Paper Titles

Acid Attack Resistance of Magnesium Phosphate Cement
p.392

The Effect of Sample Storage and Inspection Equipment on the Rheological Property of Oil Well Cement
p.398

Chloride Ion Erosion in Concrete under Sustained Axial Pressure
p.402

Influence of Environmental Humidity and Test Depth on the Measured Gas Permeability of Concrete
p.406

Effect of Low Content of Metakaolin Addition on the Properties and Pore Structure of Concrete
p.411

Hydration Products, Microstructure and Durability of Concrete with Metakaolin Addition
p.420

Effect of Fly Ash Composition and Structure on the Formation of Cement Clinker
p.429

Effect of F-S Mineralizer on the Calcination of Recycled Cement Clinker Produced from Waste Concrete
p.435

Hydration Properties and Sulfate Attack of Composite Cement Mixed with High Titanium Slag
p.439

HomeKey Engineering MaterialsKey Engineering Materials Vol. 680Effect of Low Content of Metakaolin Addition on...

Effect of Low Content of Metakaolin Addition on the Properties and Pore Structure of Concrete

Article Preview

Abstract:

The properties and microstructure of concrete containing 0-6wt% metakaolin (MK) were studied by analytical techniques. The compressive strength increased with the content of MK and reached the maximum by 5wt% MK addition, where the compressive strength increased by 33% at 28 days comparing to the control. The pore structure was refined in the concrete containing MK due to the increase of amount of pores smaller than 10 nm. There is a relationship between average pore diameter and compressive strength.

You might also be interested in these eBooks

Properties and Testing Techniques of Inorganic Materials

Info:

Periodical:

Key Engineering Materials (Volume 680)

Pages:

411-419

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.680.411

Citation:

Cite this paper

Online since:

February 2016

Authors:

Hai Ning Geng, Qiu Li*, Zhi Guang Shi, Zhong He Shui

Keywords:

Compressive Strength, Hydration Products, Metakaolin, Pore Size Distribution, Portland Cement

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] C. He, B. Osbaeck, E. Makovicky, Pozzolanic reactions of six principal clay minerals: activation, reactivity assessments and technological effects, Cement and Concrete Research, 25 (1995) 1691-1702.

DOI: 10.1016/0008-8846(95)00165-4

[2] M. Murat, C. Comel, Hydration reaction and hardening of calcined clays and related minerals III. Influence of calcination process of kaolinite on mechanical strengths of hardened metakaolinite, Cement and Concrete Research, 13 (1983) 631-637.

DOI: 10.1016/0008-8846(83)90052-2

[3] M. Frias, O. Rodriguez Largo, R. Garcia Jimenez, I. Vegas, Influence of Activation Temperature on Reaction Kinetics in Recycled Clay Waste-Calcium Hydroxide Systems, Journal of the American Ceramic Society, 91 (2008) 4044-4051.

DOI: 10.1111/j.1551-2916.2008.02807.x

[4] A. Tironi, M.A. Trezza, E.F. Irassar, A.N. Scian, Thermal treatment of kaolin: effect on the pozzolanic activity, in: A.F. Armas (Ed. ) 11th International Congress on Metallurgy & Materials Sam/Conamet 20112012, pp.343-350.

DOI: 10.1016/j.mspro.2012.06.046

[5] A. Tironi, M.A. Trezza, A.N. Scian, E.F. Irassar, Assessment of pozzolanic activity of different calcined clays, Cement & Concrete Composites, 37 (2013) 319-327.

DOI: 10.1016/j.cemconcomp.2013.01.002

[6] C. Bich, J. Ambroise, J. Pera, Influence of degree of dehydroxylation on the pozzolanic activity of metakaolin, Applied Clay Science, 44 (2009) 194-200.

DOI: 10.1016/j.clay.2009.01.014

[7] B.B. Sabir, S. Wild, J. Bai, Metakaolin and calcined clays as pozzolans for concrete: a review, Cement & Concrete Composites, 23 (2001) 441-454.

DOI: 10.1016/s0958-9465(00)00092-5

[8] R. Fernandez, F. Martirena, K.L. Scrivener, The origin of the pozzolanic activity of calcined clay minerals: A comparison between kaolinite, illite and montmorillonite, Cement and Concrete Research, 41 (2011) 113-122.

DOI: 10.1016/j.cemconres.2010.09.013

[9] C.A. Love, I.G. Richardson, A.R. Brough, Composition and structure of C-S-H in white Portland cement-20% metakaolin pastes hydrated at 25 degrees C, Cement and Concrete Research, 37 (2007) 109-117.

