Optical and Photovoltaic Properties of CdS/Ag2S Quantum Dots Co-Sensitized-Solar Cells

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Subscript textWe present a co-sensitization of CdS/Ag2S quantum-dot as sensitizers for solar cells. The optical properties of single and double-layered quantum-dot conditions were monitored using UV-Vis spectrophotometer. The results show that the different characteristics of absorption spectra depended on the types of QDs, indicating to the different energy gap of each QDs deposited on TiO2 surface and the tunable absorption ranges of the sample of double-layered quantum-dot-sensitized TiO2 electrodes are broader and the absorption intensity are higher than the single-layered quantum-dot, attributed to the co-absorption of two QDs to the light and both CdS and Ag2S are activated in visible to near-infrared region (450-1100 nm). The photovoltaic data shows that the highest efficiency of 1.41% with a photocurrent density, Jsc of 20.6 mA/cm2, an open-circuit voltage, Voc of 0.32 V and a fill factor, FF of 21.3% were yielded by the sample of CdS(3)/Ag2S(4) as an optimum condition of dipping cycles for CdS and Ag2S under irradiance of 100 mW/cm2 (AM 1.5G).

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15-18

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July 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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