New Kinetic Model of Polyaddition of Asymmetric ABВ/ Monomer in the Presence of Trifunctional Core with Substitution Effect

Sergei V. Karpov; A.G. Iakunkov; Georgiy V. Malkov

doi:10.4028/www.scientific.net/KEM.816.339

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HomeKey Engineering MaterialsKey Engineering Materials Vol. 816New Kinetic Model of Polyaddition of Asymmetric...

New Kinetic Model of Polyaddition of Asymmetric ABВ/ Monomer in the Presence of Trifunctional Core with Substitution Effect

Abstract:

Three-dimensional step polymerization of ABB^/ and В₃ monomers (ABB^/+В₃) was described using the new structural-kinetic model. Polymerization process was simulated with the variation of reactivity of B groups in the ABB^/ and B₃ monomers during the process (substitution effect). Polymerization simulation with substitution effect represents the most general case of three-dimensional step polymerization ABB^/+В₃.

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Periodical:

Key Engineering Materials (Volume 816)

Pages:

339-344

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.816.339

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Online since:

August 2019

Authors:

Sergei V. Karpov*, A.G. Iakunkov, Georgiy V. Malkov

Keywords:

Asymmetrical Monomer ABB/, Degree of Branching, Hyperbranched Polymers, Kinetic Analysis, Molecular Weight Parameters, Trifunctional Core

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