Isothermal Corrosion Behaviors of TiAl–Nb Alloys in Liquid Zn-55Al-1.6Si (wt.%)

Article Preview

Abstract:

The isothermal static corrosion of Ti-45Al-8Nb and Ti-53Al-20Nb (at.%) in liquid Zn-55Al-1.6Si (wt.%) at 630°C was studied. Incubation periods without any corrosion occurred are exhibited in both alloys. After the incubation time, the corrosion rate increases noticeably which is controlled by the reaction-diffusion and dissolution mechanism. Thick transition layers were formed. The EDS results show that Si and Al diffused into the TiAl-Nb alloys preferentially, while Zn was hindered from diffusing and segregated in spots. All the transition layers are porous and composed mainly of Al3Ti (Nb), SiTi and AlNbZn2. The fracture of the transition layers of Ti-45Al-8Nb should be attributed to the defects of the lamellar colony boundaries. nanoIndenter was used to check the mechanical properties of the materials. The results show that the transition layers have higher micro-hardness and elastic modulus than the matrix.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 747-748)

Pages:

69-76

Citation:

Online since:

February 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] B. G. Seonga, S. Y. Hwanga, M. C. Kim, et al, Reaction of WC/Co coating with molten zinc in a zinc pot of a continuous galvanizing line, Surf. Coat. Technol. 138 (2001) 101-110.

DOI: 10.1016/s0257-8972(00)01136-1

Google Scholar

[2] K. Zhang, L. Battiston, Friction and wear characterization of some cobalt- and iron-based superalloys in zinc alloy baths, Wear 252 (2002) 332-344.

DOI: 10.1016/s0043-1648(01)00889-4

Google Scholar

[3] K. Zhang, L. Battiston, Sliding wear of various materials in molten zinc, Mater. Sci. Tech. 18 (2002) 1551-1560.

DOI: 10.1179/026708302225007682

Google Scholar

[4] D. M. Dimiduk, Gamma titanium aluminide alloys-an assessment within the competition of aerospace structural materials, Mater. Sci. & Eng. A 263 (1999) 281-288.

DOI: 10.1016/s0921-5093(98)01158-7

Google Scholar

[5] W. J. Wang, J. P. Lin, Y. L. Wang, et al, Isothermal corrosion TiAl-Nb alloy in liquid zinc, Mater. Sci. & Eng. A 452 (2007) 194-201.

DOI: 10.1016/j.msea.2006.10.152

Google Scholar

[6] P. Qiu, C. Leygraf, I. O. Wallinder, Evolution of corrosion products and metal release from Galvalume coatings on steel during short and long-term atmospheric exposures, Mater. Chem. & Phys. 133 (2012) 419-428.

DOI: 10.1016/j.matchemphys.2012.01.054

Google Scholar

[7] P. F. Sun, L. Q. Zhang, J. P. Lin, Improvement in the liquid zinc corrosion resistance of high Nb-TiAl alloys by pre-oxidation in a SiO2-powder pack, Sci. Chin. (Technol. Sci. ) 55(2012) 505-509.

DOI: 10.1007/s11431-011-4700-x

Google Scholar

[8] J. McMinis, R. Crombez, E. Montalvo, et al, Determination of the cross-sectional area of the indenter in nano-indentation tests, Physica. B 391 (2007) 118-123.

DOI: 10.1016/j.physb.2006.09.006

Google Scholar