DOI: 10.1016/j.cemconres.2006.11.012

[10] N.J. Coleman, W.R. McWhinnie, The solid state chemistry of metakaolin-blended ordinary Portland cement, Journal of Materials Science, 35 (2000) 2701-2710.

[11] M. Frias, The effect of metakaolin on the reaction products and microporosity in blended cement pastes submitted to long hydration time and high curing temperature, Advances in Cement Research, 18 (2006) 1-6.

DOI: 10.1680/adcr.2006.18.1.1

[12] M.S. Morsy, Y.A. Al-Salloum, H. Abbas, S.H. Alsayed, Behavior of blended cement mortars containing nano-metakaolin at elevated temperatures, Construction and Building Materials, 35 (2012) 900-905.

DOI: 10.1016/j.conbuildmat.2012.04.099

[13] M.S. Morsy, Effect of temperature on hydration kinetics and stability of hydration phases of metakaolin-lime sludge-silica fume system, Ceramics-Silikaty, 49 (2005) 237-241.

[14] W. Aquino, D.A. Lange, J. Olek, The influence of metakaolin and silica fume on the chemistry of alkali-silica reaction products, Cement & Concrete Composites, 23 (2001) 485-493.

DOI: 10.1016/s0958-9465(00)00096-2

[15] E. Gueneyisi, M. Gesoglu, K. Mermerdas, Improving strength, drying shrinkage, and pore structure of concrete using metakaolin, Materials and Structures, 41 (2008) 937-949.

DOI: 10.1617/s11527-007-9296-z

[16] Z. Shui, T. Sun, Z. Fu, G. Wang, Dominant Factors on the Early Hydration of Metakaolin-Cement Paste, Journal of Wuhan University of Technology-Materials Science Edition, 25 (2010) 849-852.

DOI: 10.1007/s11595-010-0106-z

[17] M. Frias, M.I.S. de Rojas, J. Cabrera, The effect that the pozzolanic reaction of metakaolin has on the heat evolution in metakaolin-cement mortars, Cement and Concrete Research, 30 (2000) 209-216.

DOI: 10.1016/s0008-8846(99)00231-8

[18] F. Cassagnabere, M. Mouret, G. Escadeillas, Early hydration of clinker-slag-metakaolin combination in steam curing conditions, relation with mechanical properties, Cement and Concrete Research, 39 (2009) 1164-1173.

DOI: 10.1016/j.cemconres.2009.07.023

[19] F. Cassagnabere, M. Mouret, G. Escadeillas, P. Broilliard, A. Bertrand, Metakaolin, a solution for the precast industry to limit the clinker content in concrete: Mechanical aspects, Construction and Building Materials, 24 (2010) 1109-1118.

DOI: 10.1016/j.conbuildmat.2009.12.032

[20] A. Tironi, M.A. Trezza, A.N. Scian, E.F. Irassar, Incorporation of calcined clays in mortars: porous structure and compressive strength, in: A.F. Armas (Ed. ) 11th International Congress on Metallurgy & Materials Sam/Conamet 20112012, pp.366-373.

DOI: 10.1016/j.mspro.2012.06.049

[21] F. Lagier, K.E. Kurtis, Influence of Portland cement composition on early age reactions with metakaolin, Cement and Concrete Research, 37 (2007) 1411-1417.

DOI: 10.1016/j.cemconres.2007.07.002

[22] E. -H. Kadri, S. Kenai, K. Ezziane, R. Siddique, G. De Schutter, Influence of metakaolin and silica fume on the heat of hydration and compressive strength development of mortar, Applied Clay Science, 53 (2011) 704-708.

DOI: 10.1016/j.clay.2011.06.008

[23] M. Frias, S. Martinez-Ramirez, Use of micro-Raman spectroscopy to study reaction kinetics in blended white cement pastes containing metakaolin, Journal of Raman Spectroscopy, 40 (2009) 2063-(2068).

DOI: 10.1002/jrs.2372

[24] F. Cassagnabere, G. Escadeillas, M. Mouret, Study of the reactivity of cement/metakaolin binders at early age for specific use in steam cured precast concrete, Construction and Building Materials, 23 (2009) 775-784.

DOI: 10.1016/j.conbuildmat.2008.02.022

[25] M.S. Morsy, S.H. Alsayed, Y.A. Salloum, Development of eco-friendly binder using metakaolin-fly ash-lime-anhydrous gypsum, Construction and Building Materials, 35 (2012) 772-777.

DOI: 10.1016/j.conbuildmat.2012.04.142

[26] M. Arikan, K. Sobolev, T. Ertuen, A. Yeginobali, P. Turker, Properties of blended cements with thermally activated kaolin, Construction and Building Materials, 23 (2009) 62-70.

