Application of SMA on the Alloy of Nylon6/ABS

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The alloy of Nylon6/Acrylonitrile-Butadiene-Styrene (ABS) with styrene-maleic anhydride (SMA) was prepared by melt blending as the compatilizer. Mechanical characteristics, dynamic mechanical analysis (DMA) and fracture appearances were determined. It was found that the impact and tensile strength firstly increased and then decreased along with the increase of the SMA content. The properties reached maximum values when the content of SMA was 2%. The results of DMA and scanning electron microscope (SEM) indicated that the addition of SMA can effectively enhance the compatibility of Nylon6 and ABS.

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57-63

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January 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] Triacca. V. J., Reactive compatibilization of blends of nylon 6 and ABS materials, Polymer. 32 (1991) 1401.

DOI: 10.1016/0032-3861(91)90420-n

Google Scholar

[2] Otterson D. M, Kim B. H, Lavengood. R. E., The effect of compatibilizer level on the mechanical properties of a nylon 6/ABS polymer blend, J. Mater. Sci. 26 (1991) 1479.

DOI: 10.1007/bf00544656

Google Scholar

[3] Usuki A., Kojima Y., Kawasumi M., Okada A., et al, Synthesis of nylon 6-clay hybrid, J. Mater. Res. 8 (1993) 1174.

Google Scholar

[4] Usuki A., Kojima Y., Kawasumi M., Okada A., et al, Synthesis of nylon 6-clay hybrid, J. Mater. Res. 8 (1993) 1179.

DOI: 10.1557/jmr.1993.1179

Google Scholar

[5] Usuki A., Kojima Y., Kawasumi M., Okada A., et al, Synthesis of nylon 6-clay hybrid, J. Mater. Res. 8 (1993) 1185.

Google Scholar

[6] S. M. Lai, Y. C. Liao, T. W. Chen., Properties and preparation of compatibilized nylon 6 nanocomposites/ABS blends using functionalized metallocene polyolefin elastomer. I. Impact properties, J. Appl. Polym. Sci. 100 (2006) 1364.

DOI: 10.1002/app.23630

Google Scholar

[7] R. A. Kudva, H. Keskkula, D.R. Paul., Properties of compatibilized nylon 6/ABS blends: Part I. Effect of ABS type, Polymer. 41 (2000) 225.

DOI: 10.1016/s0032-3861(99)00105-6

Google Scholar

[8] R. A. Kudva, H. Keskkula, D.R. Paul., Properties of compatibilized nylon 6/ABS blends: Part II. Effects of compatibilizer type and processing history, Polymer. 41 (2000) 239.

DOI: 10.1016/s0032-3861(99)00106-8

Google Scholar

[9] Triacca V., Kesukkula H., Paul D. R., Reactive compatibilization of blends of nylon 6 and ABS materials, Polymer. 32 (1991) 1404.

DOI: 10.1016/0032-3861(91)90420-n

Google Scholar

[10] Duin M. V., Aussems M., Borggreve R. J. M., Graft formation and chain scission in blends of polyamide-6 and -6. 6 with maleic anhydride containing polymers, J. Polym. Sci. 36 (1998) 181.

DOI: 10.1002/(sici)1099-0518(19980115)36:1<179::aid-pola22>3.0.co;2-f

Google Scholar

[11] Triacca V. J., Ziaee S., Barlow J. W., Reactive compatibilization of blends of nylon 6 and ABS materials, Polymer. 32 (1991) 1409.

DOI: 10.1016/0032-3861(91)90420-n

Google Scholar

[12] Kim B. K., Lee Y. M., Jeong H. M., Physical properties of ABS/SMA/nylon-6 ternary blends: effect of blending sequence, Polymer. 34 (1993) (2078).

DOI: 10.1016/0032-3861(93)90734-r

Google Scholar

[13] Majumdar B., Keskkula H., Paul D. R., Deformation mechanisms in nylon 6/ABS blends, J. Polym. Sci. 32 (1994) 2131.

DOI: 10.1002/polb.1994.090321219

Google Scholar

[14] Majumdar B., Keskkula H., Paul D. R., Effect of the nature of the polyamide on the properties and morphology of compatibilized nylon/acrylonitrile-butadiene-Styrene blends, Polymer. 35 (1994) 5473.

DOI: 10.1016/s0032-3861(05)80010-2

Google Scholar

[15] Kudva R. A., Keskkula H., Paul D. R., Fracture behavior of nylon 6/ABS blends compatibilized with an imidized acrylic polymer, Polymer. 41 (2000) 345.

DOI: 10.1016/s0032-3861(99)00244-x

Google Scholar

[16] Kudva R. A., Keskkula H., Paul D. R., Properties of compatibilized nylon 6/ABS blends: Part II. Effects of compatibilizer type and processing history, Polymer. 41 (2000) 242.

DOI: 10.1016/s0032-3861(99)00106-8

Google Scholar

[17] Marchal P., Coppens G., Legras R., et al, Molecular weight segregation induced by interfacial melt reactivity in polyamide 6/reactive rubber blends, J. Polym. Sci. Pol. Chem. 33 (1995) 760.

DOI: 10.1002/polb.1995.090331305

Google Scholar

[18] Pitman I. H., Higuchi T., Fung H. L. Specific solvation effects on acylation of amines in solvents with low dielectric constants, J. Org. Chem. 40 (1975) 379.

DOI: 10.1021/jo00891a026

Google Scholar

[19] Lu Wang, Guo Baohua, Xie Xuming, The preparation of MAH/St multi-monomer melt grafting on ABS and its compatibilizer effect on PA6/ABS blends, Acta Polymerica Sinica. 4 (2005) 213.

Google Scholar

[20] Chen Yujun, Wu Xianfeng, Study of the nylon6/nylon 1010 blend Ⅲ: dynamic mechnanical behavior, Polymer Materials Science and Engineering. 5 (1997) 123.

Google Scholar

[21] Jin Riguang, Hua Youqing. Polymer Science. Chemical Industry Press,Beijing, 2007, pp.213-219.

Google Scholar

[22] Wang Peipeng, Fan Qingchun, Application of ABS grafted with maleic anhydride in PA 6/ABS blend , China Synthetic Resin and Plastics. 2 (2008) 36.

Google Scholar