Effect of Additives and Carbon Resources on Thermal Shock Resistance of Spinel-C Material

Article Preview

Abstract:

Spinel-C material is important for monolithic stopper and submerged nozzle, which usually determine the application effects. Spinel-C specimens with 8% flake graphite is characterized by good corrosion resistance but poor thermal shock resistance. The effects of additives (Al-Si alloy, silicon powder, B4C and SiC), flake graphite (+199/-199), ultrafine flake graphite, expanded graphite and nickel nitrate + pitch powder on thermal shock resistance of spinel-C material were investigated by using water-quenching method. The results show that: (1) The addition of Al-Si alloy and B4C can significantly decrease the residual strength ratios (RSR) of the specimens. The addition of SiC and silicon powder can improve the RSR obviously. (2) The flake graphite of different particle sizes has little effect on the RSR of the specimens. With the increasing of the expanded graphite content, the RSR of the specimens increases. (3) The addition of mesophase pitch and Carboresâ P can receive the RSR rise of 74% and 59% respectively.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

440-444

Citation:

Online since:

January 2017

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Li XM, Fan JM, Zhao HQ, Effect of boron carbide on properties of aluminum carbon and zirconium carbon nozzle, in: Li DY, Applied technology of auxiliary material for steelmaking, Metallurgy Industry Press. Peking, 2003. pp.35-36.

Google Scholar

[2] Sun Y, Yu JK, Effect of B4C and SiC additives on properties of alumina carbon refractories, J. Refractories. 41 (2007) 156-158.

Google Scholar

[3] Liu DY, Xu N, Study on the oxidation of boron in silicate glass, J. East china science & technology. 2013: 472-472.

Google Scholar

[4] Wang JZ, Zhao JX, Zhang HX, Effect of carbon resources on properties and microstructure of Al2O3-C materials, J. Bulletin of the Chinese ceramic society. 32 (2013) 844-846+851.

Google Scholar

[5] Zhu TB, Li YW, Sang SB, Effect of expanded graphite on microstructure and properties of MgO-C refractories, J. Bulletin of the Chinese ceramic society. 34 (2015) 2436-2441.

Google Scholar

[6] Zhang XS, Cheng Y, Shui HF, Mesophase pitch-phenolic resin binder for MgO-C brick, J. Refractories. 41 (2007) 271-273.

Google Scholar

[7] Li SQ, Zhao L, Li YW, Newly-developed carbonaceous binder for carbon-containing refractories: a comparative analysis, J. Journal of wuhan university of science and technology. 30 (2007) 484-487.

Google Scholar