DOI: 10.1016/j.conbuildmat.2008.02.008

[27] F. Cassagnabere, P. Diederich, M. Mouret, G. Escadeillas, M. Lachemi, Impact of metakaolin characteristics on the rheological properties of mortar in the fresh state, Cement & Concrete Composites, 37 (2013) 95-107.

DOI: 10.1016/j.cemconcomp.2012.12.001

[28] M. Antoni, J. Rossen, F. Martirena, K. Scrivener, Cement substitution by a combination of metakaolin and limestone, Cement and Concrete Research, 42 (2012) 1579-1589.

DOI: 10.1016/j.cemconres.2012.09.006

[29] M.A.M. Johari, J.J. Brooks, S. Kabir, P. Rivard, Influence of supplementary cementitious materials on engineering properties of high strength concrete, Construction and Building Materials, 25 (2011) 2639-2648.

DOI: 10.1016/j.conbuildmat.2010.12.013

[30] J.M. Justice, K.E. Kurtis, Influence of metakaolin surface area on properties of cement-based materials, Journal of Materials in Civil Engineering, 19 (2007) 762-771.

DOI: 10.1061/(asce)0899-1561(2007)19:9(762)

[31] J.M. Khatib, Metakaolin concrete at a low water to binder ratio, Construction and Building Materials, 22 (2008) 1691-1700.

DOI: 10.1016/j.conbuildmat.2007.06.003

[32] J.M. Khatib, Low Temperature Curing of Metakaolin Concrete, Journal of Materials in Civil Engineering, 21 (2009) 362-367.

DOI: 10.1061/(asce)0899-1561(2009)21:8(362)

[33] J.M. Khatib, S. Wild, Pore size distribution of metakaolin paste, Cement and Concrete Research, 26 (1996) 1545-1553.

DOI: 10.1016/0008-8846(96)00147-0

[34] M. Frias, J. Cabrera, Pore size distribution and degree of hydration of metakaolin-cement pastes, Cement and Concrete Research, 30 (2000) 561-569.

DOI: 10.1016/s0008-8846(00)00203-9

[35] E. Aggelakopoulou, A. Bakolas, A. Moropoulou, Properties of lime-metakolin mortars for the restoration of historic masonries, Applied Clay Science, 53 (2011) 15-19.

DOI: 10.1016/j.clay.2011.04.005

[36] M.F. Rojas, M.I.S. de Rojas, Influence of metastable hydrated phases on the pore size distribution and degree of hydration of MK-blended cements cured at 60 degrees C, Cement and Concrete Research, 35 (2005) 1292-1298.

DOI: 10.1016/j.cemconres.2004.10.038

[37] C.S. Poon, S.C. Kou, L. Lam, Compressive strength, chloride diffusivity and pore structure of high performance metakaolin and silica fume concrete, Construction and Building Materials, 20 (2006) 858-865.

DOI: 10.1016/j.conbuildmat.2005.07.001

[38] M. Frias, J. Cabrera, Influence of MK on the reaction kinetics in MK/lime and MK-blended cement systems at 20 degrees C, Cement and Concrete Research, 31 (2001) 519-527.

DOI: 10.1016/s0008-8846(00)00465-8

[39] M. Frias, R. Vigil de la Villa, M.I. Sanchez de Rojas, C. Medina, A. Juan Valdes, Scientific Aspects of Kaolinite Based Coal Mining Wastes in Pozzolan/Ca(OH)2 System, Journal of the American Ceramic Society, 95 (2012) 386-391.

DOI: 10.1111/j.1551-2916.2011.04985.x

[40] A. Gameiro, A. Santos Silva, R. Veiga, A. Velosa, Hydration products of lime-metakaolin pastes at ambient temperature with ageing, Thermochimica Acta, 535 (2012) 36-41.

DOI: 10.1016/j.tca.2012.02.013

[41] H. Zibara, R.D. Hooton, M.D.A. Thomas, K. Stanish, Influence of the C/S and C/A ratios of hydration products on the chloride ion binding capacity of lime-SF and lime-MK mixtures, Cement and Concrete Research, 38 (2008) 422-426.

DOI: 10.1016/j.cemconres.2007.08.024

[42] P. Duan, Z. Shui, W. Chen, C. Shen, Influence of metakaolin on pore structure-related properties and thermodynamic stability of hydrate phases of concrete in seawater environment, Construction and Building Materials, 36 (2012) 947-953.

DOI: 10.1016/j.conbuildmat.2012.06.073

[43] M. Kumar, S.K. Singh, N.P. Singh, N.B. Singh, Hydration of multicomponent composite cement: OPC-FA-SF-MK, Construction and Building Materials, 36 (2012) 681-686.

DOI: 10.1016/j.conbuildmat.2012.06.055