Investigation of Clinoptylolite Ion Exchange Capacity Relative to Copper and Zinc Ions in Conditions of Ideal Intermixing Mode

Abstract:

The sorption method of purification of flushing water from non-ferrous metal ions in galvanizing-bath rooms of mechanical facilities was investigated, which is one of the most realistic ways to solve the problem of environmental protection from such pollution. The effect of preliminary thermal and chemical modification of the crystal structure in order to improve the sorption capacity of clinoptilolite was established. The kinetics of the copper ion exchange process on clinoptilolite in static conditions was determined.

• Periodical: Key Engineering Materials (Volume 925)
• Pages: 151-158
• DOI: https://doi.org/10.4028/p-n1rq18
• Online since: July 2022
• Authors: Myroslav Malovanyy*, Zoryana Odnorih, Ivan Tymchuk, Yurii Dziurakh, Wojciech Lutek
• Keywords: Clinoptilolite, Copper Ions, Ion Exchange, Kinetics, Modification, Process, Zinc Ions

References

[1] D.V. Kulikova, O.S. Kovrov, Іmprovement of manufacturing scheme of wastewater treatment for galvanic shops of coal machine building enterprises. Ecological Safety and Balanced Use of Resources, 2(22) (2021) 97-106.

[2] A. Zapolskyy, N. Mishkova-Klymenko, I. Astrelin, M. Bryk, Fizyko-Khimichni Osnovy Tekhnolohii Ochyshchennia Stichnykh Vod, Libra, Kyiv,(2000).

[3] I.M. Chub, Masoobminni protsesy vodopidhotovky, KhNUMH im. O.M. Beketova, Kharkiv, (2020).

[4] O.I. Kuntyi, Halvanotekhnika, Vydavnytstvo Nats. Un-tu «Lvivska politekhnika», Lviv, (2004).

[5] T.V. Klymenko, Ochystka stochnykh vod ot yonov tiazhelykh metallov. Sovremennye nauchnye іssledovanyia і іnnovatsіі, 11 (2013).

[6] H. Sakalova, M. Malovanyy, T. Vasylinych, R. Kryklyvyi, The Research of Ammonium Concentrations in City Stocks and Further Sedimentation of Ion-Exchange Concentrate. Journal of Ecological Engineering, 20(1) (2019) 158-164.

DOI: 10.12911/22998993/93944

[7] V. Iurchenko, M. Radionov, O. Melnikova, O. Rachkovskiy, L. Mykhailova, Influence on Environmental Safety of the Drinking Water of Nitrification in Water Reservoir Being a Source of Water Supply and Filter Filling, Materials in Water Treatment Facilities. Materials Science Forum, (1006 MSF) (2020) 187-193.

DOI: 10.4028/www.scientific.net/msf.1006.187

[8] M. Malovanyy, H. Sakalova, T. Vasylinycz, O. Palamarchuk, J. Semchuk, Treatment of effluents from ions of heavy metals as display of environmentally responsible activity of modern businessman. Journal of Ecological Engineering, 20(4) (2019) 167-176.

DOI: 10.12911/22998993/102841

[9] M. Malovanyy, K. Petrushka, I. Petrushka, Improvement of Adsorption-Ion-Exchange Processes for Waste and Mine Water Purification. Chemistry & Chemical Technology, 13(3) (2019) 372-376.

DOI: 10.23939/chcht13.03.372

[10] S.S. Milovych, V.I. Homonai, A. Kovalchikova, Khimichnyi sklad i krystalichna struktura pryrodnoho klynoptylolitu Sokyrnytskoho rodovyshcha ta yoho modyfikovanykh form. Nauk. visnyk Uzhhorod. un-tu (Seriia Khimiia), 2(42) (2019) 73-80.

[11] Yu.Iu. Lure, Unyfytsyrovannye metody analyza vod, Khіmіia, Moskva, (1973).

[12] V.B. Aleskovskyi, V.V. Bardyn, M.Y. Bulatov, Fyzyko-khymycheskye metody analyza. Praktycheskoe rukovodstvo, Khіmіia, Lenynhrad, (1988).

[13] D. Brek, Tseolytovyіe molekuliarnyіe syta, Mir, Moskva, (1976).

[14] M.D. Homelia, V.P. Ivanova, V.S. Kamaiev, Yu.A. Marushchak, Vyznachennia sorbtsiinoi zdatnosti ionitu pry vyluchenni ioniv midi z vody. Problemy vodopostachannia, vodovidvedennia ta hidravliky, 28 (2017) 84-91.

[15] A.S. Seheda, Analitychna khimiia. Kilkisnyi analiz, Fitosotsiotsentr, Kyiv, (2006).

[16] H.V. Sakalova, T.M. Vasylinych, Doslidzhennia efektyvnosti ochyshchennia stichnykh vod vid ioniv vazhkykh metaliv z vykorystanniam pryrodnykh adsorbentiv, TOV «Tvory»,Vinnytsia, (2019).