Synthesis and Characterization of Nanostructured Co(OH)2 and Co3O4 Thin Films by a Simple Solution Growth Process

Article Preview

Abstract:

Nanostructured Co(OH)2 thin films were synthesized by a simple solution growth process. In experiment, F and NH3 were used as Co2+ ordination agents, and hydroxyl ions were supplied by ammonia hydroxide solution for the hydrolysis reaction. The results showed that the solution pH and F/Co ratio had great influences on the morphologies of the thin films. The Co(OH)2 thin films were constructed with lots of Co(OH)2 nanoflakes. Nanostructured Co3O4 thin films were prepared by annealing the Co(OH)2 thin films at 400°C for 2 h. The magnetic properties of Co3O4 thin films were also investigated.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

247-251

Citation:

Online since:

January 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] C.Y. Ma, Z. Mu, J. J. Li, et al., Mesoporous Co3O4 and Au/Co3O4 catalysts for low-temperature oxidation of trace ethylene, J. Am. Chem. Soc. 132 (2010) 2608–2613.

Google Scholar

[2] B. Varghese, Y.S. Zhang, L. Dai, V.B.C. Tan, C.T. Lim, C.H. Sow, Structure-mechanical property of individual cobalt oxide nanowires, Nano Lett. 8 (2008) 3226–3232.

DOI: 10.1021/nl801555d

Google Scholar

[3] L. H. Hu, Q. Peng, Y. D. Li, Selective synthesis of Co3O4 nanocrystal with different shape and crystal plane effect on catalytic property for methane combustion, J. Am. Chem. Soc. 130 (2008) 16136-37.

DOI: 10.1021/ja806400e

Google Scholar

[4] Y. G. Li, B. Tan, Y. Y. Wu, Mesoporous Co3O4 nanowire arrays for lithium ion batteries with high capacity and rate capability, Nano Lett. 8 (2008) 265–270.

DOI: 10.1021/nl0725906

Google Scholar

[5] G. McDonald, A preliminary-study of a solar selective coating system using a black cobalt oxide for high-temperature solar collectors, Thin Solid Films 72 (1980) 83.

DOI: 10.1016/0040-6090(80)90561-1

Google Scholar

[6] S. Noguchi, M. Mizuhashi, Optical-properties of Cr-Co oxide-films obtained by chemical spray deposition-substrate-temperature effects, Thin Solid Films 77 (1981) 99.

DOI: 10.1016/0040-6090(81)90364-3

Google Scholar

[7] W. Y. Li, L. N. Xu, Co3O4 nanomaterials in lithium-ion batteries and gas sensors, J. Chen, Adv. Funct. Mater. 15 (2005) 851.

DOI: 10.1002/adfm.200400429

Google Scholar

[8] S. A. Makhlouf, Magnetic properties of Co3O4 nanoparticles, J. Magn. Magn. Mater 246 (2002) 184.

Google Scholar

[9] Y. G. Zhang, Y. C. Chen, T. Wang, J. Zhou, Y. G. Zhao, Synthesis and magnetic properties of nanoporous Co3O4 nanoflowers, Micropor. Mesopor. Mater.114 (2008) 257.

Google Scholar

[10] Y. Kitamoto, S. Kantake, et al., Low-temperature fabrication of Co ferrite thin films with high coercivity for perpendicular recording disks by wet process, J. Magn. Magn. Mater. 193 (1999) 97.

DOI: 10.1016/s0304-8853(98)00409-0

Google Scholar

[11] W. W. Wang, Y. J. Zhu, Microwave-assisted synthesis of cobalt oxalate nanorods and their thermal conversion to Co3O4 rods, Mater. Res. Bull. 40 (2005) 1929.

DOI: 10.1016/j.materresbull.2005.06.004

Google Scholar

[12] L. X. Yang, Y. J. Zhu, L. Li, L. Zhang, H. Tong, W. W. Wang, A facile hydrothermal route to flower- like cobalt hydroxide and oxide, Eur. J. Inorg. Chem. 23 (2006) 4787.

DOI: 10.1002/ejic.200600553

Google Scholar

[13] M. Hamdani, J. F. Koenig, P. Chartier, Co3O4 and NiCo2O4 thin-films prepared by reactive-spraying for electrocatalysis.2.cyclic-voltammetry, J. Appl. Electrochem. 18 (1988) 568.

Google Scholar

[14] Y. Lu, Y. Wang, Y. Q. Zou, Z. Jiao, B. Zhao, Y. Q. He, et al. Macroporous Co3O4 platelets with excellent rate capability as anodes for lithium ion batteries, Electrochem Commun 12 (2010) 101-5.

DOI: 10.1016/j.elecom.2009.10.046

Google Scholar

[15] Y. Y. Xu, C. Q. Wang, Y. Q. Sun, G. Y. Zhang, D. Z. Gao, Fabrication and characterization of nearly monodisperse Co3O4 nanospheres, Mater Lett 64 (2010) 1275-8.

DOI: 10.1016/j.matlet.2010.03.007

Google Scholar

[16] Q. Y. Li, R. N. Wang, et al., Preparation and characterization of nanostructured Ni(OH)(2) and NiO thin films by a simple solution growth process, J. Colloid Interface Sci. 320 (2008) 254-258.

DOI: 10.1016/j.jcis.2007.11.006

Google Scholar

[17] Y. Ichiyanagi, Y. Kimishima, S. Yamada, Magnetic study on Co3O4 nanoparticles, J. Magn. Magn. Mater. 1245 (2004) 272–276.

Google Scholar