First Steps on the Modeling and Simulation of Thermoplastic/Thermoset Phase Separation

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Abstract:

Matrices employed in composites parts of aeronautic structures consist of a thermoset / thermoplastic mixture. Thermoplastic is introduced in low concentration in order to improve the mechanical properties, in particular the ones related to choc resistance. However, there are two antagonist mechanisms, the one related to energy that leads to demixing and the one related to entropy that tends to mix. These effects are strongly coupled with the elasticity of thermoplastic, the evolution from a newtonian fluid to a viscoelastic one of thermosets, the presence of reinforcement fibers, … and are nowadays bad understood despite the significant impact that these effects have on the composite microstructure and then on its mechanical properties. This work constitutes a first attempt to understand these complex physics.

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Key Engineering Materials (Volumes 504-506)

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283-288

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February 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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