Improvement of Filler-Rubber Interaction by Grafting of Acrylamide onto Saponified Natural Rubber under Ultraviolet Radiation as a Continuous Process

Nattanee Dechnarong; Adun Nimpaiboon; Jitladda Sakdapipanich

doi:10.4028/www.scientific.net/KEM.659.414

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Functionalization of Styrene-Butadiene Rubber and Skim Latex by Photo-Catalytic Reaction Using Nanometric TiO₂ Film as a Photocatalyst
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Improvement of Filler-Rubber Interaction by Grafting of Acrylamide onto Saponified Natural Rubber under Ultraviolet Radiation as a Continuous Process
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HomeKey Engineering MaterialsKey Engineering Materials Vol. 659Improvement of Filler-Rubber Interaction by...

Improvement of Filler-Rubber Interaction by Grafting of Acrylamide onto Saponified Natural Rubber under Ultraviolet Radiation as a Continuous Process

Abstract:

Silica and carbon black have been widely used as the main reinforcing fillers for improving the properties of natural rubber (NR). In a silica-filled rubber compound, it is known that the low compatibility between NR and silica affects the mechanical properties of rubber products. In order to overcome this drawback, the functionalized saponified NR (FSPNR) was carried out by grafting acrylamide (AM) onto the saponified NR (SPNR) under UV radiation as a continuous process. An increasing in the bound rubber content and Mooney viscosity was found as an increasing AM content. Storage modulus at low strain amplitude of the silica-filled FSPNR was lower than that of the raw NR. In addition, SEM micrographs showed the good dispersion of silica in FSPNR. These confirmatory evidences indicate the improvement of rubber-filler interaction and the reduction of filler-filler interaction by functionalization under UV radiation.

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Periodical:

Key Engineering Materials (Volume 659)

Pages:

414-417

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.659.414

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Online since:

August 2015

Authors:

Nattanee Dechnarong, Adun Nimpaiboon, Jitladda Sakdapipanich*

Keywords:

Grafting by Uv Radiation, Natural Rubber, Rubber-Filler Interaction, Silica

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References

[1] J. Tangpakdee, M. Mizokoshi, A. Endo, Y. Tanaka, Novel Method for Preparation of Low Molecular Weight Natural Rubber Latex, Rubber Chemistry and Technology. 71 (1998) 795-802.

DOI: 10.5254/1.3538505

Google Scholar

[2] H. J. Chun, S. M. Cho, Y. M. Lee, H. K. Lee, T. S. Suh, K. S. Shinn , Graft copolymerization of mixtures of acrylic acid and acrylamide onto polypropylene film, Journal of Polymer Science. 72 (1999) 251-256.

DOI: 10.1002/(sici)1097-4628(19990411)72:2<251::aid-app10>3.0.co;2-v

Google Scholar

[3] N. Pukkate, T. Kitai, Y. Yamamoto, T. Kawazura, J. Sakdapipanich, S. Kawahara, Nano-matrix structure formed by graft-copolymerization of styrene onto natural rubber, European Polymer Journal. 43 (2007) 3208–3214.

DOI: 10.1016/j.eurpolymj.2007.04.037

Google Scholar

[4] A. Nimpaiboon, S. Amnuaypornsri, J. Sakdapipanich, Influence of gel content on the physical properties of unfilled and carbon black filled natural rubber vulcanizates, Polymer Testing. 32 (2013) 1135–1144.

DOI: 10.1016/j.polymertesting.2013.07.003

Google Scholar