Response Surface Methodology Optimization of Chemical Oxygen Demand Removal by Rice Husk Activated Carbon

Article Preview

Abstract:

High Chemical Oxygen Demand (COD) levels in water indicate a vast amount of oxidizable matter that consumes a lot of dissolved oxygen in water. This results in adverse impacts on both aquatic ecosystems and human health. Wastewater from the fish cracker industry typically has high organic content and high COD value. In this study, rice husk was chosen as the raw material because of its abundance and economy. The optimum adsorption parameters such as flow rate, contact time, and initial COD concentration that affect adsorption by rice husk activated carbon were studied using Response Surface Methodology. The treatment was done in a continuous fixed-bed column. From the Box-Behnken design, it was determined that 68.09% removal percentage resulted from the best combination of 4.5 hours of contact time, 1 mL/min of flowrate, and 5% initial COD concentration. The SEM micrograph shows the adsorbent consists of a large number of pores before adsorption. Based on the study, rice husk activated carbon can be an alternative treatment for COD removal in wastewater. The use of activated carbon derived from agricultural waste materials can help reduce the waste produced, which will otherwise end up in the landfill.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

385-391

Citation:

Online since:

January 2022

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2022 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] M. Meybeck, R. Helmer, The Quality of Rivers: From pristine stage to Global Pollution, ‎Glob. Planet. Change. 1(4) (1989) 283–309.

DOI: 10.1016/0031-0182(89)90191-0

Google Scholar

[2] A. Hajali, COD and TOC Removal Assessment in Effluent from Anaerobic Bioreactor and Effluent from Cyclic Ozonation-Biotreatment in A Pulp Factory Wastewater Treatment, 4th International Conference on Energy, Environment and Sustainable Development at Pakistan, (2016).

DOI: 10.1109/ciem.2017.8120786

Google Scholar

[3] G. Kirbria, Environmental Update-Dissolved Oxygen: The Facts, Outlet. 162 (2004) 2-4.

Google Scholar

[4] C. Assmann, A. Scott, D. Biller, Online Total Organic Carbon (TOC) Monitoring for Water and Wastewater Treatment Plants Processes and Operations Optimization. Drink. Water Eng. Sci. 10(2) (2017) 61-68.

DOI: 10.5194/dwes-10-61-2017

Google Scholar

[5] E. Amanatidou, E. Trikoilidou, G, Samiotis, N.P Benetis, N. Taousanidis, An Easy Uncertainty Evaluation of the COD Titrimetric Analysis in Correlation with Quality Control and Validation Data. Method Applicability Region, Anal. Methods. 4(12) (2012) 4204-4212.

DOI: 10.1039/c2ay25687h

Google Scholar

[6] P.T. Nguyen, T.H. Dao, Study on modelling fish processing wastewater anaerobic treatment, Asean Eng J Part C. 4(3) (2015) 6-15.

Google Scholar

[7] M.Z. Mohd Alias, R. Mohd Ghazi, N.R. Nik Yusoff, M.H. Jamaludin, The Efficiency of Bamboo Activated Carbon for Removal of COD from Fish Cracker Industry Wastewater via Response Surface Methodology (RSM), IOP Conf. Ser.: Earth Environ. Sci. 549 (2020) 012058.

DOI: 10.1088/1755-1315/549/1/012058

Google Scholar

[8] C.P. Goh, R. Mohd Ghazi, N.R. Nik Yusoff, M.Z. Mohd Alias, M. Jani. Adsorption of COD in wastewater by Activated Carbon from Rice Husk. IOP Conf. Ser.: Earth Environ. Sci. (2020) 596 (1) 012063.

DOI: 10.1088/1755-1315/596/1/012063

Google Scholar

[9] B. Viswanathan, P. Neel, T. Varadarajan, Methods of activation and specific applications of carbon materials, first ed., Chennai, India, (2009).

Google Scholar

[10] C. Correa Rodriguez, T. Otto, A. Kruse, Influence of the biomass components on the pore formation of activated carbon, Biomass Bioenerg. 97 (2017) 53–64.

DOI: 10.1016/j.biombioe.2016.12.017

Google Scholar

[11] J. Rosas, J.R.M.J. Bedia, T. Cordero, HEMP-Derived Activated Carbon Fibers by Chemical Activation with Phosphoric Acid, Fuel. 88(1) (2009) 19-26.

DOI: 10.1016/j.fuel.2008.08.004

Google Scholar

[12] T.H. Liou, S.J. Wu, Characteristics of microporous/mesoporous carbons prepared from rice husk under base-and acid-treated conditions, J. Hazard. Mater. 171(1) (2009) 693-703.

DOI: 10.1016/j.jhazmat.2009.06.056

Google Scholar

[13] H. Patel, R. Vashi, Characterization and column adsorptive treatment for COD and color removal using activated neem leaf powder from textile wastewater, J. Urban Environ. Eng. 9(1) (2014) 45-53.

DOI: 10.4090/juee.2015.v9n1.045053

Google Scholar

[14] N. Kannan, R. Jeya Ganesh, Studies on the removal of malachite green from aqueous solutions by mixed adsorbent, Indian J. Environ. Prot. 21 (2001) 127-133.

Google Scholar

[15] Y. Pan, Y. Zhu, Z. Xu, R. Lu, Z. Zhang, M. Liang, H. Liu, Adsorption removal of COD from wastewater by the activated carbons prepared from sugarcane bagasse, The 5th International Conference on Bioinformatics and Biomedical Engineering at Guilin, P. R. China, (2011).

DOI: 10.1109/icbbe.2011.5781097

Google Scholar