Phase Formation, Microstructures and Mechanical Properties of Lead-Free BNKT Ferroelectric Ceramics Doped with BZZ

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In this research, the effects of bismuth zinc zirconate (BZZ) additive on phase formation, microstructural and mechanical properties of bismuth sodium potassium titanate (BNKT) ceramics were investigated. The BZZ-doped BNKT ceramics were prepared using solid state reaction technique. The pure phase of BZZ-doped BNKT powders were achieved for a calcinations temperature of 850 °C for 4h. The obtained powders were pressed into small pellets and sintered at optimum temperature to from dense ceramics. The XRD analysis of the ceramics shows that all ceramic samples exhibited a pure phase perovskite structure. The bulk densities of samples were about 5.82-6.03 g/cm3 which measured using the Archimedes method. The mechanical properties were measured using micro hardness tester. The microstructural of sintered surface was investigated using scanning electron microscopy (SEM). Average grain size increased with increasing BZZ content. The relations of these results were discussed and compared to the previous works.

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Key Engineering Materials (Volumes 675-676)

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589-592

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January 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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[1] Y. Guo, M. Gu, H. Luo, Y. Liu, and R. L. Withers, Composition-induced antiferroeletric phase and giant strain in lead-free (Nay, Biz)Ti1-xO3(1-x)-xBaTiO3 ceramics, Phys. Rev. B 83 (2011) 054118.

Google Scholar

[2] S. Manotham, C. Kruea-In, G. Rujijanagul, Properties of 0. 94Bi0. 5Na0. 5TiO3-0. 06BiAlO3 ceramics prepared by two steps sintering technique, Ferroelectrics 458 (2014) 152-157.

DOI: 10.1080/00150193.2013.850366

Google Scholar

[3] A. B. Kounga, S. T. Zhang, W. Jo, T. Granzow, J. Rödel, Morphotropic phase boundary in (1-x)Bi0. 5Na0. 5TiO3-xK0. 5Na0. 5NbO3 Lead-free piezoceramics, Appl. Phys. Lett. 92 (2008) 222902.

DOI: 10.1063/1.2938064

Google Scholar

[4] A. Ullah, C. W. Ahn, A. Hussain, I. W. Kim, The effect of sintering temperatures on dielectric, ferroelectric and electric field-induced strain of lead-free Bi0. 5(Na0. 78K0. 22)0. 5TiO3 piezoelectric ceramics synthesized by the sol-gel technique, Curr. Appl. Phys. 10 (2010).

DOI: 10.1016/j.cap.2010.05.004

Google Scholar

[5] A. Hussain, C. W. Ahn, J. S. Lee, A. Ullah, III W. Kim, Large electric-field-induced strain in Zr-modified lead-free Bi0. 5(Na0. 78K0. 22)0. 5TiO3 piezoelectric ceramics, Sensor. Actuat. A-Phys. 158 (2010) 84-89.

DOI: 10.1016/j.sna.2009.12.027

Google Scholar

[6] A. Ullah, C. W. Ahn, A. Hussain, S. Y. Lee, H. J. Lee, III W. Kim, Phase transitions and large electric field-induced strain in BiAlO3-modified Bi0. 5(Na, K)0. 5TiO3 lead-free piezoelectric ceramics. Curr. Appl. Phys. 10 (2010) 1174-1181.

DOI: 10.1016/j.cap.2010.02.006

Google Scholar

[7] A. Ullah, C. W. Ahn, S. Y. Lee, J. S. Kim, III W. Kim, Structure, ferroelectric properties, and electric field-induced large strain in lead-free Bi0. 5(Na, K)0. 5TiO3–(Bi0. 5La0. 5)AlO3 piezoelectric ceramics, Ceram. Int. 38 (2012) S363-S368.

DOI: 10.1016/j.ceramint.2011.05.013

Google Scholar

[8] B. H. Kim, S. J. Han, J. H. Kim, J. H. Lee, B. K. Ahn, Q. Xu, Electrical properties of (1-x)(Bi0. 5Na0. 5)TiO3-xBaTiO3 synthesized by emulsion method, Ceram. Int. 33 (2007) 447-452.

DOI: 10.1016/j.ceramint.2005.10.022

Google Scholar

[9] C. Wichasilp, S. Introng, W. Maithong, N. Kruea-In, C. Kruea-In, Synthesis and Characterization of BNKT/ZnO Ferroelectric Lead-free Nanocomposites, Adv. Mater. Res. 979 (2014) 232-235.

DOI: 10.4028/www.scientific.net/amr.979.232

Google Scholar