Synthesis, Characterization and Thermal Properties of an Europium (III) Nanocomplex

Article Preview

Abstract:

The coordination of lanthanide íons with organic ligands has provided good luminescent properties and allows its application in molecular light converter devices, which motivates the scientific interest of seeking coordination of these íons with organic ligands that potentiate the luminescence and associate biological properties of the complexes formed. From this perspective the complex was synthesized Eu (III) with mesoionic 2(4-chlorophenyl)-3-methyl (methoxyphenyl)-1,3-thiazole-5-thiolate (MS-1) and bipy, with the aim of its possible application in the areas of photoluminescence and drug. Analyses were performed using TG, DSC, XRD and IR. The complex obtained after reaction of the lanthanide salt and organic ligands showed five stages of decomposition and different fusion of the isolated ligands.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 727-728)

Pages:

1913-1918

Citation:

Online since:

August 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] SABBATINI, N., GUARDIGU, N., LENH, J. M. Coordination Chemistry Reviews, 123, (1993).

Google Scholar

[2] JALES-FILHA, M. P. A. Síntese, Caracterização e Avaliação Biológica de Novos Compostos Mesoiônicos de Núcleo 1, 3, 4-Tiadiazólio-5-Tiolato e seus Derivados Ftalidínicos. Dissertação de Mestrado, UFPB, (2005).

Google Scholar

[3] MORAIS, C. R. S.; SOUZA, A. G.; LOPES, W. S. Synthesis and thermal characterization of luminescent powers of terbium(III) with mixed ligands. Advanced Powder Technology, Suíça. v. 499, pp.535-539, (2005).

Google Scholar

[4] NASCIMENTO, R. S. T. R. et al. Synthesis and characterization of nanocomplexes of Eu(III) and Er(III) coordinate with 2(4-clorophenil)-3-phenil-1, 3, 4-thiadiazoleo-5-tiolate mesoionic 2010. Jalcom. Ed Elservier.

DOI: 10.1016/j.jallcom.2009.12.003

Google Scholar

[5] MORAIS, C. R. S; NASCIMENTO, Railda Shelsea Taveira R; MORAIS, Soraya Alves; ATHAYDE FILHO, Petrônio Filgueiras; Synthesis and characterization of nanocomplexes of Eu(III) and Er(III) coordinate with 2(4-clorophenil)-3-phenil-1, 3, 4-thiadiazoleo-5-tiolate mesoionic. Jalcom. Ed Elservier JCR, v. 495, pp.603-605, (2009).

DOI: 10.1016/j.jallcom.2009.12.003

Google Scholar

[6] MORAIS, Soraya Alves de; MORAIS, C. R. S.; ATHAYDE FILHO, Petrônio Filgueiras de; B. Freitas Lira; NASCIMENTO, Railda Shelsea Taveira Rocha. A kinetic study of the thermal decomposition of mesoionic compounds within scope of its application in nonlinear optical devices. JTACJCR, v. 97, pp.1572-8943, (2009).

DOI: 10.1007/s10973-009-0082-8

Google Scholar

[7] LIRA, B. F.; Athayde-Filho; P.F.; Miller, J.; Simas, A .M.; Dias, A. de F.; Vieira, M. J., Synthesis and Characterization of some New Mesoionic 1, 3-Thiazolium-5-thiolates via Cyclodehydration and in situ 1, 3-Dipolar Cycloaddition/Cycloreversion, Molecules 2002, 7, 791-800.

DOI: 10.3390/71100791

Google Scholar

[8] ATHAYDE-FILHO, P. F, Tese de Doutorado – DQF, UFPE, (1999). 9 CHENG, M. T, e Rinehart, K. L, JACS, 100-7411 (1978). 10 FREY, S. T, Gong, M. L, De. W Horrocks, Inorg. Chem, 33 (15), 3229 (1994).

Google Scholar

[9] CHENG, M. T, e Rinehart, K. L, JACS, 100-7411 (1978).

Google Scholar

[10] FREY, S. T, Gong, M. L, De. W Horrocks, Inorg. Chem, 33 (15), 3229 (1994).

Google Scholar