The Effect of Partial Substitution of Non-Magnetic Impurity Zn on the Magnetic Moments of Eu_1.88Ce_0.12Cu_1-yZn_yO_4+α-δ

Abstract:

Structure and magnetic properties of electron-doped superconducting cuprates have been investigated in order to study the effect of magnetic impurity to its physical properties. Here, we reported structure and magnetic properties of Eu_1.88Ce_0.12Cu_1-yZn_yO_4+α-δ (ECCZO) with y = 0 and 0.03. The properties of ECCZO have been studied from X-ray diffraction data and temperature dependence of magnetic susceptibility data, to elucidate the effect of partial substitution of non-magnetic impurity Zn for Cu to its structure, T_c and the value of magnetic moments per unit volume extracted from susceptibility data in normal state. Magnetic-susceptibility measurements were carried out down to 2 K on-field cooling at 5 Oe for Eu_1.88Ce_0.12Cu_1-yZn_yO_4+a-d with y = 0 and 0.03. For ECCZO sample with y = 0 and d = 0.0669 indicated the change of magnetic behavior from paramagnetic to diamagnetic below 12 K which is addressed to the Tc onset of this samples. Diamagnetic behavior is observed starting from about 12 K. Above 12 K, all samples show paramagnetic behavior with the values of the magnetic moment in every volume unit increased with increasing Zn.

• Periodical: Materials Science Forum (Volume 1028)
• Pages: 15-20
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.1028.15
• Online since: April 2021
• Authors: Muhammad Abdan Syakuur, Yati Maryati, Togar Saragi, Risdiana Risdiana*
• Keywords: Electron-Doped Superconductor, Magnetic Moments, Susceptibility, Zn Impurities

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