Nanomaterial-Polymer Composites for High-Temperature Fluid Loss Reduction in Water-Based Drilling Fluids

Article Preview

Abstract:

In this study, we systematically evaluated the fluid loss reduction effect of four nanomaterials in high-temperature water-based drilling fluids. Compared to the natural polymer PAC, the synthetic acrylamide-based polymer-maintained integrity and reduced fluid loss from 36.25 mL to 14 mL after aging at 180 °C, while forming a thinner and less permeable filter cake. Among the nanomaterials tested, 0.5 wt.% TiO2 showed the most significant fluid loss reduction after aging at 180 °C, significantly optimizing the particle size distribution and reducing the fluid loss. When the polymer was used in combination with TiO2, a significant synergistic enhancement was observed, which reduced the fluid loss to a minimum value of 11.6 mL at 180 °C. Zeta potential, particle size analysis, and SEM images showed that the effect resulted from the improved colloidal stability, closer packing of the particles, and the formation of a dense filter cake structure. The results show that the nanomaterial-polymer composite system can significantly improve the high-temperature fluid loss reduction performance of drilling fluids through the dual mechanism of physical blocking and chemical interaction, which provides an effective strategy for the design of high-performance fluid loss reduction agents.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

75-81

Citation:

Online since:

March 2026

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2026 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Li, J. et al. A zwitterionic copolymer as fluid loss reducer for water-based drilling fluids in high temperature and high salinity conditions. Geoenergy Science and Engineering 222 (2023), p.111200.

DOI: 10.1016/j.petrol.2022.111200

Google Scholar

[2] Aftab, A., Ismail, A. R., Ibupoto, Z. H., Akeiber, H. & Malghani, M. G. K. Nanoparticles based drilling muds a solution to drill elevated temperature wells: A review. Renewable and Sustainable Energy Reviews 76 (2017), pp.1301-1313.

DOI: 10.1016/j.rser.2017.03.050

Google Scholar

[3] Huo, J.-h. et al. Investigation of synthesized polymer on the rheological and filtration performance of water-based drilling fluid system. Journal of Petroleum Science and Engineering 165 (2018), pp.655-663.

DOI: 10.1016/j.petrol.2018.03.003

Google Scholar

[4] Lei, M., Huang, W., Sun, J., Jin, Z. & Huang, X. The Utilization of Self-Crosslinkable Nanoparticles as High-Temperature Plugging Agent in Water-Based Drilling Fluid. SPE Journal 27 (2022), pp.2628-2641.

DOI: 10.2118/209805-pa

Google Scholar

[5] Zhu, W., Zheng, X., Shi, J. & Wang, Y. A high-temperature resistant colloid gas aphron drilling fluid system prepared by using a novel graft copolymer xanthan gum-AA/AM/AMPS. Journal of Petroleum Science and Engineering 205 (2021), p.108821.

DOI: 10.1016/j.petrol.2021.108821

Google Scholar

[6] Zhu, W. & Zheng, X. Effective Modified Xanthan Gum Fluid Loss Agent for High-Temperature Water-Based Drilling Fluid and the Filtration Control Mechanism. ACS Omega 6 (2021), pp.23788-23801.

DOI: 10.1021/acsomega.1c02617

Google Scholar

[7] Luo, Y. et al. Degradation Mechanism of P(AA/AMPS)and P(AM/AA/AMPS)Aqueous Solutions at High Temperature. Oilfield Chemistry 39 (2022), pp.202-208.

Google Scholar

[8] Lin, M. et al. Temperature resistance of AM/AMPS/NVP copolymer microspheres. Iranian Polymer Journal 29 (2020), pp.445-453.

DOI: 10.1007/s13726-020-00809-5

Google Scholar

[9] Huang, Y., Zhang, D. & Zheng, W. Synthetic copolymer (AM/AMPS/DMDAAC/SSS) as rheology modifier and fluid loss additive at HTHP for water-based drilling fluids. Journal of Applied Polymer Science 136 (2019), p.47813.

