Effect of Ground Vulcanizate Modification Methods on Properties of Oil-Petroleum-Resistant Rubber

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In this paper, the influence of the modification method applied to ground vulcanizate (GV) on the properties of elastomeric compositions based on nitrile rubber is discussed. Modified GV has been mixed with the elastomeric composition, which is used for the manufacturing of oil-petroleum-resistant rubber products.The work takes into consideration two types of GV with different chemical nature. The first GV type is rubber crumb produced from end-of-life tires. The second GV type was obtained from rubber wastes based on nitrile rubber. Three methods of the modification are compared in the research: mechanical activation in a planetary ball mill, swelling in a Polyethylene glycol (PEG-400) medium, and the mechano-chemical transformation of GV with PEG-4000. It is shown that depending on the dosage addition of GV modified with PEG-4000 reduce the compression set up for (16.1±0.7%), the strength decreases only by 2.1–8.3%, and the elongation at break increases by 0.8–10.3% compared to rubber without additives.

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127-133

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November 2021

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[1] J. Karger-Kocsis, L. Mészáros, and T. Bárány, Ground tyre rubber (GTR) in thermoplastics, thermosets, and rubbers,, J Mater Sci, vol. 48, no. 1, p.1–38, Jan. 2013,.

DOI: 10.1007/s10853-012-6564-2

Google Scholar

[2] S. K. De, A. Isayev, and K. Khait, Eds., Rubber Recycling, 1 edition. Boca Raton, FL: CRC Press, (2004).

Google Scholar

[3] A. Rowhani and T. J. Rainey, Scrap Tyre Management Pathways and Their Use as a Fuel—A Review,, Energies, vol. 9, no. 11, Art. no. 11, Nov. 2016,.

DOI: 10.3390/en9110888

Google Scholar

[4] V. Lapkovskis, V. Mironovs, I. Jevmenov, A. Kasperovich, and V. Myadelets, Multilayer material for electromagnetic field shielding and EMI pollution prevention,, Agronomy Research, vol. 15, p.1067–1071, May (2017).

Google Scholar

[5] M. Sambucci, D. Marini, and M. Valente, Tire Recycled Rubber for More Eco-Sustainable Advanced Cementitious Aggregate,, Recycling, vol. 5, no. 2, Art. no. 2, Jun. 2020,.

DOI: 10.3390/recycling5020011

Google Scholar

[6] V. Lapkovskis, V. Mironovs, A. Kasperovich, V. Myadelets, and D. Goljandin, Crumb Rubber as a Secondary Raw Material from Waste Rubber: A Short Review of Processing Methods,, Sep. 2020,.

DOI: 10.20944/preprints202009.0315.v1

Google Scholar

[7] M. Marín-Genescà, J. García-Amorós, R. Mujal-Rosas, L. M. Vidal, J. B. Arroyo, and X. C. Fajula, Ground Tire Rubber Recycling in Applications as Insulators in Polymeric Compounds, According to Spanish UNE Standards,, Recycling, vol. 5, no. 3, Art. no. 3, Sep. 2020,.

DOI: 10.3390/recycling5030016

Google Scholar

[8] Y.-T. Lin, G.-L. Zhuang, M.-Y. Wey, and H.-H. Tseng, The Viable Fabrication of Gas Separation Membrane Used by Reclaimed Rubber from Waste Tires,, Polymers, vol. 12, no. 11, Art. no. 11, Nov. 2020,.

DOI: 10.3390/polym12112540

Google Scholar

[9] Ł. Zedler, D. Kowalkowska-Zedler, X. Colom, J. Cañavate, M. R. Saeb, and K. Formela, Reactive Sintering of Ground Tire Rubber (GTR) Modified by a Trans-Polyoctenamer Rubber and Curing Additives,, Polymers, vol. 12, no. 12, Art. no. 12, Dec. 2020,.

DOI: 10.3390/polym12123018

Google Scholar

[10] F. Cavalieri, F. Padella, and F. Cataldo, Mechanochemical surface activation of ground tire rubber by solid-state devulcanisation and grafting,, Journal of Applied Polymer Science, vol. 90, no. 6, p.1631–1638, 2003,.

