Tribological Analysis of Manganese Phosphate Coating on Steel Pistons for Internal Combustion Engines

Article Preview

Abstract:

Aluminum, steel, and cast iron pistons all function in the automotive market, each possessing specific properties. The most common type of piston is aluminum, but in recent years, there has been a noticeable increase in the production of steel pistons. One of the manufacturing processes used in the production of steel pistons is manganese phosphating. The coating obtained through this process provides corrosion resistance and enhances the sliding properties of the working surfaces, thereby extending the lifespan of the internal combustion engine piston. When conducting a tribological analysis of the surface created in the chemical process, it is essential to pay particular attention to the grain size and the thickness of the coating to ensure that the pistons have the appropriate properties. The analysis was carried out using both micro and macroscopic examination. A grain growth analysis was conducted over time, and a comparative analysis was performed to evaluate the impact of operating time in an internal combustion engine on the working surface of the piston. The grain size affects the amount of oil carried during operation. These grains tend to wear down during operation, losing their properties, and the degree of change occurring on the surface was described using a piston with a mileage of approximately 100,000 kilometers as an example.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

43-59

Citation:

Online since:

June 2025

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2025 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] D. Özkan, H. Kaleli, Surface and wear analysis of zinc phosphate coated engine oil ring and cylinder liner tested with commercial lubricant, Hindawi Publishing Corporation Advances in Mechanical Engineering Volume 2014.

DOI: 10.1155/2014/150968

Google Scholar

[2] R.A. Mufti, M. Priest, Effect of engine operating conditions and lubricant rheology on the distribution of losses in an internal combustion engine, ASME J. Tribol. 131 (2009) 1–9.

DOI: 10.1115/1.3176988

Google Scholar

[3] S.C. Tung, M. McMillan, Automotive tribology overview of current advances and challenges for the future, Tribol. Int. 37 (2004) 517–536.

DOI: 10.1016/j.triboint.2004.01.013

Google Scholar

[4] H.V. Chavan, M. Yadav: Investigation of significant process parameter in manganese phosphating of piston pin mate", Int Journal of Engineering Research and Applications, Vol. 5, Issuse 12, (2015) 17-20.

Google Scholar

[5] S. Shanmugama, K. Ravichandran, T.S.N. Sankara Narayanan, Min Ho Lee, A facile electrochemical approach for the deposition of iron-manganese phosphate composite coatings on aluminium, RSC Advances, (2015).

DOI: 10.1039/c4ra08195a

Google Scholar

[6] V. Kvedaras, J. Vilys, V. Ciuplys, A. Ciuplys, Fatigue strenght of chrominium plated steell, Material science, vol 12, (2006).

Google Scholar

[7] C. Marikkanu, N.S. Rengaswamy, Studies on manganese phospahting on steel, bulletin of Electrochemistry, 15 (1999) pp.104-108.

Google Scholar

[8] S. Ilaiyavela, A. Venkatesan, Investigation of wear coefficient of manganese phosphate coated tool steel, Tribology in Industry, Vol.35 (2013) p.69‐73.

Google Scholar

[9] T. V. Doan, D. Kusmič, M. Pospíchal, D Dobrocký, Improvement of wear resistance for C45 steel using plasma nitriding, nitrocarburizing and nitriding/ manganese phosphating duplex treatment, IOP Conf. Series: Materials Science and Engineering 179 (2017).

DOI: 10.1088/1757-899x/179/1/012017

Google Scholar

[10] D. Ozkan, H. Kaleli, L. Yuksek, Quantitative comparison of tribological performance of chromium- and zinc-phosphate-coated piston rings in tribotest rig, J Engineering Tribology (2017), Vol. 231 75–92.

DOI: 10.1177/1350650116646918

Google Scholar

[11] J. Pohl, K. E. Rydberg, P. Krus, Thermal aspects in lubrication system design for internal combustion engines, Journal of Shanghai Jiaotong University (2000).

Google Scholar

[12] A. Wolf, Influence of piston ring profiles and oil temperature distribution on cylinder liner lubrication of a marine two-stroke engine. Combustion Engines 178 (2019) pp.257-263.

DOI: 10.19206/ce-2019-345

Google Scholar

[13] A. Usman, C. W. Park, Numerical investigation of frictional behaviour and energy loss in mixed hydrodynamic contact of piston ring pack with deformed cylinder liner during warm up period of SI engine. Energy Conserv. Manage 117 (2016) p.115–131.

DOI: 10.1016/j.enconman.2016.03.035

Google Scholar

[14] S. H. Park, C. S. Lee, Applicability of dimethyl ether (DME) in a compression ignition engine as an alternative fuel. Energy Conv. Manage 86 (2014) p.848–863.

DOI: 10.1016/j.enconman.2014.06.051

Google Scholar

[15] A. Usman, T. V Cheema, P. C. W. Ahmad, Tribological performance evaluation and sensitivity analysis of piston ring lubricating film with deformed cylinder liner. Proc. Inst. Mech. Eng. Part J. J. Eng. Tribol 229 (2015) p.1455–1468.

DOI: 10.1177/1350650115581029

Google Scholar

[16] K. Siadkowska, A. Majczak, G. Barański, Studying a construction of piston for the aircraft CI engine. Combustion Engines 168 (2017) pp.161-167.

DOI: 10.19206/ce-2017-126

Google Scholar

[17] P. Żurawski, Optimization of the combustion chamber strength of aluminum pistons in diesel engines using the DuralBowl technology. Combustion Engines 192 (2023) pp.91-96.

DOI: 10.19206/ce-153000

Google Scholar

[18] A. Wolff, G. Koszałka, Influence of engine load on piston ring pack operation of an automotive IC engine. Combustion Engines 190 (2022) pp.88-94.

DOI: 10.19206/ce-141737

Google Scholar

[19] M. A. Zayedu, F.A. Nour El-Dien and Amal I. Hassan, Effect of chemical composition of zinc phosphating solution on phosphate coating properties, Egyptian Journal of Chemistry 52 (2009) pp.699-709.

Google Scholar

[20] J.D. B. De Mello, H.L. Costa, R. Binder. Friction and wear behavior of steam‐ oxidized sintered iron components coated with manganese Phosphate, Wear 263 (2007) p.842‐848.

DOI: 10.1016/j.wear.2007.01.062

Google Scholar

[21] G. Arundeesh S. Lakshmanan, N. Dileepan, Dr. N. Balakraishnan, Analysis the effect of fatigue performance of phosphate surface coating on the cylinder liner materials by using ANOVA and FTest. International Journal For Research In Mechanical & Civil Engineering Volume-3, Issue-4, Paper-15 (2017).

Google Scholar

[22] L. Fang, L. Xie, J. Hu, Y. Li, W. Zhng, Study on the growth and corrosion resistance of manganese phosphate coatings on 30CrMnMoTi alloy steel, The Fourth International Conference on Surface and Interface Science and Engineering, Physics Procedia 18 (2011) p.227–233.

DOI: 10.1016/j.phpro.2011.06.086

Google Scholar

[23] F. Pastorek, K. Borko, S. Fintova, D. Kajanek, B. Hadzima. Effect of surface pretreatment on quality and electrochemical corrosion properties of manganese phosphate on S355J2 HSLA steel. Coatings (2016).

DOI: 10.3390/coatings6040046

Google Scholar

[24] C. Nejneru, D.P. Burduhos-Nergis, M. Axinte, M.C. Perju, C. Bejinariu. Analysis of the physical-mechanical properties of the zinc phosphate layer deposited on a nodular cast iron substrate. Coatings 12 (2022) , 1384.

DOI: 10.3390/coatings12101384

Google Scholar