Paper Titles

Activity of Ni-NH₂/Mesoporous Silica Material as Bifunctional Catalyst for Hydrocracking of Used Cooking Oil
p.83

Recovery of Au(III) from Gold Mining Rock with Silica/Chitosan Coated on Iron Sand Magnetic Material
p.90

Upgrading Methane Purity in Biogas Plant Gamping by Using Carbon-Based Molecular Sieve
p.98

The Effect of Biogas Purification Using Biochar from Biogas Waste on Biogas Combustion
p.104

Hydrodeoxygenation of Anisole and Benzaldehyde Over Bifunctional CoMo/USY Catalyst
p.109

Effects of the Molar Ratio of Acetic Acid to UFA and Stirring Velocity in the Tung Oil Epoxidation
p.117

The Effect of Glycerol on Alginate/Zeolite Membranes for Selectivity of CH₄/CO₂ Gas
p.125

Extraction Behavior of Trivalent Rare Earth Metal Ions with Diphosphonic Acid Type Extraction Reagent
p.133

Conversion of Nyamplung Oil (Calophyllum inophyllum L.) into Liquid Fuel by Hydrocracking Process Using NiMo/γ-Al₂O₃ Bimetallic Based Catalyst
p.140

HomeKey Engineering MaterialsKey Engineering Materials Vol. 884Hydrodeoxygenation of Anisole and Benzaldehyde...

Hydrodeoxygenation of Anisole and Benzaldehyde Over Bifunctional CoMo/USY Catalyst

Article Preview

Abstract:

Hydrodeoxygenation (HDO) of anisole and Benzaldehyde over bifunctional zeolite USY (ultra-stable Y) supported CoMo catalysts has been studied. The catalyst consisted of metals that Co and Mo were loaded at three different sequences; Co loaded first (Co-Mo/USY), Mo loaded first (Mo-Co/USY), and simultaneously loaded (CoMo/USY). The experiments were conducted in a flow reactor within a temperature of 350 °C for an hour. The oxygen-free products from the HDO process were benzene and toluene compounds. CoMo/USY catalyst exhibited the best catalytic activity of anisole towards the total production of aromatic hydrocarbons yield by 9.17%. It was also found that Mo-Co/USY catalyst exhibited the best catalytic activity of Benzaldehyde with aromatic hydrocarbons yield by 10.46%.

You might also be interested in these eBooks

Symposium of Materials Science and Chemistry III

Info:

Periodical:

Key Engineering Materials (Volume 884)

Pages:

109-116

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.884.109

Citation:

Cite this paper

Online since:

May 2021

Authors:

Khoirina Dwi Nugrahaningtyas*, Eddy Heraldy, Ferdinand Tri Aji Pamungkas, Aji Gusti

Keywords:

Anisole, Benzaldehide, CoMo/USY, Hydrodeoxygenation

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2021 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Y. Dahman, K. Syed, S. Begum, P. Roy, B. Mohtasebi, Biofuels: Their characteristics and analysis, in: D. Verma, E. Fortunati, S. Jain, X. Zhang (Eds.), Biomass, Biopolym. Mater. Bioenergy, Woodhead Publishing, Cambridge, 2019: p.277–325.

DOI: 10.1016/b978-0-08-102426-3.00014-x

[2] Y. Huang, L. Wei, X. Zhao, S. Cheng, J. Julson, Y. Cao, Z. Gu, Upgrading pine sawdust pyrolysis oil to green biofuels by HDO over zinc-assisted Pd/C catalyst, Energy Convers. Manag. 115 (2016) 8–16.

DOI: 10.1016/j.enconman.2016.02.049

[3] C. González, P. Marín, F. V. Díez, S. Ordóñez, Gas-Phase Hydrodeoxygenation of Benzaldehyde, Benzyl Alcohol, Phenyl Acetate, and Anisole over Precious Metal Catalysts, Ind. Eng. Chem. Res. (2016).