DOI: 10.1002/app.47813

Google Scholar

[10] Liu, F., Jiang, G., Peng, S., He, Y. & Wang, J. Amphoteric Polymer as an Anti-calcium Contamination Fluid-Loss Additive in Water-Based Drilling Fluids. Energy & Fuels 30 (2016), pp.7221-7228.

DOI: 10.1021/acs.energyfuels.6b01567

Google Scholar

[11] Xie, B. & Liu, X. Thermo-thickening behavior of LCST-based copolymer viscosifier for water-based drilling fluids. Journal of Petroleum Science and Engineering 154 (2017), pp.244-251.

DOI: 10.1016/j.petrol.2017.04.037

Google Scholar

[12] Pang, S., Zhao, L. & An, Y. Advanced developments in nanotechnology and nanomaterials for the oil and gas industry: A review. Geoenergy Science and Engineering 238 (2024), p.212872.

DOI: 10.1016/j.geoen.2024.212872

Google Scholar

[13] Parizad, A., Shahbazi, K. & Ayatizadeh Tanha, A. Enhancement of polymeric water-based drilling fluid properties using nanoparticles. Journal of Petroleum Science and Engineering 170 (2018), pp.813-828.

DOI: 10.1016/j.petrol.2018.06.081

Google Scholar

[14] Cheraghian, G. Nanoparticles in drilling fluid: A review of the state-of-the-art. Journal of Materials Research and Technology 13 (2021), pp.737-753.

DOI: 10.1016/j.jmrt.2021.04.089

Google Scholar

[15] Zhong, H. et al. Nano-CaCO3/AA-AM-AMPS cross-linked polymer core-shell structural nanocomposite as high temperature and high salt resistant filtration reducer in water-based drilling fluid. Geoenergy Science and Engineering 224 (2023), p.211590.

DOI: 10.1016/j.geoen.2023.211590

Google Scholar

[16] Parizad, A., Shahbazi, K. & Tanha, A. A. SiO2 nanoparticle and KCl salt effects on filtration and thixotropical behavior of polymeric water based drilling fluid: With zeta potential and size analysis. Results in Physics 9 (2018), pp.1656-1665.

DOI: 10.1016/j.rinp.2018.04.037

Google Scholar

[17] Li, X. et al. Compatibility and efficiency of hydrophilic/hydrophobic nano silica as rheological modifiers and fluid loss reducers in water-based drilling fluids. Geoenergy Science and Engineering 234 (2024), p.212628.

DOI: 10.1016/j.geoen.2023.212628

Google Scholar

[18] Ibrahim, M. A. et al. The influence of nanoparticle size, concentration, and functionalization on drilling fluid filtration properties. Colloids and Surfaces A: Physicochemical and Engineering Aspects 693 (2024), p.134020.

DOI: 10.1016/j.colsurfa.2024.134020

Google Scholar

[19] Ma, J., Pang, S., Zhang, Z., Xia, B. & An, Y. Experimental Study on the Polymer/Graphene Oxide Composite as a Fluid Loss Agent for Water-Based Drilling Fluids. ACS Omega 6 (2021), pp.9750-9763.

DOI: 10.1021/acsomega.1c00374

Google Scholar

[20] Li, H., Huang, X., Sun, J. & Lv, K. Multi-ring side groups copolymer as an effective filtration control additive for water-based drilling fluids under high temperature and salt contamination. Geoenergy Science and Engineering 225 (2023), p.211690.

DOI: 10.1016/j.geoen.2023.211690

Google Scholar

[21] Sun, J. et al. Environmentally friendly and salt-responsive polymer brush based on lignin nanoparticle as fluid-loss additive in water-based drilling fluids. Colloids and Surfaces A: Physicochemical and Engineering Aspects 621 (2021), p.126482.

DOI: 10.1016/j.colsurfa.2021.126482

Google Scholar