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A Review on the Investigation of Acetylated Starch & Silica Nanoparticles for Enhanced Oil Recovery (EOR) Application

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Abstract:

The decline in conventional oil recovery efficiency necessitates the development of advanced tertiary methods such as Enhanced Oil Recovery (EOR). This study investigates a hybrid nanofluid composed of acetylated cassava starch and silica nanoparticles for application in chemical EOR. Acetylated starch was synthesized to enhance viscosity and thermal stability, while silica nanoparticles were incorporated for their interfacial activity and wettability alteration capabilities. Comprehensive laboratory experiments were conducted to evaluate the hybrid fluid’s physicochemical, rheological, and recovery performance. Characterization using FTIR, XRD, SEM, and TGA confirmed successful functionalization and improved thermal resilience. Rheological tests demonstrated shear-thinning behavior with high viscosity retention. The hybrid fluid also achieved a 57.7% reduction in interfacial tension and altered sandstone wettability from oil-wet to strongly water-wet conditions. Core flooding tests revealed a recovery factor of 68.9%, outperforming starch-only, silica-only, and brine controls. The synergy between the polymer and nanoparticles enhanced colloidal stability, flow performance, and oil displacement efficiency under simulated reservoir conditions. The use of cassava starch as a biodegradable and locally sourced material underscores the environmental and economic viability of the formulation. These findings support the potential of acetylated starch–silica nanofluids as sustainable, high-performance EOR agents.

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Periodical:

Materials Science Forum (Volume 1181)

Pages:

61-77

DOI:

https://doi.org/10.4028/p-UTR1eW

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Online since:

March 2026

Authors:

Jakada Khaleel*, Nur Abubakar Isa, Chizoma Nwakego Adewumi, Temitayo Samson Ogedengbe, Fauziya Ramzy, Farouk Garba, Osasu Enoma Fountain

Keywords:

Nanoparticles, Oil Recovery, Recovery Factor, Silica

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© 2026 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] Abidin, A. Z., Puspasari, T., & Nugroho, W. A. (2012). Polymers for Enhanced Oil Recovery Technology. Procedia Chemistry, 4, 11–16

DOI: 10.1016/J.PROCHE.2012.06.002

Google Scholar

[2] Adeniyi, A. T., & Emmanuel, P. P. (2021). Development and evaluation of locally made polymer for improved oil recovery. Society of Petroleum Engineers - SPE Nigeria Annual International Conference and Exhibition 2021, NAIC 2021

DOI: 10.2118/207162-MS

Google Scholar

[3] Aftab, A., Ismail, A. R., Ibupoto, Z. H., Akeiber, H., & Malghani, M. G. K. (2017). Nanoparticles based drilling muds a solution to drill elevated temperature wells: A review. Renewable and Sustainable Energy Reviews, 76, 1301–1313

DOI: 10.1016/J.RSER.2017.03.050

Google Scholar

[4] Al-Asadi, A., Rodil, E., & Soto, A. (2022). Nanoparticles in Chemical EOR: A Review on Flooding Tests. Nanomaterials, 12(23)

DOI: 10.3390/NANO12234142

Google Scholar

[5] Alvarado, V., & Manrique, E. (2010). Enhanced oil recovery: An update review. Energies, 3(9), 1529–1575

DOI: 10.3390/en3091529

Google Scholar

[6] Amanullah, M., & Al-Tahini, A. M. (2009). Nano-Technology - Its Significance in Smart Fluid Development for Oil and Gas Field Application. Society of Petroleum Engineers - SPE Saudi Arabia Section Technical Symposium 2009

DOI: 10.2118/126102-MS

Google Scholar

[7] An Experimental Investigation of EOR Mechanisms for Nanoparticles Fluid in Glass Micromodel. (n.d.). Retrieved November 20, 2023, from https://www.researchgate.net/publication/272826278_An_Experimental_Investigation_of_EOR_Mechanisms_for_Nanoparticles_Fluid_in_Glass_Micromodel

DOI: 10.2118/159161-ms

Google Scholar

[8] Bhoyar, A., Patil, R., & Banerjee, S. (2022). Functional biopolymer nanocomposites for sustainable oil recovery. Carbohydrate Polymers, 283, 119178.

