Analysis on Charge and Discharge Mechanism of the Modified Lithium Iron Phosphate Positive Material

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Abstract:

Along with the thorough research of lithium ion battery, the lithium iron phosphate with the peridot structure becomes a new higher energy power battery anode material. But the charge and discharge mechanism of the modified lithium iron phosphate positive material did not get the unity understanding. In this paper, the carbon coating modification, metal ion doping, particle surfaces coated iron-phosphorus phase network and the nanoparticles of lithium iron phosphate were analyzed from the modified microstructure of the lithium ion phosphate batteries, so as to get the charge and discharge mechanism is the results of the active atoms and lithium ion embedded in the grid work and emergence in the layer structure, leading to the energy changes in lithium iron phosphate microstructure.

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Key Engineering Materials (Volumes 579-580)

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41-45

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September 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] J.W. Fergus: Journal of Power Sources, Vol. 195 (2010), p.939.

Google Scholar

[2] J.L. Fan, H.G. Pan and M.X. Gao: Journal of Inorganic Materials, Vol. 22 (2007), p.1032.

Google Scholar

[3] T. Nagakane, H. Yamauchi and K. Yuki: Solid State Ionics, Vol. 206 (2012), p.78.

Google Scholar

[4] A.S. Andersson, J.O. Thomas and B. Kalsk: Electrochem Solid-State Lett, Vol. 3 (2000), p.66.

Google Scholar

[5] J.H. Tian, X.J. Li and C.X. Wei: Chemical Industry and Engineering, Vol. 24 (2007), p.1.

Google Scholar

[6] W.L. Yu, Y.P. Zhao and Q.L. Rao: Chinese Journal of Chemical Engineering, Vol. 17 (2009), p.171.

Google Scholar

[7] J. Chong, S.D. Xun and H.H. Zheng: Journal of Power Sources, Vol. 196 (2011), p.7707.

Google Scholar

[8] E.S. Han, Z.H. Wei and Y. Liu: Chemical Industry and Engineering Progress, Vol. 26 (2007), p.238.

Google Scholar

[9] S. YChung, J. T Bloking and Y. MChiang: Nature Materials, Vol. 1 (2002), p.123.

Google Scholar

[10] A S Andersson, B Kalska and L. Haggstrom: Solid State Ionics, Vol. 130 (2000), p.41.

Google Scholar

[11] G.R. Hu, X.G. Gao and Z.D. Peng: Transactions of Nonferrous Metals Society of China, Vol. 17 (2007), p.296.

Google Scholar

[12] L. Wu, X.H. Li and Z.X. Wang: Powder Technology, Vol. 199 (2010), p.293.

Google Scholar

[13] Y. Zhang, H. Feng and X.B. Wu: Electrochimica Acta, Vol. 54 (2009), p.3206.

Google Scholar

[14] Y.H. Huang: Journal of Power Sources, Vol. 195 (2010), p.610.

Google Scholar

[15] Y.B. Xu and Y.J. Lu: Journal of Power Sources, Vol. 160 (2006), p.570.

Google Scholar

[16] J. Sugiyama, H. Nozaki and K. Kamazawa: Physics Procedia, vol. 30(2012), p.190.

Google Scholar

[17] C.F. Huai, P.G. Liu: Procedia Engineering, Vol. 15 (2011), p.2619.

Google Scholar

[18] Y. Wang, B. Su and J. Park: Journal of Alloys and Compounds, Vol. 509 (2011), p.1040.

Google Scholar

[19] A.R. Michael, J. Vetter and D.U. Sauer: Journal of Power Sources, Vol. 191 (2009), p.582.

Google Scholar

[20] E Zhecheva, Ml Mladenov and P Zlatilova: Journal of Physics and Chemistry of Solids, Vol. 71 (2010), p.848.

Google Scholar