Preparation of Two Carbazole Derivatives and its Third-Order Nonlinear Optical Properties

Liang Li; Yi Qun Wu; Chun Ying He; Wu Biao Duan

doi:10.4028/www.scientific.net/MSF.663-665.231

Paper Titles

Investigation of Optical Properties of ZnO Films Deposited by RF Magnetron Sputtering
p.215

Study of Vacuum-Sealed Field Emission Display Device with Discrete Anode Sub-Pixel Layer
p.219

Measurement on Thermal Radiation of Standard High-Temperature Blackbody Furnace in Visible Spectrum Range
p.223

Antimony Bismuth Alloy Films: Preparation, Optical and Thermal Properties
p.227

Preparation of Two Carbazole Derivatives and its Third-Order Nonlinear Optical Properties
p.231

The Luminescence Property Study of CdTe/PMMA Emitting Green Light under Visible Light
p.235

Combustion Synthesis and Photoluminescent Properties of Ca₃((P,V)O₄)₂: Eu³⁺ Nanophosphor
p.239

Preparation and Characterization of Skin-Colored N-Doped ZnO Nanocrystals
p.243

Research on the Eye Controlled Model of Anti-Glare Imaging Detector Based on Liquid Crystal
p.247

HomeMaterials Science ForumMaterials Science Forum Vols. 663-665Preparation of Two Carbazole Derivatives and its...

Preparation of Two Carbazole Derivatives and its Third-Order Nonlinear Optical Properties

Abstract:

Carbazole derivative is one sort of important nonlinear optical materials. In this work, new symmetric-type D-π-D carbazole derivatives, 3, 6 - di- substituted carbazole chromophores with two styryl bridges of the two-dimensional conjugated D-π-D system were synthesized via Witting reaction and characterized by IR, NMR and MS. The third-order nonlinear optical properties of the material were investigated using single-beam Z-scan technique with Sapphire femtosecond laser pulses at 800nm, repetition rate of 1 KHz and pulse width of 140fs. The results of Z-scan with and without an aperture showed that larger third-order nonlinear optical polarizabilities γ can be readily obtained in such carbazole chromophores because of the incorporation with two styryl bridges, increasing of conformational planarity and molecular conjugation length.