Google Scholar

[9] Buitrago-Rincon, D. F., Ramirez-Silva, J. A., & Leon-Vallejo, M. (2023). Performance evaluation of silica–xanthan nanofluids for enhanced oil recovery. Journal of Petroleum Science and Engineering, 222, 111226.

Google Scholar

[10] Buitrago-Rincon, D. L., Sadtler, V., Mercado, R. A., Roques-Carmes, T., Marchal, P., Muñoz-Navarro, S. F., Sandoval, M., Pedraza-Avella, J. A., & Lemaitre, C. (2023). Silica Nanoparticles in Xanthan Gum Solutions: Oil Recovery Efficiency in Core Flooding Tests. Nanomaterials, 13(5)

DOI: 10.3390/NANO13050925

Google Scholar

[11] Cheraghian, G. (2016). Effect of nano titanium dioxide on heavy oil recovery during polymer flooding. Petroleum Science and Technology, 34(7), 633–641

DOI: 10.1080/10916466.2016.1156125

Google Scholar

[12] Cheraghian, G., & Goshtasp, R. (2016). Nanotechnology in enhanced oil recovery. Petroleum Chemistry, 56(6), 628–635.

Google Scholar

[13] Cheraghian, G., & Hendraningrat, L. (2016). A review on applications of nanotechnology in the enhanced oil recovery part A: effects of nanoparticles on interfacial tension. International Nano Letters 2016 6:2, 6(2), 129–138

DOI: 10.1007/S40089-015-0173-4

Google Scholar

[14] Cheraghian, G., & Hendraningrat, L. (2016). A review on applications of nanotechnology in the enhanced oil recovery part B: effects of nanoparticles on flooding. International Nano Letters, 6(1), 1–10

DOI: 10.1007/S40089-015-0170-7

Google Scholar

[15] Copeland, L. (2020). History of Starch Research. Starch Structure, Functionality and Application in Foods, 1–7

DOI: 10.1007/978-981-15-0622-2_1

Google Scholar

[16] Dahle, G. (2014). Investigation of how Hydrophilic Silica Nanoparticles Affect Oil Recovery in Berea Sandstone : An Experimental Study.

Google Scholar

[17] do Vale, T. O., de Magalhães, R. S., de Almeida, P. F., Matos, J. B. T. L., & Chinalia, F. A. (2020). The impact of alkyl polyglycoside surfactant on oil yields and its potential effect on the biogenic souring during enhanced oil recovery (EOR). Fuel, 280, 118512

DOI: 10.1016/j.fuel.2020.118512

Google Scholar

[18] Ehtesabi, H., Ahadian, M. M., Taghikhani, V., & Ghazanfari, M. H. (2014). Enhanced heavy oil recovery in sandstone cores using TiO2 nanofluids. Energy and Fuels, 28(1), 423–430

DOI: 10.1021/EF401338C

Google Scholar

[19] El-Diasty, A. I., & Aly, A. M. (2015). Understanding the Mechanism of Nanoparticles Applications in Enhanced Oil Recovery. Society of Petroleum Engineers - SPE North Africa Technical Conference and Exhibition 2015, NATC 2015, 944–962

DOI: 10.2118/175806-MS

Google Scholar

[20] El-Diasty, A. I., & Aly, A. M. (2015). Understanding the mechanisms of nanoparticle-enhanced oil recovery: A review. Egyptian Journal of Petroleum, 24(3), 427–438.

