Key Engineering Materials Vol. 899

Abstract: This work presents the results of optimization compositions of polymer-modified binder (PMB) by a compromise task. The conducted study of influence two prescription factors – containing styrene-butadiene-styrene and sulfur – on which is a set of indicators of polymer-bitumen binders were carried out. The regularities of these factors of mutual influence were established by such indicators as the Fraas brittleness temperature, penetration, softening point, ductility. The dosages of SBS and sulfur have been determined by ensuring the achievement of the required level of PBB indicators in accordance with GOST R 52056-2003 «Bitumen-polymer road binders are based on styrene-butadiene-styrene block copolymers. Specifications».

Abstract: The influence of sizing compositions on the reinforcing properties of hydrated cellulose technical yarns has been investigated. The optimal mode of modification of hydrated cellulose yarns has been determined. The evaluation of the structural properties of the modified yarns has been carried out. The kinetic features of the modified yarns wetting by an epoxy oligomer have been studied.

Abstract: A technique for starch modification by graft polymerization of acrylamide has been developed. The obtained copolymer is soluble in a wide range of pH 2 - 12. The modification of starch made it possible to freely combine it with aqueous acid solutions of chitosan, in order to achieve a synergistic effect of their properties. A porous material based on modified starch and its mixtures with chitosan, which has high sorption characteristics, has been developed. The resulting material is promising as a sorbent of heavy metal ions and packing materials for transportation and storage.

Abstract: In the present work, composite materials with a two wastes - waste goose feather as a filler and resinous waste from HMF production as a binder - have been developed. The mechanical properties and water sorption in dependence with feather/HMF resin composite content were studied. The composites containing 50% of feather have high strength properties up to 46 N/mm² and low water sorption (lower 1%), which results in high water resistance. Due to these properties, they can become an excellent alternative to urea-formaldehyde resins and plastics based on them.

Abstract: pH-sensitive hydrogels based on chitosan-graft-poly(acrylamide-co-sodium acrylate) were synthesized via radical polymerization in solution. Ammonium persulfate was used as initiator, and various amounts of hexamine were used as a cross-linking agent. The structure of obtained hydrogels was characterized by Fourier transform infrared spectroscopy. Moisture-absorbing power of hydrogels in buffer solution with various pH value (pH = 1.65; 4.01; 12.43) was investigated. It is turned out that such a copolymers have a high moisture retention capacity (swelling index attains the value 1100%) and are capable for reusing, that makes it possible to apply the hydrogels in different areas.

Abstract: The paper presents the influence research results of the structure of the original polymer composition on the resulting films physical and mechanical properties. Films are intended for gluing of protective clothing thread connections. It is shown that the change of the composition viscosity in the studied interval does not have a significant effect on the finished material performance properties.

Abstract: In this work the properties of multilayer packaging materials based on PET/AlOx film with acrylic coating were studied. Multilayer packaging materials were produced on industrial laminators using three different adhesive compositions with different content of reactive groups. It is shown that the peculiarity of the chemical nature of adhesive components affects the bond strength and the seal strength of multilayer packaging materials.

Abstract: Optically transparent organic-inorganic terpolymers based on poly (titanium oxide), hydroxyethyl methacrylate and organic monomers of the vinyl and (meth) acrylic series (acrylonitrile, butyl methacrylate, vinyl butyl ether, 2-ethylhexyl acrylate) were obained as a coating on silicate glass, polycarbonate, touch-up paint and metal. Materials’ light transmittance in the visible spectral range is 87 - 92% depending on the composition. The adhesion of terpolymers’ thin layers to substrates of various natures was investigated under shear deformations and by the lattice notch method according to ISO 15140. It was found that it is necessary to selectively excerpt composition of terpolymers in accordance with the nature of the substrate for creation adhesive durable coatings. The most durable coatings are formed on glass, polycarbonate and automotive enamel. It was revealed that the nature of the substrate and the composition of organic-inorganic terpolymers affect the hydrophobicity of the coatings and their ability to hydrophilize under the influence of UV-irradiation. The contact wetting angle of coatings with water, on average, reversibly varied within ~ 90 ° ↔ ~ 30 °.

Abstract: The article describes the results of aging of samples of cold-cured molded polyurethanes of SKU-PFL brand filled with zeolite and silica gel - wastes of petrochemical production. The samples were aged under normal climatic conditions for 5 years. Filling of the samples varied from 10 to 50 %wt. Investigations of physical and mechanical properties of the samples before and after aging were carried out, the basic indicators of material quality were calculated using Microsoft Office Excel package. As a result of researches it was established that after aging the basic physical and mechanical properties of cast polyurethanes of SKU-PFL brand of cold curing filled with zeolite and silica gel change insignificantly, however the best resistance to aging are in samples with 20 %wt. zeolite and 10 %wt. silica gel filling both before and after aging that allowed to recommend them for long-term use of articles.

Abstract: Electrospinning as a high-functioning, multi-operated, and advanced method of nanofiber production allowing to obtain fibrous materials based on different polymers for a wide range of biomedical and bioengineering applications. Hyaluronic acid is one of the most promising polymers for nanofiber formation due to its unique biological and biochemical properties. In spite of the difficulties and special features of the electrospinning from hyaluronic acid solutions, the amount of studies in this field is ever-growing. Unfortunately, there is a significant shortage of fundamental data describing the relations between the technological parameters and the nanofiber morphology. This study considers the key technological parameters of the electrospinning process such as applied voltage and flow volume rate and evaluates their influence on the morphology, mean diameter, and diameter distribution width of nanofibers based on native hyaluronic acid. The optimal range of the defined parameters has been established, at which the stability of the fiber formation is ensured. It is shown that by varying of the applied voltage and the flow volume rate of the polymer spinning solution, it is possible to control the properties of nanofibers.