Study on Soldering Alloy Structure Influence on Whiskers Germination and Grow Process in Joints Executed Using Tin Base Soldering Alloys

Article Preview

Abstract:

Electronic components soldered with tin base alloys are subject to whiskers formations after an operation period, which produced failures by short circuits. The main factors which determine formation of whiskers are soldering alloy characteristics, substrate alloys which is placed on the surface of the PCB boards and not the least the working environment. Soldering alloy has a major influence on germination and growing whiskers process, by its nature and grain form, dimensions and orientation. Given the preliminary research carried out to diminish the formation of these defects, was proposed to realize these soldered joints using new soldering alloys obtained by melt-spinning method, which have a nanocrystalline, quasi-crystalline or even amorphous structure. In this paper are presented some results obtained on following the influence of soldering alloy structure over whiskers germination and growing process, by simulating the operation conditions according to applicable standards. Were obtained soldered joints on copper plates using a commercial soldering alloy as well as soldering alloys base on Sn-Cu-Ga, Sn-Cu-Ni, Sn-Cu-CO families, obtained by melt-spinning method. Soldering was performed using a soldering iron and after this process, the soldered joints were placed in an incubator under controlled temperature and humidity conditions. Performing SEM analyzes on soldered joints subject to the above treatment, was observed that formation and growing of whiskers diminished with decrease of the grain size.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

123-130

Citation:

Online since:

May 2022

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2022 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] C-M Huang, A. Raj, M. Osterman, M. Pecht, Assembly Options and Challenges for Electronic Products with Lead-Free Exemption, DOI 10.1109/ACCESS.2020.3010771, IEEE Access vol XX, (2017).

DOI: 10.1109/access.2020.3010771

Google Scholar

[2] Osterman M [and others] Evaluation of faradayic plating method for controlling tin whisker growth,, Maryland, University of Maryland, CALCE EPSC, (2007).

Google Scholar

[3] Osterman M. Assessing the risk posed by tin whiskers, Retrieved November 27, http://www.calce.umd.edu/lead-free/STMAKeyNote.pdf. 27 11 2006- 15 2 (2010).

Google Scholar

[4] Jadhav, N., Buchovecky, E., Chason, E., Bower, A., Real-time SEM/FIB Studies of Whisker Growth and Surface Modification. 2010, Vol. 62, No. 7, pp.30-37, glasses by in-situ tensile tests, Materials Science and Engineering A, 2009, 516, p.148–153, ISSN 0921-5093.

DOI: 10.1007/s11837-010-0105-8

Google Scholar

[5] P. Xue, W. L. Liang, P. He, K. Suganuma, H. Zhang, Tin Whisker Growth Inhibition in RE-Doped Sn-Zn Soldered Joints, Applied Science-Basel, Volume9, Issue7, 2019, Article Number1406.

DOI: 10.3390/app9071406

Google Scholar

[6] Ashworth A. Mark [and others] An investigation into zinc diffusion and tin whisker growth for electroplated tin deposits on brass, Journal of ELECTRONIC MATERIALS, Loughborough, Leicestershire LE11 3TU, UK, 2014,-.

DOI: 10.1007/s11664-014-2983-y

Google Scholar

[7] B. Illes, A. Skwarek, J. Ratajczak, K. Dusek, D. Busek, The influence of the crystallographic structure of the intermetallic grains on tin whisker growth, J. Alloys Compd., vol. 785, pp.774-780, (2019).

DOI: 10.1016/j.jallcom.2019.01.247

Google Scholar

[8] Bunyan D [and others]] Tin whisker growth from electroplated finishes - a review,, Transactions of the Institute of Metal Finishing, 2013, 91(5), pp.249-259,.

DOI: 10.1179/0020296713z.000000000119

Google Scholar

[9] Crandall Erika R. Factors governing tin whisker growth,- Auburn: A dissertation submitted to the Graduate Faculty of Auburn University Doctor of Philosophy, (2012).

Google Scholar

[10] H. Johan, S. A. Hall, N. A. Henningsson, J. Engvist, M. Ristinmaa, F. Lenrick, J. P. Wright, Scanning 3DXRD Measurement of Grain Growth, Stress and Formation of Cu6Sn5 around a Tin Whiskers during Heat Treatment, Materials, vol. 12, nr. 446, 2019.

DOI: 10.3390/ma12030446

Google Scholar

[11] Codrean C., Buzdugan D., Serban, V.A., Voda M., Determination of internal stress in soldered joints with Sn-based alloys by X-ray diffraction, Materials Today-Proceedings, Volume45, Special IssueSI, Part5, Page4364-4366, (2021).

DOI: 10.1016/j.matpr.2021.02.761

Google Scholar

[12] Şerban, V.A., Codrean, C., Uţu, D., Opriş, C. Amorphous alloys for brazing copper based alloys. The 13th International Conference on Rapidly Quenched and Metastable Materials, Conference Series 2009, 144., 12098, pp.1-4. Journal of Physics, 2009, ISSN 1742-6596.

DOI: 10.1088/1742-6596/144/1/012098

Google Scholar

[13] Panashchenko Lyudmyla Evaluation of environmental tests for tin whisker assessment,, Maryland, Masters of Science, (2009).

Google Scholar

[14] K. Lin, J. Wang, C. L. Yang, M. L. Sun, A. M. Hu, Y. W. Wu, H. Q. Ling, M. Li, Growth behavior of tin whisker and hillock on Cu/Ni/Sn/Ag micro-bumps under high temperature and humidity storage, Materials Letters-X, Volume9, 2021, Article Number100060.

DOI: 10.1016/j.mlblux.2021.100060

Google Scholar

[15] J. Hektor, Tin whiskers: experiments and modelling, Doctoral thesis, Lunds Universitet, 2018, ISBN: 978-91-7753-917-9.

Google Scholar

[16] Chiu Tsung-Chieh and Lin Kwang-Lung Tin whiskers induced within the unreacted solder are believed to be due to the mechanical stress induced by this IMC rotation, Microstructural electromigration through a Cu/Sn3.5Ag/Au solder joint Scripta Materialia, Elsevier Ltd. 2009, 60, pg. 1121–1124.

DOI: 10.1016/j.scriptamat.2009.02.061

Google Scholar

[17] Kim K S [and others] Investigation of relation between intermetallic and tin whisker growths under ambient condition,, Microelectronics Reliability,Ed. Ltd. 2007 Elsevier, Science Direct, 2008, 48, p.111–118.

DOI: 10.1016/j.microrel.2007.01.088

Google Scholar

[18] B. Illés, B. Horváth, Tin whisker growth from micro-alloyed SAC solders in corrosive climate,, J. Alloys Compd., vol. 616, p.116–121, (2014).

DOI: 10.1016/j.jallcom.2014.07.103

Google Scholar