Electrical Conductivity in Alkali Iron Phosphate Glasses

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Abstract:

The electrical properties of 10M2O-36Fe2O3-54P2O5 (M=Li, Na and K) glasses were studied in the temperature range from 323 to 573 K. Non-linear Arrhenius behavior was observed for all the samples examined. It was shown that in both high- and low-temperature ranges, the replacement of Li, Na and K would result in decreases in both the dc conductivity and the activation energy. Analysis of the relationship of the parameters included in the Arrhenius equation, activation energy and the pre- exponential factor for each sample, preliminary explanations for these experimental phenomena have been presented.

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Periodical:

Key Engineering Materials (Volumes 368-372)

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1446-1448

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Online since:

February 2008

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© 2008 Trans Tech Publications Ltd. All Rights Reserved

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