Disorder - Induced Characteristics Based on Optical Absorption of SiO2/rGO-Like Carbon Films

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The purpose of this research is to study the interrelation between Urbach energy (Eu), optical band gap energy (Eg), and complex dielectric constant (ε) in relation to the disorder induced properties of SiO2/rGO thin films. The rGO-like carbon was created by annealing coconut shell carbon (csc) at different temperatures of 400°C, 600 oC, and 800 oC. From the analyses, it obtained Eg which was varied from 2.01 eV until 2.67 eV. While Eu from 0.13 eV until 0.26 eV. The results showed that the Eu varied inversely to the Eg. The Penn model and hydrogen-like atom model theories were used to investigate the interrelation between Eu and ε. Finally, it is shown that the Urbach energy is linearly and inversely related to the imaginary and real parts of dielectic constant, respectively.

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Materials Science Forum (Volume 1094)

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99-104

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July 2023

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© 2023 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. Chantana, Y. Kawano, T. Nishimura, A. Mavlonov, and T. Minemoto, 'Impact of Urbach energy on open-circuit voltage deficit of thin-film solar cells', Solar Energy Materials and Solar Cells, vol. 210, p.110502, Jun. 2020.

DOI: 10.1016/j.solmat.2020.110502

Google Scholar

[2] C. Kaiser, O. J. Sandberg, N. Zarrabi, W. Li, P. Meredith, and A. Armin, 'A universal Urbach rule for disordered organic semiconductors', Nat Commun, vol. 12, no. 1, p.3988, Dec. 2021.

DOI: 10.1038/s41467-021-24202-9

Google Scholar

[3] V. R. Akshay, B. Arun, G. Mandal, and M. Vasundhara, 'Visible range optical absorption, Urbach energy estimation and paramagnetic response in Cr-doped TiO 2 nanocrystals derived by a sol–gel method', Phys. Chem. Chem. Phys., vol. 21, no. 24, p.12991–13004, 2019.

DOI: 10.1039/C9CP01351B

Google Scholar

[4] V. Mishra et al., 'Metastable behavior of Urbach tail states in BaTiO3 across phase transition', p.18.

Google Scholar

[5] A. Y. Nugraheni, M. Nasrullah, F. A. Prasetya, F. Astuti, and Darminto, 'Study on Phase, Molecular Bonding, and Bandgap of Reduced Graphene Oxide Prepared by Heating Coconut Shell', MSF, vol. 827, p.285–289, Aug. 2015.

DOI: 10.4028/www.scientific.net/MSF.827.285

Google Scholar

[6] I. Khambali et al., 'N-Doped rGO-Like Carbon Prepared from Coconut Shell: Structure and Specific Capacitance', Journal of Renewable Materials, vol. 0, no. 0, p.1–11, 2022.

DOI: 10.32604/jrm.2023.025026

Google Scholar

[7] M. A. Baqiya et al., 'Structural study on graphene-based particles prepared from old coconut shell by acid–assisted mechanical exfoliation', Advanced Powder Technology, vol. 31, no. 5, p.2072–2078, May 2020.

DOI: 10.1016/j.apt.2020.02.039

Google Scholar

[8] C.-B. Yu et al., 'Graphene oxide deposited microfiber knot resonator for gas sensing', Opt. Mater. Express, vol. 6, no. 3, p.727, Mar. 2016.

DOI: 10.1364/OME.6.000727

Google Scholar

[9] D. Ristiani et al., 'Mesostructural study on graphenic-based carbon prepared from coconut shells by heat treatment and liquid exfoliation', Heliyon, vol. 8, no. 3, p. e09032, Mar. 2022.

DOI: 10.1016/j.heliyon.2022.e09032

Google Scholar

[10] A. S. Hassanien and A. A. Akl, 'Effect of Se addition on optical and electrical properties of chalcogenide CdSSe thin films', Superlattices and Microstructures, vol. 89, p.153–169, Jan. 2016.

DOI: 10.1016/j.spmi.2015.10.044

Google Scholar

[11] N. S.,. K. P.,. S. I.,. S. D., and . A. K.T., 'Optical band-gap and associated Urbach energy tails in defected AlN thin films grown by ion beam sputter deposition: Effect of assisted ion energy', Advanced Materials Proceedings, vol. 2, no. 5, p.342–346, Dec. 2021.

