Preparation and Characterization of an Emulsion Paint Based on Arghel Extract as an Eco-Friendly Corrosion Inhibitor

Article Preview

Abstract:

Corrosion control of metals is of technical, economical, environmental, and aesthetical importance. The use of inhibitors is one of the best options of protecting metals and alloys against corrosion globally. The environmental toxicity of organic corrosion inhibitors has prompted the search for green corrosion inhibitors which do not contain heavy metals or other toxic compounds. In addition to being environmentally friendly, plant products are inexpensive, readily available and renewable. With the growth of the green movement, it is important to prepare environmentally friendly anticorrosive paints to save lot of money, which are lost each year because of corrosion. This study utilized optical measurements, electrochemical impedance spectroscopy (EIS) analysis, scanning electron microscope (SEM) analysis, immersion test in artificial sea water and morphology observations of Arghel extract (AE) as Eco-friendly corrosion inhibitor incorporated in (styrene-acrylic) emulsion paint. In addition Physical, Chemical and Mechanical Properties of dry paint films of the paint test has been done in absence and presence of the corrosion inhibitor. We found that (styrene-acrylic) emulsion paint with 75ppm AE (SP2) has the best performance in protecting mild steel from corrosion.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

149-158

Citation:

Online since:

October 2018

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Sastri VS. Green Corrosion Inhibitors, Theory and Practice, John Wiley & Sons:Hoboken, NJ; (1998).

Google Scholar

[2] Sastri Vs. Corrosion Inhibitors Principles and Applications, John Wiley & Sons: NewYork,(1998).

Google Scholar

[3] Rafael Martinez Palou1, Octavio Olivares-Xomelt2 and Natalya V. Likhanova11Instituto Mexicano del Petróleo, Dirección de Investigación y Posgrado, México, México2 Benemérita Universidad Autónoma de Puebla, Facultad de IngenieríaQuímica, Puebla,México.

DOI: 10.24850/j-tyca-14-6-7

Google Scholar

[4] A. M. Abdel-Gaber, E. Khamis and A. Hefnawy Utilizing Arghel extract as corrosion inhibitor for reinforced steel in concrete (2011), 62, No. 12.

DOI: 10.1002/maco.201005653

Google Scholar

[5] G.K. van der Wel, O.C.G. Adan, Moisture in organic coatings a review, Prog.Org. Coat. 37, (1999).

Google Scholar

[6] B. Vengadaesvaran, S.R. Rau, R. Kasi, a. K. Arof, Evaluation of heat resistantproperties of silicone-acrylic polyol coating by electrochemical methods, Pigment Resin Technol, 42, (2013).

DOI: 10.1108/03699421311301106

Google Scholar

[7] E.A. Papaj, D.J. Mills, S.S. Jamali, Effect of hardener variation on protectiveproperties of polyurethane coating, Prog. Org. Coat, 77, (2014).

Google Scholar

[8] A.C. Balaskas, I.A. Kartsonakis, L.-A. Tziveleka, G.C. Kordas, Improvement ofanti-corrosive properties of epoxy-coated AA 2024-T3 with TiO2 nanocontainers loaded with 8-hydroxyquinoline, Prog. Org. Coat,74,(2012),418–426.

DOI: 10.1016/j.porgcoat.2012.01.005

Google Scholar

[9] S. Sathiyanarayanan, S.S. Azim, G.Venkatachari, A new corrosion protectioncoating with polyaniline–TiO2 composite for steel, Electrochim. Acta,52,(2007), 2068–(2074).

DOI: 10.1016/j.electacta.2006.08.022

Google Scholar

[10] Y. Dong, Q. Zhou, Relationship between ion transport and the failure behavior of epoxy resin coatings, Corros. Sci.,78, (2014),22–28.

DOI: 10.1016/j.corsci.2013.08.017

Google Scholar

[11] F. Mansfeld, Electrochemical impedance spectroscopy (EIS) as new tool forinvestigating methods of corrosion protection, Electrochim. Acta, 35, (1990),1533.

DOI: 10.1016/0013-4686(90)80007-b

Google Scholar

[12] J. Bisquert, G. Garcia-Belmonte, F. Fabregat-Santiago, P.R. Bueno, Theoreticalmodels for ac impedance of finite diffusion layers exhibiting low frequencydispersion, J. Electroanal. Chem. 475, (1999), 152–163.

DOI: 10.1016/s0022-0728(99)00346-0

Google Scholar

[13] D. Weng, P. Jokiel, A. Uebleis, H. Boehni, Corrosion and protectioncharacteristics of zinc and manganese phosphate coatings, Surf. Coat. Technol,88, (1997),147.

DOI: 10.1016/s0257-8972(96)02860-5

Google Scholar

[14] A. M.Fekry and R. R. Mohamed,Acetyl thiourea chitosan as an eco-friendly inhibitor for mild steel in sulphuric acid medium,Electrochim. Acta, (2010), 55, 1933–(1939).

DOI: 10.1016/j.electacta.2009.11.011

Google Scholar

[15] D. Schmidt, B. Shaw, E. Sikora, W. Shaw, L. Laliberte, Corrosion,63,(2007), 958-974.

Google Scholar

[16] J.M. Yeh, K.C. Chang, Polymer/layered silicate nanocomposite anticorrosivecoatings, J. Ind. Eng. Chem, 14 ,3,(2008), 275–291.

Google Scholar