Visualization of the Vacancy-Wind Effect Occurring in Chemical Diffusion and Ionic Conductivity in Solids

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Abstract:

Net fluxes of vacancies commonly occur during chemical interdiffusion in alloys, ionic conductivity and the annealing out of radiation damage. When atoms with different jump rates diffuse in a net flux of vacancies the phenomenon of the vacancy-wind effect will occur. This effect, first discovered by the late Dr John Manning, is a subtle phenomenon arising from a disturbed distribution of vacancies with respect to a given moving atom or species of atom. In this paper, the vacancy-wind effect is discussed and its visualization, performed for the first time by computer simulation, is demonstrated.

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Periodical:

Defect and Diffusion Forum (Volumes 273-276)

Pages:

431-444

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Online since:

February 2008

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© 2008 Trans Tech Publications Ltd. All Rights Reserved

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