Influence of Polar Groups on the Ability of Polymers to Form Nanopenocox when Heated to Reduce the Fire Hazard of Building Materials

Tatyana A. Matseevich; Andrey A. Askadskii

doi:10.4028/www.scientific.net/KEM.906.85

Paper Titles

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Simplification and Improvement of the Efficiency of Testing Thermophysical Properties of Facade Composite Materials
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Influence of Polar Groups on the Ability of Polymers to Form Nanopenocox when Heated to Reduce the Fire Hazard of Building Materials
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HomeKey Engineering MaterialsKey Engineering Materials Vol. 906Influence of Polar Groups on the Ability of...

Influence of Polar Groups on the Ability of Polymers to Form Nanopenocox when Heated to Reduce the Fire Hazard of Building Materials

Abstract:

The method for estimating the influence of polar groups on the temperature of the onset of the intense thermal degradation of polymers under heating is proposed. This estimate is based on the equation for calculating this value for the entire repeating link proposed earlier [1-4]. The method is computerized and is included as an integral part of the computer program "Cascade" (INEOS RAS). The calculated estimation is carried out for one of the structures of the rejected cycloaliphatic epoxy resin. The most "weak" group was the group –CO–. The temperature of the onset of intensive thermal degradation of this group is 547 K.

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Periodical:

Key Engineering Materials (Volume 906)

Pages:

85-92

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.906.85

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Online since:

January 2022

Authors:

Tatyana A. Matseevich*, Andrey A. Askadskii

Keywords:

Cycloaliphatic Epoxy Resin, Polar Groups, Temperature of the Onset of Intensive Thermal Degradation

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References

[1] A.A. Askadskii, YU.I. Matveev, Himicheskoe stroenie i fizicheskie svojstva polimerov // M.: Himiya, 1983, p.248.

Google Scholar

[2] A.A. Askadskii, V.I. Kondrashchenko, Komp'yuternoe materialovedenie polimerov. T.1. Atomno-molekulyarnyj uroven' // Izd-vo Nauchnyj Mir, 1999, p.543.

Google Scholar

[3] A.A. Askadskii, Computational Materials Science of Polymers // Cambridge International Science Publishing Ltd. Cambridge, 2003, p.695.

Google Scholar

[4] A.A. Askadskii, T.A. Matseevich, M.N. Popova, Vtorichnye polimernye materialy. Mekhanicheskie i bar'ernye svojstva, plastifikaciya, smesi i nanokompozity // M.: Izd-vo ASV, 2017, p.490.

Google Scholar

[5] L.V. Gurvich, G.V. Karachencev, V.I. Kondrat'ev and etc., Energiya razryva himicheskih svyazej. Potencialy ionizacii i srodstvo k elektronu // M.: Nauka, 1974, p.351.

Google Scholar

[6] A.A. Koptelov, Teplofizika vysokih temperature // Vysokomolekulyarnye soedineniya, Seriya A, T.42, № 2, 2004, p.307.

Google Scholar

[7] A.A. Koptelov, YU.M. Milekhin, O.F. SHlenskj, Teplovye effekty termicheskogo razlozheniya polimerov // Vysokomolekulyarnye soedineniya, Seriya A, T.47, № 9, 2005, pp.1628-1634.

Google Scholar

[8] M.A. Villetti, J.S. Crespo, M.S. Soldi, A.T.N. Pires, R. Borsali and V. Soldi, Thermal degradation of natural polymers // Journal of Thermal Analysis and Calorimetry, V. 67, 2002, 295-303.

DOI: 10.1023/a:1013902510952

Google Scholar

[9] A. Lafuma, D. Quere // Nature Materials, Vol. 2, 2003, p.457.

Google Scholar

[10] A. Tuteja, W. Choi, M. Ma, J.M. Mabry, S.A. Mazella, G.C. Rutledge, G.H. McKinley, R.E. Cohen // Science, V.318, 2007, p.1618.

Google Scholar

[11] Marius C. Costache, Dongyan Wang, Matthew J. Heidecker, E. Maniasa and Charles A. Wilkie The thermal degradation of poly(methyl methacrylate) nanocomposites with montmorillonite, layered double hydroxides and carbon nanotubes // Polym. Adv. Technol, T.17, 2006: p.272–280.

DOI: 10.1002/pat.697

Google Scholar

[12] A. Kulkarni, H. Dasar, Current Status of Methods Used In Degradation of Polymers: // MATEC Web of Conferences №144, 2018, p.02023.

DOI: 10.1051/matecconf/201814402023

Google Scholar

[13] A.A. Askadskii, A.I. Barabanova, E.S. Afanasev, N.D. Kagramanov, N.E. Mysova, N.S. Ikonnikov, E.P. Kharitonova, B.V. Lokshin, A.R. Khokhlov, O.E. Philippova, Revealing defects hampering the formation of epoxy networks with extremely high thermal properties: Theory and experiments // Polymer Testing, V. 90, 2020, p.106645.

DOI: 10.1016/j.polymertesting.2020.106645

Google Scholar

[14] G.E. Zaikov, Gorenie, destrukciya i stabilizaciya polimerov // S.-Peterburg, Nauchnye osnovy i tekhnologii, 2008, p.424.

Google Scholar

[15] A.K. Mikitaev, M.Kh. Ligidov, G.E. Zaikov, Modern tendencies in organic and bioorganic chemistry. Today and tomorrow. // N.-Y., Nova Science Publishers, 2008, p.428.

Google Scholar