Google Scholar

[21] Esfandyari Bayat, A., Junin, R., Derahman, M. N., & Samad, A. A. (2015). TiO2 nanoparticle transport and retention through saturated limestone porous media under various ionic strength conditions. Chemosphere, 134, 7–15

DOI: 10.1016/j.chemosphere.2015.03.052

Google Scholar

[22] Esfandyari Bayat, A., Junin, R., Shamshirband, S., & Tong Chong, W. (2015). Transport and retention of engineered Al2O3, TiO2, and SiO2 nanoparticles through various sedimentary rocks. Scientific Reports, 5

DOI: 10.1038/SREP14264

Google Scholar

[23] Gbadamosi, A. O., Junin, R., Manan, M. A., Yekeen, N., Agi, A., & Ali, M. (2019). Recent advances and prospects in polymeric nano fluids application for enhanced oil recovery. International Nano Letters, 9, 171–202

DOI: 10.1007/s40089-019-0272-8

Google Scholar

[24] Haq, F., Yu, H., Wang, L., Teng, L., Haroon, M., Khan, R. U., Mehmood, S., Bilal-Ul-Amin, Ullah, R. S., Khan, A., & Nazir, A. (2019). Advances in chemical modifications of starches and their applications. Carbohydrate Research, 476, 12–35

DOI: 10.1016/J.CARRES.2019.02.007

Google Scholar

[25] Hendraningrat, L., Li, S., & Torsæter, O. (2013). A coreflood investigation of nanofluid enhanced oil recovery. Journal of Petroleum Science and Engineering, 111, 128–138

DOI: 10.1016/J.PETROL.2013.07.003

Google Scholar

[26] Hendraningrat, L., Torsæter, O., & Li, S. (2013). Improved oil recovery by nanofluids flooding: An experimental study. SPE Enhanced Oil Recovery Conference.

DOI: 10.2118/163335-ms

Google Scholar

[27] Ikeagwu, C., & Samuel, A. (2015). The study of local polymers on enhance oil recovery. Scholars Research Library Archives of Applied Science Research, 7(6), 48–55. http://scholarsresearchlibrary.com/archive.html

Google Scholar

[28] IntechOpen. (2019). Methods for enhancing recovery of heavy crude oil. In Enhanced Oil Recovery Processes - New Technologies (Chapter 3). https://www.intechopen.com/chapters/70191

Google Scholar

[29] Investopedia. (2023). Tertiary recovery: What it means, how it works. https://www.investopedia.com/terms/t/tertiary-recovery.asp

Google Scholar

[30] Kamal, M. S., Adewunmi, A. A., Sultan, A. S., Al-Hamad, M. F., & Mehmood, U. (2017). Recent advances in nanoparticles enhanced oil recovery: Rheology, interfacial tension, oil recovery, and wettability alteration. Journal of Nanomaterials, 2017

DOI: 10.1155/2017/2473175

Google Scholar

[31] Kamal, M. S., Hussein, I. A., & Sultan, A. S. (2017). Review on nanoparticle-based fluids for EOR applications: Recent advances and challenges. Journal of Petroleum Science and Engineering, 157, 451–465.

Google Scholar

[32] Kang, W., Cao, C., Guo, S., Tang, X., Lashari, Z. A., Gao, Y., Zhang, X., Iqbal, M. W., & Yang, H. (2019). Mechanism of silica nanoparticles' better-thickening effect on amphiphilic polymers in high salinity condition. Journal of Molecular Liquids, 277, 254–260

DOI: 10.1016/J.MOLLIQ.2018.12.092

Google Scholar

[33] Kang, W., Liu, Y., Li, Y., Zhong, H., Wang, Z., & Yang, H. (2019). Experimental study of the stability and EOR performance of polymer nanocomposite solutions in harsh conditions. Fuel, 256, 115891.

Google Scholar

[34] Kazemzadeh, Y., Shojaei, S., Riazi, M., & Sharifi, M. (2019). Review on application of nanoparticles for EOR purposes: A critical review of the opportunities and challenges. Chinese Journal of Chemical Engineering, 27(2), 237–246. https://doi.org/10.1016/ J.CJCHE.2018.05.022

DOI: 10.1016/j.cjche.2018.05.022

Google Scholar

[35] Lawal, O. S. (2009). Studies on the hydroxypropylation of pigeon pea (Cajanus cajan) starch. Food Chemistry, 112(3), 728–734.

