Effect of the Addition of ZrSiO4 on Alkali-Resistance and Liquidus Temperature of Basaltic Glass

Napaporn Vaiborisut; Chanittha Chunwises; Dararat Boonbundit; Sirithan Jiemsirilers; Apirat Theerapapvisetpong

doi:10.4028/www.scientific.net/KEM.766.145

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HomeKey Engineering MaterialsKey Engineering Materials Vol. 766Effect of the Addition of ZrSiO4 on...

Effect of the Addition of ZrSiO₄ on Alkali-Resistance and Liquidus Temperature of Basaltic Glass

Abstract:

Basalt fiber has been used as a reinforced material in cement-based materials because it has higher mechanical strength and cheaper than common silicate based glass-fibers. However, silicate-based glass fibers have low alkali resistance especially in cement matrix composite. In this work, we studied the improvement of alkali resistance by addition of zirconium silicate (ZrSiO₄) in original basalt glass composition. The batch of basalt glass with additional ZrSiO₄ contents of 0.00, 2.50, 5.00, 7.50 and 10.00 wt% were melted at 1500 °C. The liquidus temperature (T_L) is important in for the fiber glass manufacturing. It need to formulate glass composition which requires a lower melting temperature and is crystallization resistant. T_L as a function of composition is usually determined experimentally. In this study, glassy phase was determined by X-ray Diffraction (XRD). The glass transition temperature (T_g), the crystallization temperature (T_c) and T_L were analyzed by Differential Thermal Analysis (DTA). The results found that the addition of ZrSiO₄ in a basalt glass batch increased T_g while T_c of each sample was closed to original basalt fiber. Moreover, the alkali resistance of these glasses increased with an increasing of ZrSiO₄ content. However, excessive ZrSiO₄ contents (7.50 and 10.00 wt%) resulted in crystallization of ZrO₂ which separated from glassy phase.

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Periodical:

Key Engineering Materials (Volume 766)

Pages:

145-150

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.766.145

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April 2018

Authors:

Napaporn Vaiborisut, Chanittha Chunwises, Dararat Boonbundit, Sirithan Jiemsirilers, Apirat Theerapapvisetpong*

Keywords:

Basaltic Glasses, Liquidus Temperature, Zirconium Silicate

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