DOI: 10.1021/acs.iecr.6b00036

[4] S. Czernik, A. V. Bridgwater, Overview of Applications of Biomass Fast Pyrolysis Oil, Energy & Fuels. 18 (2004) 590–598.

DOI: 10.1021/ef034067u

[5] Q. Zhang, J. Chang, T. Wang, Y. Xu, Review of biomass pyrolysis oil properties and upgrading research, Energy Convers. Manag. 48 (2007) 87–92.

DOI: 10.1016/j.enconman.2006.05.010

[6] A. Imran, E.A. Bramer, K. Seshan, G. Brem, High quality bio-oil from catalytic flash pyrolysis of lignocellulosic biomass over alumina-supported sodium carbonate, Fuel Process. Technol. 127 (2014) 72–79.

DOI: 10.1016/j.fuproc.2014.06.011

[7] M. Li, X. Wang, N. Perret, M.A. Keane, Enhanced production of benzyl alcohol in the gas phase continuous hydrogenation of benzaldehyde over Au / Al 2 O 3 ( A ), CATCOM. 46 (2014) 187–191.

DOI: 10.1016/j.catcom.2013.12.024

[8] X. Kong, L. Chen, Hydrogenation of aromatic aldehydes to aromatic hydrocarbons over Cu-HZSM-5 catalyst, CATCOM. 57 (2014) 45–49.

DOI: 10.1016/j.catcom.2014.07.038

[9] A.M.H. Rasmussen, B. Hammer, Adsorption , mobility , and dimerization of benzaldehyde on Pt ( 111 ), 174706 (2012) 1–10.

DOI: 10.1063/1.4707952

[10] D. Shi, J.M. Vohs, Lignin-derived oxygenate reforming on a bimetallic surface: The reaction of benzaldehyde on Zn/Pt(111), Surf. Sci. (2016).

DOI: 10.1016/j.susc.2015.10.015

[11] J. Zhang, B. Fidalgo, A. Kolios, D. Shen, S. Gu, Mechanism of deoxygenation in anisole decomposition over single-metal loaded HZSM-5: Experimental study, Chem. Eng. J. 336 (2018) 211–222.

DOI: 10.1016/j.cej.2017.11.128

[12] J. Zhang, B. Fidalgo, S. Wagland, D. Shen, X. Zhang, S. Gu, Deoxygenation in anisole decomposition over bimetallic catalysts supported on HZSM-5, Fuel. 238 (2019) 257–266.

DOI: 10.1016/j.fuel.2018.10.129

[13] X. Zhu, L.L. Lobban, R.G. Mallinson, D.E. Resasco, Bifunctional transalkylation and hydrodeoxygenation of anisole over a Pt / HBeta catalyst, J. Catal. 281 (2011) 21–29.

DOI: 10.1016/j.jcat.2011.03.030

[14] X. Zhu, R.G. Mallinson, D.E. Resasco, Role of transalkylation reactions in the conversion of anisole over HZSM-5, Appl. Catal. A Gen. 379 (2010) 172–181.

DOI: 10.1016/j.apcata.2010.03.018

[15] K.A. Rogers, Y. Zheng, Selective Deoxygenation of Biomass-Derived Bio-oils within Hydrogen-Modest Environments: A Review and New Insights, ChemSusChem. 9 (2016) 1750–1772.

DOI: 10.1002/cssc.201600144

[16] M. Asadieraghi, W.M.A. Wan Daud, H.F. Abbas, Model compound approach to design process and select catalysts for in-situ bio-oil upgrading, Renew. Sustain. Energy Rev. 36 (2014) 286–303.

DOI: 10.1016/j.rser.2014.04.050

[17] A.A. Philippov, A.M. Chibiryaev, O.N. Martyanov, Raney® nickel-catalyzed hydrodeoxygenation and dearomatization under transfer hydrogenation conditions—Reaction pathways of non-phenolic compounds, Catal. Today. (2019) 0–1.

