Investigation of the Microstructure and Bio-Corrosion Behaviour of Mg-Zn and Mg-Zn-Ca Alloys

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Biomedical applications of magnesium alloys have attracted increasing attention due to their unique combination of advantages. However, the poor corrosion resistance is an obstacle to magnesium alloys being used as biodegradable materials. As zinc (Zn) and calcium (Ca) are non-toxic and recognized as nutritionally essential elements in the human body, in this study Zn and Ca were selected as alloying elements to produce suitable bio-corrosion properties. The grain size was reduced significantly from 141.4 μm to 97.3 μm by adding Ca. The bio-corrosion performance of the two alloys (Mg-3Zn and Mg-3Zn-0.3Ca) was characterized using immersion tests in simulated body fluid at 37 °C. The alloys were dominated by pitting corrosion. Heat treatment was used to alter the microstructure and influence further the corrosion rate. The correlation between microstructure and bio-corrosion rate was evaluated, in the light of the alloying elements and the heat treatment employed.

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July 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] F. Witte, J. Fischer, J. Nellesen, H.A. Crostack, V. Kaese, A. Pisch, F. Beckmann, H. Windhagen, In vitro and in vivo corrosion measurements of magnesium alloys, Biomaterials 27 (2006) 1013-1018.

DOI: 10.1016/j.biomaterials.2005.07.037

Google Scholar

[2] F. Witte, V. Kaese, H. Haferkamp, E. Switzer, A. Meyer-Lindenberg, C.J. Wirth, H. Windhagen, In vivo corrosion of four magnesium alloys and the associated bone response, Biomaterials 26 (2005) 3557-3563.

DOI: 10.1016/j.biomaterials.2004.09.049

Google Scholar

[3] G.L. Song, Control of biodegradation of biocompatable magnesium alloys, Corros. Sci. 49 (2007) 1696-1701.

DOI: 10.1016/j.corsci.2007.01.001

Google Scholar

[4] G. Mani, M.D. Feldman, D. Patel, C.M. Agrawal, Coronary stents: A materials perspective, Biomaterials 28 (2007) 1689-1710.

DOI: 10.1016/j.biomaterials.2006.11.042

Google Scholar

[5] C.T. Walsh, H.H. Sandstead, A.S. Prasad, P.M. Newberne, P.J. Fraker, Zinc - Health-Effects and Research Priorities for the 1990s, Environmental Health Perspectives 102 (1994) 5-46.

DOI: 10.2307/3431820

Google Scholar

[6] Z.J. Li, X.N. Gu, S.Q. Lou, Y.F. Zheng, The development of binary Mg-Ca alloys for use as biodegradable materials within bone, Biomaterials 29 (2008 ) 1329-1344.

DOI: 10.1016/j.biomaterials.2007.12.021

Google Scholar

[7] Y.W. Song, E.H. Han, D.Y. Shan, C.D. Yim, B.S. You, The role of second phases in the corrosion behavior of Mg-5Zn alloy, Corros. Sci. 60 (2012) 238-245.

DOI: 10.1016/j.corsci.2012.03.030

Google Scholar

[8] H.R. Bakhsheshi-Rad, M.R. Abdul-Kadir, M.H. Idris, S. Farahany, Relationship between the corrosion behavior and the thermal characteristics and microstructure of Mg-0.5Ca-xZn alloys, Corros. Sci. 64 (2012) 184-197.

DOI: 10.1016/j.corsci.2012.07.015

Google Scholar

[9] E.L. Zhang, L. Yang, J.W. Xu, H.Y. Chen, Microstructure, mechanical properties and bio-corrosion properties of Mg-Si(-Ca, Zn) alloy for biomedical application, Acta Biomaterialia 6 (2010) 1756-1762.

DOI: 10.1016/j.actbio.2009.11.024

Google Scholar

[10] G.L. Song, A. Atrens, Corrosion mechanisms of magnesium alloys, Adv. Eng. Mater. 1 (1999) 11-33.

Google Scholar

[11] M.C. Zhao, M. Liu, G.L. Song, A. Atrens, Influence of the beta-phase morphology on the corrosion of the Mg alloy AZ91, Corros. Sci. 50 (2008) 1939-1953.

DOI: 10.1016/j.corsci.2008.04.010

Google Scholar

[12] T. Kokubo, H. Takadama, How useful is SBF in predicting in vivo bone bioactivity?, Biomaterials 27 (2006) 2907-2915.

DOI: 10.1016/j.biomaterials.2006.01.017

Google Scholar

[13] D.H. StJohn, M. Qian, M.A. Easton, P. Cao, Z. Hildebrand, Grain refinement of magnesium alloys, Metall. Mater. Trans. A 36 (2005) 1669-1679.

DOI: 10.1007/s11661-005-0030-6

Google Scholar

[14] Y.C. Lee, A.K. Dahle, D.H. StJohn, The role of solute in grain refinement of magnesium, Metall. Mater. Trans. A 31 (2000) 2895-2906.

DOI: 10.1007/bf02830349

Google Scholar

[15] H.R.B. Rad, M.H. Idris, M.R.A. Kadir, S. Farahany, Microstructure analysis and corrosion behavior of biodegradable Mg-Ca implant alloys, Mater. Design 33 (2012) 88-97.

DOI: 10.1016/j.matdes.2011.06.057

Google Scholar

[16] H.S. Brar, J. Wong, M.V. Manuel, Investigation of the mechanical and degradation properties of Mg-Sr and Mg-Zn-Sr alloys for use as potential biodegradable implant materials, J. Mech. Behav. Biomed. Mater. 7 (2012) 87-95.

DOI: 10.1016/j.jmbbm.2011.07.018

Google Scholar