Chemiluminescence Enhancement Effect for the Determination of Acetaminophen with the Catalysis of Manganese Deuteroporphyrin (Mn(III)DP)

Ying Jun Chao; Liang Xiao Xie; Wei Cao

doi:10.4028/www.scientific.net/KEM.575-576.249

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HomeKey Engineering MaterialsKey Engineering Materials Vols. 575-576Chemiluminescence Enhancement Effect for the...

Chemiluminescence Enhancement Effect for the Determination of Acetaminophen with the Catalysis of Manganese Deuteroporphyrin (Mn(III)DP)

Abstract:

It is found thatManganese Deuteroporphyrin (Mn(Ⅲ)DP) can greatly enhance the chemiluminescence intensity of luminol-hydrogen peroxide system in alkaline conditions. Basing on that fact a flow injection chemiluminescence (CL) method has been developed for the determination of acetaminophen. With the peak height as a quantitative parameter applying optimum conditions, the relative CL intensity was linear with acetaminophen concentration in the range of 1.0×10^-9～1.0×10^-7g/mL with a detection limit of 2.8×10^-10g/mL. The relative standard deviation (RSD) was 2.7% for 2.0 x10^-8 g/mL acetaminophen (n = 11). The proposed method held low detection limit and was successfully applied to determination of acetaminophen in pharmaceutical preparations.

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Key Engineering Materials (Volumes 575-576)

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249-252

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https://doi.org/10.4028/www.scientific.net/KEM.575-576.249

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September 2013

Authors:

Ying Jun Chao, Liang Xiao Xie, Wei Cao

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Acetaminophen, Chemiluminescence, Manganese Deuteroporphyrin (Mn(III)DP)

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