Materials Science Forum Vol. 1016

Abstract: In the present work, uniaxial tension tests have been conducted to study the mechanical response of a commercial Al4.5wt%Mg alloy (AA5182). The measurements range from the strain rate of 10^-4 to 10⁰ s^-1 at room temperature. Digital image correlation (DIC) is also utilized to characterize the heterogeneous deformation of PLC localization. An extremely high camera frame rate (1000Hz) is applied to accurately measure the critical strain of instabilities, especially for tests at high strain rates (>10^-1 s^-1). The objective of this work has been to evaluate currently existing constitutive and physically based models to see to which extent they can match the experimental findings related to dynamic strain aging, i.e. stress-strain curves, work hardening behavior and critical strain behavior.

Abstract: Relationships between macroscopic and microscopic constitutive parameters associated with steady state DDRX are derived for a material in which strain-hardening and dynamic recovery are described by the Yoshie-Laasraoui-Jonas equation. First examples are given for illustration.

Abstract: The reduction of harmful greenhouse gas (GHG) emissions can be realized by utilizing lightweight structural metals, such as magnesium. Magnesium alloys have the potential to replace higher-density aluminum and ferrous components in automotive and aerospace industries, thereby decreasing vehicle weight and the associated fuel requirements. However, their strength and ductility must be improved to ensure widespread application. This goal can be achieved through ultrasonic processing in the molten state, a technique that is gaining popularity in the manufacturing of light alloys. In this study, the effects of high-intensity ultrasonic vibration on the microstructure and hardness of AZ91E Mg alloy was investigated. The molten alloys were subjected to sonication of varying durations, and the resulting castings were characterized using optical microscopy, scanning electron microscopy and hardness testing. Sonication was found to successfully increase the hardness of the alloy relative to the base condition. This improvement was attributed to the refinement of the magnesium grain structure as well as the Mg₁₇Al₁₂ and Mn-Al secondary phases in the sonicated alloys. The competitiveness of magnesium alloys can be significantly enhanced via ultrasonic processing, offering important opportunities for the production of greener, light metal components.

Abstract: Computer simulation of the α/γ phase transformation in multipass weld of duplex stainless steel was made for predicting the distribution of the γ phase fraction in the weld metal (WM) and HAZ. The kinetic equations including rate constants of the dissolution behaviour as well as precipitation behaviour of γ phase were determined by isothermal heat treatment test. Based on the kinetic equations determined, the distribution of the γ phase fraction in multipass weld of duplex stainless steel was calculated applying the incremental method combined with the heat conduction analysis in welding process. The γ phase fraction was reduced in the higher temperature HAZ and WM, however, that in the reheated HAZ and WM was increased and recovered to the base metal level. Microstructural analysis revealed that the calculated results of the γ phase fraction in multipass weld were consistent with experimental ones. Based on the computer prediction, the microstructural improvement welding (“reheat bead welding”) process, with analogous concept to the temper bead welding technique, was newly proposed for recovering the γ phase fraction in weld even in the as-welded situation.

Abstract: Particle size and distribution affect the thermal properties such as thermal conductivity, thermal expansion, and mechanical properties. In this study, TiB2 particles were used for the dispersant of pure aluminum composites because of high thermal conductivity and low thermal expansion of TiB2. Composites with different dispersibility and volume fraction of particles were prepared by spark plasma sintering. The effect of particle dispersibility in composites on thermal conductivity was estimated quantitatively by the simulation and experiments. As increasing dispersibility, the thermal conductivity was decreased and Vickers's hardness increased, but alternation for thermal conductivity was very small. With increasing volume fraction of particles, the effect of the particle dispersion on the change of the thermal conductivity increased. In addition, the empirical equation of the thermal conductivity considering dispersibility was estimated. The coefficient of thermal expansion decreased with increasing the particle volume fraction, and the experimental value quite accorded with a result provided by the rule of mixture.

