Alum Production from some Nigerian Kaolinite Deposits

Article Preview

Abstract:

The Development of Sustainable Processing Technologies for the Vast Mineral Resources Available in Nigeria and their Varied Applications Is a Major Pursuit by the Federal Ministry of Science and Technology. in this Work, Alum Was Produced from Three Different Kaolin Deposits in Nigeria Namely Kankara Brown, Bauchi and Kankara White by Acid Dealumination of the Metakaolin Obtained by Calcination of the Beneficiated Kaolinites and the Yields Were Measured to Ascertain the Process Repeatability. the Reproducibility Studies Carried Out on Samples from each Deposit Showed a Mean Yield of 80 %, 92 % and 87 % and Standard Deviation of 2.50 %, 1.063 % and 1.296 %, for Kankara Brown, Bauchi and Kankara White Respectively. the Values from the Three Deposits Fall within 3 Standard Deviations of the Mean in Accordance with the 68-95-99.7/three-Sigma Rule. the Alum Quality Also Compares Well with Available Commercial Alums in the Market. BET Analysis, of the Alumina Obtained by Calcination of the Alum (Kankara White), Gave a Surface Area of 192.2441m2/g Comparable to Commercial Alumina. these Results Suggest/establishes the Huge Possibility of Commercial Alum Production, Including Alumina, Using Kaolinite Clay from these Deposits as Starting Materials.

You might also be interested in these eBooks

Info:

Pages:

13-19

Citation:

Online since:

September 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Solid Mineral Development, Community portal of Nigeria [Retrieved 2010 May 17], Available from www. onlinenigeria. com.

Google Scholar

[2] K.S. Ahmed, Development of phosphate bonded fireclay refractory, M. Sc thesis, Department of Chemical Engineering, Ahmadu Bello University, Zaria, (1986).

Google Scholar

[3] B.O. Aderemi, Kinetics Study on Aluminum Sulphate Crystal Growth out of Kankara Kaolin Dealumination Spent Acid – A Spent Acid Recovery Process. Nig. Jour. of Eng. 10 (1) (2002) 27– 34.

Google Scholar

[4] B.O. Aderemi, A.S. Ahmed, B.D. Abdul. Production of alum from Kankara clay, Jour. of Nig. Soc. Chem. Eng. 21(1, 2) (2006) 120-124.

Google Scholar

[5] B.O. Aderemi, L.C. Edomwonyi-Out and S.S. Adefila. A new approach to metakaolin Dealumination, Aus. Jour. of Basic and Appl. Sci. (AJBAS) 3 (3) (2009) 2243-2248.

Google Scholar

[6] L. Edomwonyi-Otu and B.O. Aderemi. Alums from Kankara kaolin. Jour. of Res. in Eng. 6 (1) (2009) 105-111.

Google Scholar

[7] K. Othmer, Alumina. In Encyclopedia of Chemical Technology, Wiley Inter-science, New York, 1997 Vol 2 pp.219-234, 240- 268.

Google Scholar

[8] B.O. Aderemi, E.F. Oloro, D. Joseph and J. Oludipe. Kinetics of the Dealumination of Kankara Kaolin Clay, Nig. Jour. Eng. 9 (1) (2001) 40-44.

Google Scholar

[9] L. Edomwonyi-Otu, B.O. Aderemi and K.S. Ahmed. Effect of beneficiation on the yield and quality of alum from Kankara kaolin, Nig. Jour. Eng. 16 (2) (2010) 36-43.

Google Scholar

[10] Alum and some industrial applications. [NPCS homepage; cited 2010 Dec 10]. Available from http: /www. niir. org.

Google Scholar

[11] Alum. Microsoft Encarta Premium 2009 DVD.

Google Scholar

[12] R.R. Smith, S.W. McCrary and R.N. Callahan, Gauge repeatability and reproducibility studies and measurement system analysis: A multi-method exploration of the state of practice, Jour of Ind. Tech. 1 (23) (2007) 2.

Google Scholar

[13] C. Herrnstein, R. Murray, The bell curve: intelligence and class structure in American life, Free Press. (1994).

Google Scholar

[14] W.H. Kruskal, S.M. Stigler, Normative terminology: normal, in statistics and elsewhere. In Statistics and public policy, edited by Bruce D. Spencer, Oxford University Press, (1997).

Google Scholar

[15] K. Krishnamurthy, Handbook of statistical distributions with applications, Chapman & Hall/CRC, (2006).

Google Scholar

[16] F. Acquah, B. Mensah, Y. Obeng, Production of alum from Awaso Bauxite, Ghana Engineer, May (1999).

Google Scholar

[17] L.K. Hudson, C. Misra, A.J. Perrotta, K. Wefers, F.S. Williams, Aluminum Oxide" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, (2002).

DOI: 10.1002/14356007.a01_557

Google Scholar

[18] P. Patnaik, Handbook of Inorganic Chemicals. McGraw-Hill, New York, (2002).

Google Scholar

[19] G. Paglia, Determination of the structure of γ-Alumina using Empirical and First Principles Calculations Combined with Supporting Experiments, Curtin University of Technology, Perth, 2004, Retrieved 2011-05-05.

Google Scholar