DOI: 10.1002/app.12829

Google Scholar

[11] S. H. Lee, A. M. Shanmugharaj, V. Sridhar, Z. X. Zhang, and J. K. Kim, Preparation and characterisation of polypropylene and waste tire powder modified by allylamine blends,, Polymers for Advanced Technologies, vol. 20, no. 7, p.620–625, 2009,.

DOI: 10.1002/pat.1307

Google Scholar

[12] V. Myadelets, A. Kasperovich, and V. Farofontov, Application of siliceous compounds in recycling of vulcanised wastes based on nitrile rubber,, Proceedings of BSTU, vol. Chemistry, Organic Substances Technology and Biotechnology, no. 4, p.103–106, (2013).

Google Scholar

[13] P. J. Flory, Statistical Mechanics of Swelling of Network Structures,, J. Chem. Phys., vol. 18, no. 1, p.108–111, Jan. 1950,.

Google Scholar

[14] Handbook of Organic Solvent Properties. Elsevier, 1996.

Google Scholar

[15] J. Brandrup, E. H. Immergut, and E. A. Grulke, Polymer Handbook, 4th ed., 2 vols. Wiley, (2003).

Google Scholar

[16] L. E. Nielsen, Models for the Permeability of Filled Polymer Systems,, Journal of Macromolecular Science: Part A - Chemistry, vol. 1, no. 5, p.929–942, Aug. 1967,.

DOI: 10.1080/10601326708053745

Google Scholar

[17] J. Lamminmäki, S. Li, and K. Hanhi, Feasible incorporation of devulcanised rubber waste in virgin natural rubber,, Journal of Materials Science, vol. 24, no. 41, p.8301–8307, 2006,.

DOI: 10.1007/s10853-006-1010-y

Google Scholar

[18] M. Luo, X. Liao, S. Liao, and Y. Zhao, Mechanical and dynamic mechanical properties of natural rubber blended with waste rubber powder modified by both microwave and sol–gel method,, Journal of Applied Polymer Science, vol. 129, no. 4, p.2313–2320, 2013,.

DOI: 10.1002/app.38954

Google Scholar

[19] M. M. Hassan, R. O. Aly, S. E. A. Aal, A. M. El-Masry, and E. S. Fathy, Styrene butadiene-based blends containing waste rubber powder: Physico-mechanical effects of mechanochemical devulcanisation and gamma irradiation,, Journal of Industrial and Engineering Chemistry, vol. 19, no. 5, p.1735–1742, Sep. 2013,.

DOI: 10.1016/j.jiec.2013.02.014

Google Scholar

[20] J. Yun, A. I. Isayev, S. H. Kim, and M. Tapale, Comparative analysis of ultrasonically devulcanised unfilled SBR, NR, and EPDM rubbers,, Journal of Applied Polymer Science, vol. 88, no. 2, p.434–441, 2003,.

DOI: 10.1002/app.11741

Google Scholar

[21] M. Ridhwan et al., The Effects of Different Particle Sizes of Recycled Acrylonitrile Butadiene Rubber and its Blend Ratios on Mechanical and Morphological Properties of vNBR/rNBR Blends,, MATERIALE PLASTICE, vol. 51, p.201–204, Jun. (2014).

DOI: 10.1080/03602550802355206

Google Scholar

[22] K. Formela, M. Klein, X. Colom, and M. R. Saeb, Investigating the combined impact of plasticiser and shear force on the efficiency of low temperature reclaiming of ground tire rubber (GTR),, Polymer Degradation and Stability, vol. 125, p.1–11, Mar. 2016,.

DOI: 10.1016/j.polymdegradstab.2015.12.022

Google Scholar

[23] M. S. Sobhy, M. M. M. Mahdy, M. A. K. El-Fayoumi, and E. M. Abdel-Bary, Effect of waste rubber powder in SBR formulations on the swelling of different organic solvents,, Polymer Testing, vol. 16, no. 4, p.349–362, Aug. 1997,.

DOI: 10.1016/s0142-9418(96)00056-6

Google Scholar

[24] A. N. Gent, Engineering with Rubber: How to Design Rubber Components, 3rd ed. München: Carl Hanser Verlag GmbH & Co. KG, 2012.

Google Scholar