Morphological Studies on Microstructure of Thai Ancient Glass Beads

Article Preview

Abstract:

Various ancient glass beads in prehistorical - historical period (around 2500-1200 BP) from the collection of the Banraiprachasawan local museum (A. Pisalee, Nakhon Sawan) were studied to determine elemental compositions and morphologies using electron probe microanalysis (EPMA) and scanning electron microscopy/energy dispersive x-ray analysis (SEM/EDX). The colors of the beads range from blue to red brown. From the EPMA data, all beads contain copper in the glass matrices. The SEM/EDX showed differences in the microstructures of the glass beads. The transparent blue, greenish blue and light green beads contain small particles of tin oxide while the opaque orange or red brown beads contain both copper oxide and tin oxide particles. The forms of copper oxide in the orange and red brown beads were proposed from previous work: Cu2O in the orange glass and copper metal in the red brown glass.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

8-12

Citation:

Online since:

July 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] K. Won-in, Y. Thongkam, W. Dhammanonda, J. Dutchaneephet, T. Kamwanna, S. Intarasiri, et al., Characterization on mosaic glass excavated from Phu Khao Thong (Ranong), Thailand, Phys. Procedia 48 (2013) 30 – 37.

DOI: 10.1016/j.phpro.2013.07.006

Google Scholar

[2] K. Won-in, Y. Thongkam, W. Dhammanonda, J. Dutchaneephet, T. Kamwanna, S. Intarasiri, et al., Characterization on eye glass bead found at Khao Sri Vichai (Surat Thani), Thailand, Phys. Procedia 48 (2013) 23 – 29.

DOI: 10.1016/j.phpro.2013.07.005

Google Scholar

[3] K. Polikreti, J.M.A. Murphy, V. Kantarelou and A.G. Karydas, XRF analysis of glass beads from the Mycenaean palace of Nestor at Pylos, Peloponnesus, Greece: new insight into the LBA glass trade, J. Archaeol. Sci. 38 (2011) 2889-2896.

DOI: 10.1016/j.jas.2011.05.003

Google Scholar

[4] M. Verità, A. Renier and S. Zecchin, Chemical analyses of ancient glass findings excavated in the Venetian lagoon, J. Cult. Herit. 3 (2002) 261–271.

DOI: 10.1016/s1296-2074(02)01235-9

Google Scholar

[5] L. Dussubieux, B. Gratuze and M. Blet-Lemarquand, Mineral soda alumina glass: occurence and meaning. J. Archaeol. Sci. 37 (2010) 1646–1655.

DOI: 10.1016/j.jas.2010.01.025

Google Scholar

[6] M. Bertini, A. Shortland, K. Milek and E.M. Krupp, Investigation of Iron Age north-eastern Scottish glass beads using element analysis with LA-ICP-MS, J. Archaeol. Sci. 38 (2011) 2750-2766.

DOI: 10.1016/j.jas.2011.06.019

Google Scholar

[7] J. Lankton and L. Dussubieux, Early Glass in Asian Maritime Trade: A Review and an Interpretation of Compositional Analysis, J. Glass Stud. 48 (2006) 121-144.

Google Scholar

[8] J. Lankton and L. Dussubieux, Early Glass in Southeast Asia, in: K. Janssens (Eds. ), Modern Methods for Analysing Archaeological and Historic Glass, Wiley and Sons, West Sussex, 2013, pp.413-441.

DOI: 10.1002/9781118314234.ch20

Google Scholar

[9] Y. Lei and Y. Xia, Study on production techniques and provenance of faience beads excavated in China, J. Archaeol. Sci. 53 (2015) 32-42.

DOI: 10.1016/j.jas.2014.09.019

Google Scholar

[10] M.B. Toffolo, E. Klein, R. Elbaum, A.J. Aja, D.M. Master and E. Boaretto, An early Iron Age assemblage of faience beads from Ashkelon, Israel: chemical composition and manufacturing process, J. Archaeol. Sci. 40 (2013) 3626-3635.

DOI: 10.1016/j.jas.2013.05.010

Google Scholar

[11] A. Silvestri, S. Tonietto, F. D'Acapito and G. Molin, The role of copper on colour of palaeo-Christian glass mosaic tesserae: An XAS study, J. Cult. Herit. 13 (2012) 137–144.

DOI: 10.1016/j.culher.2011.08.002

Google Scholar

[12] A.A. Ahmed, G.M. Ashour and T.M. El-Shamy, Effect of melting conditions on the crystallization of cuprous oxide and copper in glass, Proc. XIth Int. Cong. Glass (Prague) 2 (1977) 177–187.

Google Scholar