutants with ultrasound-activated bentonites, Chem. Chem. Technol. 17 (4) (2023) 870–877.

DOI: 10.23939/chcht17.04.870

Google Scholar

[31] C.-H. Weng, Y.-F. Pan, Adsorption of a cationic dye (methylene blue) onto spent activated clay, J. Hazard. Mater. 144 (2007) 355–362.

DOI: 10.1016/j.jhazmat.2006.09.097

Google Scholar

[32] S.S. Tahir, R. Naseem, Removal of a cationic dye from aqueous solutions by adsorption onto bentonite clay, Chemosphere. 63 (2006) 1842–1848.

DOI: 10.1016/j.chemosphere.2005.10.033

Google Scholar

[33] A.A. Adeyemo, I.O. Adeoye, O.S. Bello, Adsorption of dyes using different types of clay: A review, Appl. Water Sci. 7 (2017) 543–568.

DOI: 10.1007/s13201-015-0322-y

Google Scholar

[34] C.A.P. Almeida, N.A. Debacher, A.J. Downsc, L. Cotteta, C.A.D. Mello, Removal of methylene blue from colored effluents by adsorption on montmorillonite clay, J. Colloid Interface Sci. 332 (2009) 46–53.

DOI: 10.1016/j.jcis.2008.12.012

Google Scholar

[35] V.O. Khmelevskyi, O.V. Khmelevska, Litolohiia. Litohenez. Osadovi porody, LNU im. Iv. Franka, Lviv, 2015.

Google Scholar

[36] D.M. Moore, R.C. Reynolds, X-Ray diffraction and the identification and analysis of clay minerals, Oxford Univ. Press, Oxford, 1997.

Google Scholar

[37] Yu.I. Tarasevich, F.D. Ovcharenko, Adsorbtsiya na glinistykh mineralakh, Naukova Dumka, Kiev, 1975.

Google Scholar

[38] O. Matkovskyi, V. Kvasnytsia, I. Naumko, P. Bilonizhka, O. Hrechanovska, Mineraly Ukrainskykh Karpat. Sylikaty, Vydavnychyi tsentr LNU imeni Ivana Franka, Lviv, 2011.

Google Scholar

[39] F. Rouquerol, J. Rouquerol, P. Llewellyn, Thermal analysis, in: F. Bergaya, B.K.G. Theng, G. Lagaly (Eds.), Handbook of Clay Science, Elsevier, Amsterdam, 2013, p.361–379.

DOI: 10.1016/b978-0-08-098259-5.00014-7

Google Scholar

[40] V. Kochubei, Ya. Yaremchuk, M. Malovanyy, S. Yaholnyk, W. Lutek, Studies of adsorption capacity of montmorillonite-enriched clay from the Khmelnytskyi region, Key Eng. Mater. 925 (2022) 143–149.

DOI: 10.4028/p-i713sy

Google Scholar

[41] R. Guegan, Organoclay applications and limits in the environment, C. R. Chim. 22 (2019) 132–141.

Google Scholar

[42] R. Elmoubarki, F.Z. Mahjoubi, H. Tounsadi, J. Moustadraf, M. Abdennouri, A. Zouhri, A. ElAlbani, N. Barka, Adsorption of textile dyes on raw and decanted Moroccan clays: Kinetics, equilibrium and thermodynamics, Water Resour. Ind. 5 (2015) 16–29.

DOI: 10.1016/j.wri.2014.11.001

Google Scholar

[43] M.E. Essington, Soil and Water Chemistry, CRC Press, Boca Raton, 2004.

Google Scholar

[44] L. Perelomov, M. Gertsen, M. Burachevskaya, S. Hemalatha, A. Vijayalakshmi, I. Perelomova, Y. Atroshchenko, Organoclays based on bentonite and various types of surfactants as heavy metal remediants, Sustainability. 16 (2024) 4804.

DOI: 10.3390/su16114804

Google Scholar

[45] G. Kickelbick, Hybrid Materials: Synthesis, Characterization, and Applications, Wiley-VCH, Weinheim, 2007.

Google Scholar

[46] O.I. Olkhovyk, A.A. Biletskyi, Tekhnolohiia budivnytstva hidrotekhnichnykh vodohospodarskykh ta pryrodookhoronnykh sporud, NUVHP, Rivne, 2019.

Google Scholar