DOI: 10.1016/j.cattod.2019.05.033

[18] J. wei Zhang, K. kang Sun, D. dan Li, T. Deng, G. ping Lu, C. Cai, Pd-Ni bimetallic nanoparticles supported on active carbon as an efficient catalyst for hydrodeoxygenation of aldehydes, Appl. Catal. A Gen. 569 (2019) 190–195.

DOI: 10.1016/j.apcata.2018.10.038

[19] A. Ausavasukhi, T. Sooknoi, D.E. Resasco, Catalytic deoxygenation of benzaldehyde over gallium-modified ZSM-5 zeolite, J. Catal. 268 (2009) 68–78.

DOI: 10.1016/j.jcat.2009.09.002

[20] D. Almeida, M.D.F. Marques, Thermal and catalytic pyrolysis of plastic waste, 26 (2016) 44–51.

[21] E.N. Vlasova, G.A. Bukhtiyarova, I. V. Deliy, P. V. Aleksandrov, A.A. Porsin, M.A. Panafidin, E.Y. Gerasimov, V.I. Bukhtiyarov, The effect of rapeseed oil and carbon monoxide on SRGO hydrotreating over sulfide CoMo/Al2O3 and NiMo/Al2O3 catalysts, Catal. Today. (2019).

DOI: 10.1016/j.cattod.2019.06.011

[22] K. Li, R. Wang, J. Chen, Hydrodeoxygenation of Anisole over Silica-Supported Ni 2 P , MoP , and NiMoP Catalysts, (2011) 854–863.

DOI: 10.1021/ef101258j

[23] T. Viljava, R.S. Komulainen, A.O.I. Krause, Effect of H 2 S on the stability of CoMo / Al 2 O 3 catalysts during hydrodeoxygenation, 60 (2000) 83–92.

DOI: 10.1016/s0920-5861(00)00320-5

[24] V.O.O. Goncalves, S. Brunet, F. Richard, Hydrodeoxygenation of Cresols Over Mo/Al2O3 and CoMo/Al2O3 Sulfided Catalysts, Catal. Letters. 146 (2016) 1562–1573.

DOI: 10.1007/s10562-016-1787-5

[25] Y. Romero, F. Richard, S. Brunet, Hydrodeoxygenation of 2-ethylphenol as a model compound of bio-crude over sulfided Mo-based catalysts: Promoting effect and reaction mechanism, Appl. Catal. B Environ. 98 (2010) 213–223.

DOI: 10.1016/j.apcatb.2010.05.031

[26] N. Rahimi, R. Karimzadeh, Catalytic cracking of hydrocarbons over modified ZSM-5 zeolites to produce light olefins: A review, Appl. Catal. A Gen. 398 (2011) 1–17.

DOI: 10.1016/j.apcata.2011.03.009

[27] M. Moshoeshoe, M. Silas Nadiye-Tabbiruka, V. Obuseng, A Review of the Chemistry, Structure, Properties and Applications of Zeolites, Am. J. Mater. Sci. 2017 (2017) 196–221.

[28] K. Lazdovica, L. Liepina, V. Kampars, Catalytic pyrolysis of wheat bran for hydrocarbons production in the presence of zeolites and noble-metals by using TGA-FTIR method, Bioresour. Technol. 207 (2016) 126–133. https://doi.org/10.1016/j.biortech.2016.01.117.

DOI: 10.1016/j.biortech.2016.01.117

[29] D.Y. Hong, S.J. Miller, P.K. Agrawal, C.W. Jones, Hydrodeoxygenation and coupling of aqueous phenolics over bifunctional zeolite-supported metal catalysts, Chem. Commun. 46 (2010) 1038–1040.

DOI: 10.1039/b918209h

[30] A.M. Robinson, L. Mark, M.J. Rasmussen, J.E. Hensley, J.W. Medlin, Surface Chemistry of Aromatic Reactants on Pt- and Mo-Modi fi ed Pt Catalysts, (2016).

