The Effect of Co Addition on Glassy Forming Ability and Soft Magnetic Properties of Fe-Si-B-P Bulk Metallic Glass

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We Successfully Prepared the Rod Glassy Samples of (Fe1-xCox)76Si9B10P5 (x = 0~0.4) Bulk Metallic Glass (BMG) with the Diameters up to 3.0 mm by Substituting Fe for a Small Amount of Co Element. A Certain Amount of Co Substitution for Fe Contributes to the Increase of the Glass-Forming Ability (GFA) while Maintaining Good Mechanical Properties (the Fracture Strength up to 3700 MPa). This Co-Added Ferromagnetic Bulk Glassy Alloy System Also Exhibits a Higher Saturation Magnetization of 1.49 T and Lower Coercive Force (Hc, 1.2 A/m). The Fe-Based BMGs with Alloying a Small Amount of Co Element Demonstrate Excellent Combination of High GFA, Good Soft-Magnetic Properties as Well as High Strength.

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112-116

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March 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] H. Fujimori, T. Masumoto, Y. Obi, and M. Kikuchi, On the magnetization process in an iron-phosphorus-carbon amorphous ferromagnet, Jpn. J. Appl. Phys. 13 (1974) 1889–1890.

DOI: 10.1143/jjap.13.1889

Google Scholar

[2] T. Egami, P. J. Flanders, C. D. Graham, Low−field magnetic properties of ferromagnetic amorphous alloys, Appl. Phys. Lett. 26 (1975) 128–130.

DOI: 10.1063/1.88072

Google Scholar

[3] P. J. Flanders, C. D. Graham, T. Egami, Magnetic properties of amorphous magnetic alloys, IEEE Trans. Magn. 11, (1975) 1323–1325.

DOI: 10.1109/tmag.1975.1058903

Google Scholar

[4] R. W. Cahn, Background to rapid solidification processing, in: H. H. Liebermann (Eds. ), Rapidly Solidified Alloys, Marcel Dekker, New York, 1993, p.1–15.

Google Scholar

[5] J. Zhang, H. Fujimori, A. Inoue, T. Masumoto, Specific heat behaviour on soft magnetic thick amorphous ribbons of an Fe-B-Si alloy, Mater. Sci. Eng. 99 (1988) 35–38.

DOI: 10.1016/b978-1-85166-973-8.50013-6

Google Scholar

[6] A. Inoue, K. Ohtera, K. Kita, T. Masumoto, New amorphous Mg-Ce-Ni alloys with high strength and good ductility, Jpn. J. Appl. Phys., Part 2, 27 (1988) L2248–L2251.

DOI: 10.1143/jjap.27.l2248

Google Scholar

[7] A. Inoue, T. Zhang, T. Mosumoto, Al-La-Ni amorphous alloys with a wide supercooled liquid region, Mater. Trans. 30 (1989) 965–972.

DOI: 10.2320/matertrans1989.30.965

Google Scholar

[8] W. L. Johnson, Bulk glass-forming metallic alloys: science and technology, MRS Bull. 24 (1999) 42–56.

DOI: 10.1557/s0883769400053252

Google Scholar

[9] A. Inoue, Stabilization of metallic supercooled liquid and bulk amorphous alloys, Acta Mater. 48 (2000) 279–306.

DOI: 10.1016/s1359-6454(99)00300-6

Google Scholar

[10] A. Inoue, J. S. Gook, Fe-based ferromagnetic glassy alloys with wide supercooled liquid region, Mater. Trans. 36 (1995) 1180–1183.

DOI: 10.2320/matertrans1989.36.1180

Google Scholar

[11] A. Inoue, Y. Shinohara, J. S. Gook, Thermal and magnetic properties of bulk Fe-based glassy alloys prepared by copper mold casting, Mater. Trans. 36 (1995) 1427–1433.

DOI: 10.2320/matertrans1989.36.1427

Google Scholar

[12] T. D. Shen, R. B. Schwarz, Bulk ferromagnetic glasses prepared by flux melting and water quenching, Appl. Phys. Lett. 75 (1999) 49–51.

DOI: 10.1063/1.124273

Google Scholar

[13] A. Inoue, A. Takeuchi, B. L. Shen, Formation and functional properties of Fe-based bulk glassy alloys, Mater. Trans. 42 (2001) 970–978.

DOI: 10.2320/matertrans.42.970

Google Scholar

[14] A. Makino, T. Kubota, C.T. Chang, M. Makabe, FeSiBP bulk metallic glasses with unusual combination of high magnetization and high glass-forming ability, A. Inoue, Mater. Trans. 48 (2007) 3024–3027.

DOI: 10.2320/matertrans.mrp2007198

Google Scholar

[15] A. Inoue, B. L. Shen, New Fe-based bulk glassy alloys with high saturated magnetic flux density of 1. 4–1. 5 T, Mater. Sci. Eng. A, 375–377 (2004) 302–306.

DOI: 10.1016/j.msea.2003.10.058

Google Scholar

[16] A. Inoue, R. E. Park, Soft magnetic properties and wide supercooled liquid region of Fe-P-B-Si base amorphous alloys, Mater. Trans. 37 (1996) 1715–1721.

DOI: 10.2320/matertrans1989.37.1715

Google Scholar

[17] T. Mizushima, K. Ikarashi, A. Makino, A. Inoue, Structure and magnetic properties of bulk Fe-Al-Ga-P-C-B-Si glassy alloys in a ringed form prepared by copper mold casting IEEE Trans. Magn. 35 (1999) 3361–3363.

DOI: 10.1109/20.800524

Google Scholar

[18] H. Koshiba, A. Inoue, A. Makino, Fe-based soft magnetic amorphous alloys with a wide supercooled liquid region J. Appl. Phys. 85 (1999) 5136–5138.

DOI: 10.1063/1.369102

Google Scholar

[19] A. Makino, A. Inoue, T. Mizushima, Soft magnetic properties of Fe-based bulk amorphous alloys, Mater. Trans. 41 (2000) 1471–1477.

DOI: 10.2320/matertrans1989.41.1471

Google Scholar

[20] B. L. Shen, M. Akiba, A. Inoue, Effects of Si and Mo additions on glass-forming in FeGaPCB bulk glassy alloys with high saturation magnetization, Phys. Rev. B, 73 (2006) 104204-1–104204-6.

DOI: 10.1103/physrevb.73.104204

Google Scholar

[21] A. Inoue, B.L. Shen, A.R. Yavari, A.L. Greer, Mechanical properties of Fe-based bulk glass in Fe-B-Si-Nb and Fe-Ga-P-C-B-Si systems, J. Mater. Res. 18 (2003) 1487–1492.

DOI: 10.1557/jmr.2003.0205

Google Scholar

[22] A. Inoue, R. E. Park, Soft magnetic properties and wide supercooled liquid region of Fe-P-B-Si base amorphous alloys, Mater. Trans. 37 (1996) 1715–1721.

DOI: 10.2320/matertrans1989.37.1715

Google Scholar

[23] A. Inoue, A. Murakami, T. Zhang, A. Takeuchi, Thermal stability and magnetic properties of bulk amorphous Fe-Al-Ga-P-C-B-Si alloys, Mater. Trans. 38 (1997) 189–196.

DOI: 10.2320/matertrans1989.38.189

Google Scholar

[24] D.S. Song, J.H. Kim, E. Fleury W.T. Kim, D.H. Kim, Synthesis of ferromagnetic Fe-based bulk glassy alloys in the Fe–Nb–B–Y system, J. Alloy Compd. 389 (2005) 159–164.

DOI: 10.1016/j.jallcom.2004.08.014

Google Scholar