The Behavior of Portland Limestone-Calcined Clays Cement at 5°C

Article Preview

Abstract:

The effect of calcined clays of the swelling type, on the strength and expansion behavior of Portland limestone cement is studied at 5°C. Local clays were thermally activated by burning one hour at 900 °C and were ground to a Blaine of 2842 (cm2/g). The pozzolanic reactivity of the activated clays was defined chemically and according to ASTM C311/C311M-13. Portland limestone cement was prepared by replacing 30% CEM I 42.5 N by limestone powder. Pozzolanic cements were prepared by replacing 10 and 20% of the limestone powder by calcined clays, the mixes were used to replace 30% of CEM I. Mortars specimens pre-cured for 28-day long as well as for a short period of one day, were immersed in sulfate solutions at 5°C for time up to 90 days. The compressive strength and length change were measured for the samples.The results show that replacement of limestone with calcined clays improves the compressive strength and the expansion of Portland limestone cement mortars in water and sulfate solutions. Ettringite was detected in the expanded mortars and no thaumasite formed. The results are interpreted in terms of the mechanism of thaumasite formation.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

135-143

Citation:

Online since:

January 2018

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] R. Feret, Additions des matieres pulverulentes aux liants hydrauliquess, Annls Ponts Chauss 92 (1925) Paris.

Google Scholar

[2] H. Y. Ghorab, A. M. K. Abdel Alim and O. M. Ahmed, Hardening characteristics of some clay minerals. Zement Kalk Gips, 11 (1991) 578-583.

Google Scholar

[3] Calcined Clays for Sustainable Concrete: Proceedings of the 1st International Conference on Calcined Clays for Sustainable Concrete (2015).

DOI: 10.1007/978-94-017-9939-3_69

Google Scholar

[4] Portland limestone calcined clay cement. Patent EP2253600A1. Publication date Ni 24, (2010).

Google Scholar

[5] K. C. Thienel, N Beuntner, Ökologisch und technisch verbesserte Betone durch den Einsatz alternativer Zusatzstoffe: Nachhaltigkeit und Innovation. (2013).

Google Scholar

[6] N. Beuntner - Innovationen in Beton–1. Leistungsfähigkeit großtechnisch calcinierter Tone und deren Wirksamkeit in zementären Systemen DAfStb-Jahrestagungmit. (2013)- unibw. de.

Google Scholar

[7] M.P. Javellana, I. Jawed. Extraction of free lime in Portland cement and clinker by ethylene glycol. Cement and Concrete Research. 12 (1982) 399-403.

DOI: 10.1016/0008-8846(82)90088-6

Google Scholar

[8] A. Yahia. M. Taminura, Y. Shimoyama, Rheological properties of highly flowable mortar containing limestone filler-effect of powder content and w/c ratio. Cement and Concrete Research 35 (3) (2005) 532–539. Doi org/10 016/ cemconres. 2004. 05 008.

DOI: 10.1016/j.cemconres.2004.05.008

Google Scholar

[9] H.Y. Ghorab, I.M. Kenawi, Z. G. Abdel All, Interaction between cements and superplasticizers Materiales de Construccion 62 (307) (2012) 359-380.

Google Scholar

[10] H. Basset, Notes on the system lime water on the determination of calcium. J. Chem. Soc. (1934) 1270-1275.

Google Scholar

[11] R. Wiebe, V. L. Gaddy, The solubility of carbon dioxide in water at various temperatures from 12 to 40oC and at pressures to 500 atmospheres. Critical phenomena, J. Am. Chem. Soc., 62 (4) (1940) 815–817. DOI: 10. 1021/ja01861a033.

DOI: 10.1021/ja01861a033

Google Scholar

[12] H. Y. Ghorab, F. Zahran, M. K. Mohamed. A. S. Meawad. On the durability of Portland limestone cement: effect of pH on the thaumasite formation HBRC Journal (accepted, in press).

DOI: 10.1016/j.hbrcj.2017.04.002

Google Scholar

[13] M. K Mohamed, Investigations on the thaumasite formation in cement systems. M. Sc. Thesis. Helwan University Cairo Egypt. (2017).

Google Scholar

[14] J. Bensted, Thaumasite–direct, woodfordite and other possible formation routes Cement and Concrete Composites. 25 (2003): 873–877.

DOI: 10.1016/s0958-9465(03)00115-x

Google Scholar

[15] H.Y. Ghorab, A.M., Zayed, A.S. Mohamed, M.R. Mabrouk. The Formation of the ettringite from sulfate solutions. 12th International Congress on the Chemistry of Cement (ICCC). Montreal, Canada. (2007) W4-09. 3.

Google Scholar

[16] A.S. Mohamed, Studies on the expansion behavior of the ettringite in pure systems and its application in cement mortars and concrete, M. Sc. Thesis, Helwan University Cairo Egypt (2006).

Google Scholar

[17] H.Y. Ghorab; On the Chemistry of the Delayed Ettringite Formation, RILEM TC 186-ISA, Lausanne Switzerland, (2002), 65-71.

Google Scholar