DOI: 10.1021/acs.jpcc.6b08415

[31] K.D. Nugrahaningtyas, W. Trisunaryanti, T. Triyono, N. Nuryono, D.M. Widjonarko, A. Yusnani, M. Mulyani, Preparation and Characterization The Non-Sulfided Metal Catalyst: Ni/USY and NiMo/USY, Indones. J. Chem. 9 (2010) 177–183.

DOI: 10.22146/ijc.21526

[32] Z. He, X. Wang, Hydrodeoxygenation of model compounds and catalytic systems for pyrolysis bio-oils upgrading, Catal. Sustain. Energy. 1 (2013) 28–52.

DOI: 10.2478/cse-2012-0004

[33] D.P. Gamliel, S. Karakalos, J.A. Valla, Liquid phase hydrodeoxygenation of anisole, 4-ethylphenol and benzofuran using Ni, Ru and Pd supported on USY zeolite, Appl. Catal. A Gen. 559 (2018) 20–29.

DOI: 10.1016/j.apcata.2018.04.004

[34] D.P. Gamliel, B.P. Baillie, E. Augustine, J. Hall, G.M. Bollas, J.A. Valla, Nickel impregnated mesoporous USY zeolites for hydrodeoxygenation of anisole, Microporous Mesoporous Mater. 261 (2018) 18–28.

DOI: 10.1016/j.micromeso.2017.10.027

[35] S. Kadarwati, E.B. Susatyo, D. Ekowati, Aktivitas Katalis Cr / Zeolit Alam pada Reaksi Konversi Minyak Jelantah Menjadi Bahan Bakar, J. Sains Dan Teknol. 8 (2010) 9–16.

DOI: 10.31258/jnat.14.3.219-226

[36] D. Ariyani, K.D. Nugrahaningtyas, E. Heraldy, The Variation of Catalyst and Carrier Gas on Anisole Deoxygenation Reaction, IOP Conf. Ser. Mater. Sci. Eng. 333 (2018).

DOI: 10.1088/1757-899x/333/1/012058

[37] S.A. El-Hakam, S.E. Samra, S.M. El-Dafrawy, A.A. Ibrahim, R.S. Salama, Surface Acidity and Catalytic Activity of Sulfated Titania Supported on Mesoporous MCM-41, Int. J. Mod. Chem. 5 (2013) 55–70.

[38] M.A. Gonalez-Borja, D.E. Resasco, Anisole and Guaiacol Hydrodeoxygenation over Monolithic Pt-Sn Catalysts, Energy and Fuels. 25 (2011) 4155–4162.

DOI: 10.1021/ef200728r

[39] M. Ferrari, B. Delmon, P. Grange, Influence of the impregnation order of molybdenum and cobalt in carbon-supported catalysts for hydrodeoxygenation reactions, Carbon N. Y. 40 (2002) 497–511.

DOI: 10.1016/s0008-6223(01)00128-2

[40] R.M. Mironenko, O.B. Belskaya, T.I. Gulyaeva, M. V Trenikhin, A.I. Nizovskii, A. V Kalinkin, V.I. Bukhtiyarov, A. V Lavrenov, V.A. Likholobov, Synergistic effect between supported metals, Catal. Today. (2016).

DOI: 10.1016/j.cattod.2016.07.022

[41] C. Keresszegi, D. Ferri, T. Mallat, A. Baiker, On the role of CO formation during the aerobic oxidation of alcohols on Pd / Al 2 O 3 : an in situ attenuated total reflection infrared study, 234 (2005) 64–75.

DOI: 10.1016/j.jcat.2005.05.019

[42] K.M.A. Santos, E.M. Albuquerque, L.E.P. Borges, M.A. Fraga, Cannizzaro reaction to lactic acid over solid catalysts, Mol. Catal. (2017).