Synthesis and Characterization of WO3/S Core/Shell Nanoparticles by Thermal Evaporation

Article Preview

Abstract:

WO3 has been widely applied in many fields such as electrochromic window, photocatalyst, and gas-senor. In this paper, WO3/S core/shell nanoparticles were synthesized in high density and large scale on silicon substrates via simple thermal evaporation of WO3 and S powders at 950 °C in a tube furnace. The morphology, composition and structure of the nanoparticles were characterized by scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, and energy dispersive X-ray spectroscopy. The results indicate that the nano-particles have a uniform morphology with a diameter in the range of 150-250 nm and well crystalline structure. The growth mechanism of the nanoparticles was also proposed.

You might also be interested in these eBooks

Info:

Periodical:

Key Engineering Materials (Volumes 602-603)

Pages:

51-54

Citation:

Online since:

March 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] H. Zheng, J.Z. Ou, M.S. Strano, et al, Nanostructured tungsten oxide–properties, synthesis, and applications, Adv. Funct. Mater. 21 (2011) 2175-2196.

DOI: 10.1002/adfm.201002477

Google Scholar

[2] M. Gillet, R. Delamare, E. Gillet, Growth, structure and electrical properties of tungsten oxide nanorods,  Eur. Phys. J. D 34 (2005) 291-294.

DOI: 10.1140/epjd/e2005-00161-2

Google Scholar

[3] Z. Liu, Y. Bando, C. Tang, Synthesis of tungsten oxide nanowires, Chem. Phys. Lett. 372 (2003) 179-182.

Google Scholar

[4] E.L. Miller, B. Marsen, B. Cole, et al, Low-temperature reactively sputtered tungsten oxide films for solar-powered water splitting applications, Electrochem. Solid-State Lett. 9 (2006) G248-G250.

DOI: 10.1149/1.2201994

Google Scholar

[5] J. Tamaki, A. Hayashi, Y. Yamamoto, et al, Detection of dilute nitrogen dioxide and thickness effect of tungsten oxide thin film sensors, Sensor. Actuat. B 95 (2003) 111-115.

DOI: 10.1016/s0925-4005(03)00417-9

Google Scholar

[6] C.J. Zhong, M. M Maye, Core–shell assembled nanoparticles as catalysts, Adv. Mater. 13 (2001) 1507-1511.

DOI: 10.1002/1521-4095(200110)13:19<1507::aid-adma1507>3.0.co;2-#

Google Scholar

[7] S. Gorer, R.M. Penner, Multipulse, electrochemical/chemical synthesis of CdS/S core/shell nanocrystals exhibiting ultranarrow photoluminescence emission lines, J. Phys. Chem. B. 103 (1999) 5750-5753.

DOI: 10.1021/jp991141u

Google Scholar

[8] L. Yuan, H. Yuan, X. Qiu, et al, Improvement of cycle property of sulfur-coated multi-walled carbon nanotubes composite cathode for lithium/sulfur batteries, J. Power Sources 189 (2009) 1141-1146.

DOI: 10.1016/j.jpowsour.2008.12.149

Google Scholar

[9] A. Zak, Y. Feldman, V. Alperovich, et al, Growth mechanism of MoS2 fullerene-like nanoparticles by gas-phase synthesis, J. Am. Chem. Soc. 122 (2000) 11108-11116.

DOI: 10.1021/ja002181a

Google Scholar

[10] Y. Baek, K. Yong, Controlled growth and characterization of tungsten oxide nanowires using thermal evaporation of WO3 powder, J. Phys. Chem. C. 111 (2007) 1213-1218.

DOI: 10.1021/jp0659857

Google Scholar