Solid Proton Conductor Based on Natural Diatomite

Article Preview

Abstract:

Proton conductivity of the natural diatomite was studied by AC complex impedance technique. At room temperature, the highest proton conductivity was found to be 4.5 10-7 S·cm-1. By hydrating the diatomite, the proton conductivity was increased by two orders of magnitude. The room temperate proton conductivity of the hydrated diatomite (5.5 10-5 S·cm-1) was comparable to other hydrated solid proton conductors. Based on these results, the natural diatomite could be used as solid proton conductor for various electrochemical applications such as fuel cells, gas sensors, humidity sensors, and pH sensors.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 675-677)

Pages:

49-52

Citation:

Online since:

February 2011

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] S. Chandra, in: Proton Conductors in Superionic Solids and Solid Electrolytes, edited by A. Laskar and S. Chandra, Academic Press Inc. (1989).

DOI: 10.1016/b978-0-12-437075-3.50010-5

Google Scholar

[2] M. A. Villegas, J. M. Fernandez Navarro, J. Mater. Sci., Vol. 23, (1988), p.2464.

Google Scholar

[3] M. Nogami and Y. Moriya, J. Non-Cryst. Solids, Vol. 48, (1982), p.359.

Google Scholar

[4] B. Wang, S. Szu, M. Greenblatt, L. C. Klein, Chem. Mater, Vol. 4, (1992) p.191.

Google Scholar

[5] N. F. Borrelli, B. D. McSwain, G-J Su, Phys. Chem. Glasses, Vol. 4 (1963) p.11.

Google Scholar

[6] J. B. Bates, N. J. Dudney, G. R. Gruzalski, R. A. Zuhr, A. Choudhury, C. F. Luck and J. D. Robertson, Solid State Ionics, Vol. 53 – 56 (1992), p.647.

Google Scholar

[7] B. Wang, B. S. Kwak, B. C. Sales, J. B. Bates, J. Non-Cryst. Solids, Vol. 183, (1995), p.297.

Google Scholar

[8] B. Wang, J. B. Bates, F. X. Hart, B. C. Sales, R. A. Zuhr, J. D. Robertson, J. Electrochem. Soc., Vol. 143 (1996), p.3203.

Google Scholar

[9] W. A. England, M. G. Cross, A, Hamnett, P. J. Wiseman, J. B. Goodenough, Solid State Ionics, Vol. 1 (1980), p.231.

DOI: 10.1016/0167-2738(80)90007-7

Google Scholar

[10] S. Chandra, N. Singh, B. Singh, Solid State Comm., Vol. 57 (1986), p.519.

Google Scholar