Abstract: Friction stir welding (FSW) is one of the solid-state welding and it has been widely employed for joining aluminum alloys. In addition, as a result of R&D efforts about FSW tool, this method is expected to join the steels and/or various dissimilar materials. In order to examine the thermal and mechanical behavior in FSW, many numerical studies have been conducted and the heat generation behavior near FSW tool is precisely demonstrated by using the moving particle semi-implicit (MPS) method which is one of the particle method. In this research, in order to reduce the computational time, a new parcel method based on MPS is developed and its applicability is examined for simulating the friction stir welded dissimilar joint between V-ally and austenite stainless steel SUS316L. From the serial computational results, it is revealed that the influence of rotational speed on the heat generation during FSW seems to be larger than that of traveling speed. Moreover, the numerical result indicates that the sound dissimilar joint might be fabricated when V-alloy is set to be the retreating side (RS), the FSW tool is inserted in RS and the rotational speed increased appropriately although the two materials have not been joined in this welding condition of FSW experimentally.

Abstract: The possibility to reduce costs of the additive manufacturing (AM) technologies by using recycled powders is still an open question. The present paper aims to investigate the effect of using virgin and recycled powders on the corrosion resistance of Ti6Al4V titanium alloy additive manufactured parts. Although the study of the electrochemical behaviour of titanium parts produced by using AM is present in the literature, the corrosion resistance of samples manufactured using recycled powders is less investigated. This work would like to contribute to the deepening of this aspect. The experimental investigations have been carried out on as-built samples as well as on samples after mechanical polishing. The metallographic observations of additive manufactured samples showed a martensitic microstructure inside the prior β grain grew up as columnar structure. X-ray diffraction analysis revealed the presence of titanium oxide in rutile crystallographic phase. The electrochemical characterisation unveiled the lower corrosion resistance of the as-built additive manufactured components compared to the traditional counterpart. It also highlighted the effect due to the use of recycled powders when the bulk of the samples has been investigated.

Abstract: We have been investigating the series of P doped Ca₂SiO₄ (C₂S) using Eu²⁺ or Eu³⁺ as activator with various colors. The crystal structure of C₂S is particularly easily controlled by heating because the established polymorphs of C₂S are, in the order of increasing temperature, γ, β, α’_L, α’_H, and α. In order to control the crystal structure, the phosphors were synthesized and then annealed at temperatures 1473 K-1773 K. The crystal structures and PL properties were compared between slow cooling and quenching (cooled in water). We found unique phenomena when the phosphors were treated by quenching process. In the case of (Ba_1-xCa_x)₂(Si_0.94P_0.06)O₄:Eu³⁺ ( 0.25 ≤ x ≤ 1), color emission changed from red to blue-white for the phosphor with a high concentration of Ba and quenched at 1773 K. In general, Eu³⁺ doped phosphors showed the red emission color in any host materials. However, Ba-included and quenched-treatment phosphors emitted a bright white color. The mechanism and relationship between the PL property and crystal structure were characterized carefully using X-ray diffraction, electron microscope and X-ray absorption fine structure.

Abstract: An in-house 2D finite volume model, specific for components of simple shape, was developed and applied to predict the thermal and microstructural evolution during heat treatment of steel forgings. The results of the thermal metallurgical modelling, including hardness profiles through the thickness, were compared with the experimental ones. Moreover, the 3D FEM software Deform-HT, able to calculate the thermal and microstructural evolution and the stress field during quenching, was specialized for the cases of interest. Examples of optimal heat treatment to develop the target microstructure and strength and reduce the risk of quenching cracks are discussed.

Abstract: Pressure-sensitive conductive material is used for various pressure sensors consists of a polymer nanocomposite with carbon nanotubes (VGCF). And the resistance in it were changed by adding applied load. Recently, carbon nanotubes (VGCF) has drawn attention as a function filler that imparts various functions to a resin, including electrical properties. In polycarbonate (PC) composite with VGCF, the resistance decreases with increase in applied load. And increase of the addition amount of VGCF was enhanced the mechanical properties and electronic properties. In addition, this conclusion suggested that strain of PC/VGCF caused reducing the resistance. Therefore, changing matrix is predictably effective on electrical properties in pressure-conductive materials. In the present study, we used various matrix had different elastic modulus. The addition amount of VGCF was 12.5% volume rate. We made silicone/VGCF and polyethylene (PE)/VGCF and polycarbonate (PC)/VGCF by twin screw extruder and injection moldings. To clarify the influence of elastic modulus of matrix on conductivity of VGCF dispersed plastic matrix composites. The experimental results showed that conductive property of pressure-sensitive conductive materials is related to elastic modulus of them.