DOI: 10.5185/amp.2017/511

Google Scholar

[12] S. K. J. Al-Ani, 'Determination of the optical gap of amorphous materials', International Journal of Electronics, vol. 75, no. 6, p.1153–1163, Dec. 1993.

DOI: 10.1080/00207219308907191

Google Scholar

[13] A. Feldman, 'Basic optical properties of materials', p.256.

Google Scholar

[14] S. Benramache, Y. Aoun, S. Lakel, B. Benhaoua, and C. Torchi, 'The calculate of optical gap energy and urbach energy of Ni1−xCoxO thin films', Sādhanā, vol. 44, no. 1, p.26, Jan. 2019.

DOI: 10.1007/s12046-018-1003-y

Google Scholar

[15] J. Haiwei, Q. Li, Z. Lan, Z. Xinlin, and Y. Rui, 'Review of wide band-gap semiconductors technology', MATEC Web of Conferences, p.5, 2015.

Google Scholar

[16] A. Kumar et al., 'Possible evidence of delocalized excitons in Cr-doped PrFeO3: An experimental and theoretical realization', Journal of Physics and Chemistry of Solids, vol. 130, p.230–235, Jul. 2019.

DOI: 10.1016/j.jpcs.2019.03.012

Google Scholar

[17] F. N. C. Anyaegbunam and C. Augustine, 'A Study Of optical Band Gap And Associated Urbach Energy Tail Of Chemically Deposited Metal Oxides Binary Thin Films' p.10.

Google Scholar

[18] S. Benramache, Y. Aoun, S. Lakel, B. Benhaoua, and C. Torchi, 'The calculate of optical gap energy and urbach energy of Ni1−xCoxO thin films', Sādhanā, vol. 44, no. 1, p.26, Jan. 2019.

DOI: 10.1007/s12046-018-1003-y

Google Scholar

[19] G. Gitonga Riungu, S. Waweru Mugo, J. Mbiyu Ngaruiya, G. Mbae John, and N. Mugambi, 'Optical Band Energy, Urbach Energy and Associated Band Tails of Nano Crystalline TiO<sub>2</sub> Films at Different Annealing Rates', AJN, vol. 7, no. 1, p.28, 2021.

DOI: 10.11648/j.ajn.20210701.15

Google Scholar

[20] A. Kurt and K. Demirelli, 'A study on the optical properties of three-armed polystyrene and poly(styrene-b-isobutyl methacrylate)', Polym Eng Sci, vol. 50, no. 2, p.268–277, Feb. 2010.

DOI: 10.1002/pen.21530

Google Scholar

[21] A. Sati et al., 'Direct correlation between the band gap and dielectric loss in Hf doped BaTiO3', J Mater Sci: Mater Electron, vol. 30, no. 8, p.8064–8070, Apr. 2019.

DOI: 10.1007/s10854-019-01128-z

Google Scholar

[22] A. C. Sharma, 'Size-dependent energy band gap and dielectric constant within the generalized Penn model applied to a semiconductor nanocrystallite', Journal of Applied Physics, vol. 100, no. 8, p.084301, Oct. 2006.

DOI: 10.1063/1.2357421

Google Scholar

[23] C. Q. Hu et al., 'Relationship between dielectric coefficient and Urbach tail width of hydrogenated amorphous germanium carbon alloy films', Appl. Phys. Lett., vol. 101, no. 4, p.042109, Jul. 2012.

DOI: 10.1063/1.4739788

Google Scholar

[24] A. Kumar, O. V. Rambadey, and P. R. Sagdeo, 'Unorthodox Approach to Realize the Correlation between the Dielectric Constant and Electronic Disorder in Cr-Doped PrFeO 3', J. Phys. Chem. C, vol. 125, no. 13, p.7378–7383, Apr. 2021.

DOI: 10.1021/acs.jpcc.1c00203

Google Scholar

[25] O. V. Rambadey, A. Kumar, A. Sati, and P. R. Sagdeo, 'Exploring the Interrelation between Urbach Energy and Dielectric Constant in Hf-Substituted BaTiO 3', ACS Omega, vol. 6, no. 47, p.32231–32238, Nov. 2021.

DOI: 10.1021/acsomega.1c05057

Google Scholar