Google Scholar

[36] Li, S., & Torsæter, O. (2014). Wettability alteration to preferentially water-wet in chalk: Impact of potential determining ions on the chemical bond between surfaces and carboxylic groups. Colloids and Surfaces A, 468, 51–61.

Google Scholar

[37] Liu, H., Ramsden, L., & Corke, H. (1999). Physical Properties of Cross‐linked and Acetylated Normal and Waxy Rice Starch. Starch-Starke

DOI: 10.1002/(sici)1521-379x(199907)51:7<249::aid-star249>3.3.co;2-f

Google Scholar

[38] Machado, C. M., Benelli, P., & Tessaro, I. C. (2020). Effect of acetylated starch on the development of peanut skin-cassava starch foams. International Journal of Biological Macromolecules, 165, 1706–1716

DOI: 10.1016/J.IJBIOMAC.2020.10.048

Google Scholar

[39] Mankarious, R. A., & Radwan, M. A. (2020). Shear Thickening Fluids Comparative Analysis Composed of Silica Nanoparticles in Polyethylene Glycol and Starch in Water. Journal of Nanotechnology, 2020

DOI: 10.1155/2020/8839185

Google Scholar

[40] Nasseri, R., Ngunjiri, R., Moresoli, C., Yu, A., Yuan, Z., & Xu, C. (Charles). (2020). Poly(lactic acid)/acetylated starch blends: Effect of starch acetylation on the material properties. Carbohydrate Polymers, 229

DOI: 10.1016/J.CARBPOL.2019.115453

Google Scholar

[41] Negin, C., Ali, S., & Xie, Q. (2016). Application of nanotechnology for enhancing oil recovery – A review. Petroleum, 2(4), 324–333

DOI: 10.1016/J.PETLM.2016.10.002

Google Scholar

[42] Okonkwo, I. C. (2024). Artificial intelligence and enhanced oil recovery: Implications for Nigerian marginal fields. British Journal of Earth Sciences Research, 12(1), 22–35. https://journals.eajournals.org/index.php/BJESR/article/view/114

Google Scholar

[43] Onyekachi, O. C., Ukachukwu, D. R., Ozioma, A., & Julius, A. O. (2023). Effect of Acetylation on the Physicochemical Properties of Starch Extract from Caladium bicolor. Asian Journal of Applied Chemistry Research, 13(2), 33–45

DOI: 10.9734/AJACR/2023/V13I2241

Google Scholar

[44] Onyekonwu, M. O., & Ogolo, N. A. (2010). Investigating the Use of Nanoparticles in Enhancing Oil Recovery. Society of Petroleum Engineers - Nigeria Annual International Conference and Exhibition 2010, NAICE, 2, 974–987

DOI: 10.2118/140744-MS

Google Scholar

[45] Phillips, D. L., Liu, H., Pan, D., & Corke, H. (1999). General application of Raman spectroscopy for the determination of level of acetylation in modified starches. Cereal Chemistry, 76(3), 439–443

DOI: 10.1094/CCHEM.1999.76.3.439

Google Scholar

[46] Phillips, D. L., Prosky, L., & Onwulata, C. (1999). Determination of starch ester degree of substitution by FTIR spectroscopy. Cereal Chemistry, 76(4), 544–549.

Google Scholar

[47] Ragab, A. M. S., & Hannora, A. E. (2015). An Experimental Investigation of Silica Nano Particles for Enhanced Oil Recovery Applications. Society of Petroleum Engineers - SPE North Africa Technical Conference and Exhibition 2015, NATC 2015, 1150–1165

DOI: 10.2118/175829-MS

Google Scholar

[48] Sarah, D., Azis, M. M., Yuliansyah, A. T., & Purwono, S. (2024). On the Influence of Silica Nanoparticles for Enhanced Oil Recovery (EOR). AIP Conference Proceedings, 3073(1)

