Application of the Method of X-Ray Fluorescence Analysis to Determine the Composition of Glassy and Crystalline Alloys of the Systems As_xS_1-x and As_xSe_1-x

Abstract:

The article presents an X-ray fluorescence analysis of chalcogenide glassy semiconductors. The standard method is applied to determine the concentration of arsenic, selenium, and sulfur in alloys. This technique, the quantitative composition of the glasses is defined with an accuracy of ± 0.0002.

• Periodical: Key Engineering Materials (Volume 836)
• Pages: 97-103
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.836.97
• Online since: March 2020
• Authors: Alena Yu. Egorova, Elena S. Lomakina*
• Keywords: Chalcogenide Glassy Semiconductors, Spectra, Standard Method, X-Ray Fluorescence Analysis

References

[1] A. Marchenko, A. Dashina, I. Dzemidko, M. Kozhokar, Determination of Composition of Chalcogenide Glasses and Films by X-ray Fluorescence Spectroscopy, News of the Russ. State Pedagog. Univer. 138 (2011) 45–54.

[2] K. Paima, T. Rabchanova, A. Rasnyuk, P. Seregin, Dependence of Fine Structure of Fluorescence Spectrum Glasses AsxSe1-x, Excited By X-Ray, Bremsstrahlung on the Parameters of the X-Ray Tube, News of the Russ. State Pedagog. Univer. 173 (2015) 45–50.

[3] V.I. Bolobov, V.V., Gabov I.M. Gembitskaya et al., To the Application of the Method of X-ray Fluorescence Spectroscopy to Determine the Steel Grade of a Rock Cutting Tool, Notes of the Mining Instit. 178 (2008) 173–174.

[4] N.K. Kondrasheva, V.A. Rudko, V.G. Povarov, Determination of Sulfur and Trace Elements in Petroleum Coke by X-ray Fluorescent Spectrometry, Coke and Chemistry 60(6) (2017) 247–253.

DOI: 10.3103/s1068364x17060035

[5] G.A. Bordovskiy, A.V. Marchenko, M.Yu. Kozhokar et al., Determination of the Composition of Multicomponent Chalcogenide Glassy Semiconductors by X-ray Fluorescence Analysis, Phys. and Chemistry of Glass. 39(4) (2013) 545–552.

DOI: 10.1134/s1087659613040056

[6] S.A. Kozyukhin, T.A. Kupriyanova, A.I. Vargunin, Molecular Structure of AsxSe100-x Glasses Studied by X-ray Spectroscopy, Inorganic Mater. 43(8) (2007) 897–900.

DOI: 10.1134/s0020168507080146

[7] V.I. Nalivaiko, Nanostructured Layers of Chalcogenide Semicomductors – Structure, Optical Properties, Application, Geo-Siberia 5(1) (2009) 210–214.

[8] V.V. Maksarov, V.E. Makhov, Studying parameters and quality of thread by optical light field recorder, IOP Conf. Ser. Earth and Environmental Sci. vol. 194, no. 062017, 6 p., (2018).

DOI: 10.1088/1755-1315/194/6/062017

[9] L.B. Alekseeva, V.V. Maksarov, Evaluation of effect of oil film of rotor bearing, Int. Conf. on Mechan. Engineer., Automat. and Control Syst. (MEACS), vol. 327, no. 022003, 2 p., (2018).

DOI: 10.1088/1757-899x/327/2/022003

[10] V.V. Maksarov, J. Olt, V.A. Krasnyy, Investigation of wear resistance of bearing units engines of mining dump trucks operating in conditions of fretting corrosion, J. of Mining Instit. 235 (2019) 77–83.

DOI: 10.31897/pmi.2019.1.70

[11] E.I. Terukov, P.P. Seregin, A.V. Marchenko et al., X-ray Fluorescence Analysis of Ge1–xSex, As1–xSex, and Ge1–x–yAsySex Glasses Using Electronic Excitation (Article), Semiconductors 49(10) (2015) 1352–1356.

DOI: 10.1134/s1063782615100255

[12] G.A. Bordovsky, A.V. Marchenko, P.P. Seregin, K.U. Bobokhuzhaev, X-Ray Fluorescence Analysis of Ge-As-Se Glasses Using X-Ray and Electron-beam Excitation, Inorganic Mater. 51(9) (2015) 939–943.

DOI: 10.1134/s0020168515080063

[13] A.V. Marchenko, K.U. Bobokhuzhaev, A.V. Nikolaeva et al., X-ray Fluorescence Analysis of Chalcogenide Glass with Electron Beam Fluorescence Excitation, Glass Phys. and Chem. 41(5) (2015) 474–477.

DOI: 10.1134/s1087659615050089

[14] Bordovskii, G.A. Marchenko, A.V. Nikolaeva et al., Determination of the Composition of Multicomponent Chalcogenide Semiconductors by X-ray Fluorescence Analysis, Semiconductors 48(2) (2014) 257–262.

DOI: 10.1134/s1063782614020055

[15] G.A. Bordovskii, A.V. Marchenko, M.Y. Kozhokar et al., Composition Determination of Multicomponent Chalcogenide Glassy Semiconductors with X-ray Fluorescence Analysis, Glass Phys. and Chem. 39(4) (2013) 377–381.

DOI: 10.1134/s1087659613040056

[16] G.A. Bordovsky, A.V. Marchenko, P.P. Seregin et al., Determination of the Composition of Binary Chalcogenide Glasses by X-ray Fluorescence Analysis, Semiconductors 44(1) (2010) 24–27.

DOI: 10.1134/s1063782610010021

[17] G.A. Bordovskii, P.V. Gladkikh, I.V. Eremin et al., X-ray Fluorescence Analysis of the Composition of As-Ge-Se Glasses and Films, Technical Phys. Letters 37(3) (2011) 250–252.

DOI: 10.1134/s1063785011030199