Google Scholar

[49] Shah, A., Fishwick, R., Wood, J., Leeke, G., Rigby, S., & Greaves, M. (2010). A review of novel techniques for heavy oil and bitumen extraction and upgrading. Energy & Environmental Science, 3(6), 700–714

DOI: 10.1039/B918960B

Google Scholar

[50] Shaker Shiran, B., & Skauge, A. (2013). Enhanced Oil Recovery (EOR) by Combined Low Salinity Water/Polymer Flooding. Energy and Fuels, 27(3), 1223–1235

DOI: 10.1021/EF301538E

Google Scholar

[51] Singh, S., & Ahmed, R. (2010). Vital Role of Nanopolymers in Drilling and Stimulations Fluid Applications. Proceedings - SPE Annual Technical Conference and Exhibition, 1, 71–77

DOI: 10.2118/130413-MS

Google Scholar

[52] Taborda, E. A., Franco, C. A., Lopera, S. H., Alvarado, V., & Cortés, F. B. (2016). Effect of nanoparticles/nanofluids on the rheology of heavy crude oil and its mobility on porous media at reservoir conditions. Fuel, 184, 222–232

DOI: 10.1016/J.FUEL.2016.07.013

Google Scholar

[53] Taborda, E. A., Pereira, A. H. F., & Lomba, R. F. T. (2021). Effect of nanoparticles on the flow behavior and displacement efficiency of biopolymer solutions in porous media. Journal of Molecular Liquids, 341, 117335.

Google Scholar

[54] Tang, H., & Li, X. (2017). Structural and thermal behavior of modified starch nanocomposites. Carbohydrate Polymers, 165, 270–277.

Google Scholar

[55] Tarek, A. (2010). Reservoir Engineering Handbook | ScienceDirect. https://www.sciencedirect.com/book/9781856178037/reservoir-engineering-handbook

Google Scholar

[56] Vidyadevi, T., James, N. R., & Abraham, T. E. (2023). Acetylation of starch: A critical review on properties and industrial applications. International Journal of Biological Macromolecules, 237, 124031.

Google Scholar

[57] Wang, S., Yuanjun, L., Guang, F., Jiangang, W., Po, H., Chao, X., Liang, Z., & Hui, W. (2025). Experimental Study on CO2 Injection to Enhance Recovery and its Storage Characteristics in Low Permeability Gas Reservoirs. Chemistry and Technology of Fuels and Oils, 60(6), 1542–1552

DOI: 10.1007/s10553-025-01817-y

Google Scholar

[58] Youssif, M. I., El-Maghraby, R. M., Saleh, S. M., & Elgibaly, A. (2018). Silica nanofluid flooding for enhanced oil recovery in sandstone rocks. Egyptian Journal of Petroleum, 27(1), 105–110

DOI: 10.1016/J.EJPE.2017.01.006

Google Scholar

[59] Zdybel, B., Tomasik, P., & Zięba, T. (2021). Thermal and structural characterization of starches modified by acetylation. Thermochimica Acta, 700, 178909.

Google Scholar

[60] Zdybel, E., Wilczak, A., Kapelko-Żeberska, M., Tomaszewska-Ciosk, E., Gryszkin, A., Gawrońska, A., & Zięba, T. (2021). Physicochemical Properties and Digestion Resistance of Acetylated Starch Obtained from Annealed Starch. Polymers, 13(23)

DOI: 10.3390/POLYM13234141

Google Scholar

[61] Zheng, M., Chi, C., Lian, S., Zou, Y., Chen, B., He, Y., Zhao, Y., & Wang, H. (2023). Preparation, multi-scale structures, and functionalities of acetylated starch: An updated review. International Journal of Biological Macromolecules, 249

DOI: 10.1016/j.ijbiomac.2023.126142

Google Scholar

[62] Z. Bila, A., & Torsæter, O. (2020). Enhancing oil recovery with hydrophilic polymer-coated silica nanoparticles. Energies, 13(21), 1–15

DOI: 10.3390/en13215720

Google Scholar