Free Machining Brasses with Minimized Lead Content

Article Preview

Abstract:

Last 15 years is in the sign of increasing pressure on decreasing of content of toxic metals in consumer products. Widely known are legislative rules on decreasing the content of cadmium, hexavalent chromium and mercury in various products for their negative effect on environment and human health. Similar legislative acts take care of lead content in free machined brass. For example rules that come from directive of European Council 98/83/ES released on November the 3rd 1998 command, that maximum content of lead in brass products which are in contact with drinking water has to be less than 1%. Similar and stronger rules are applied in California by the law AB 1953 which reduces the lead content in these brass products under 0,25 %. Article describes the role of lead in free machining brass and describes the problems of its substitution by means of other elements and phases for bringing similar machinability as in case of brass with lead. Article also introduces experiments with melting of new brass with substitution of lead. Microstructures of experimental heats are shown and further experiments are described.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

421-426

Citation:

Online since:

April 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Imai, H. et al., Characteristics and machinability of lead-free P/M Cu60–Zn40 brass alloys dispersed with graphite, Powder Technology 198 (2010) 417–421.

DOI: 10.1016/j.powtec.2009.12.010

Google Scholar

[2] C. Vilarinho et al., Influence of the chemical composition on the machinability of brasses, Journal of Materials Processing Technology 170 (2005) 441–447.

DOI: 10.1016/j.jmatprotec.2005.05.035

Google Scholar

[3] P. -J. Le Thomas, D. Arnaud, Influence des impuretés sur les proprietés des laitons, Fonderie 162 (1959) 323–325 (in French).

Google Scholar

[4] COUNCIL DIRECTIVE 98/83/EC [online]. europa. eu [cited 2013-04-18]. available at http: /eur-lex. europa. eu/LexUriServ/LexUriServ. do?uri=OJ: L: 1998: 330: 0032: 0054: EN: PDF.

Google Scholar

[5] California's AB1953 Law [online]. [cited 2013-04-18] available at http: /info. sen. ca. gov/pub/05-06/bill/asm/ab_1951-2000/ab_1953_bill_20060930_chaptered. html.

Google Scholar

[6] Mohamed A. Taha et al., Machinability characteristics of lead free-silicon brass alloys as correlated with microstructure and mechanical properties, Ain Shams Engineering Journal (2012) 3, 383–392.

DOI: 10.1016/j.asej.2012.05.004

Google Scholar

[7] King, Michael G. et al., Selenium's role in new free/machining brass alloys, Modern Casting; Aug 1997; 87, 8; ProQuest pg. 53.

Google Scholar

[8] ALLOY DATA SHEET [online]. [cited 2013-04-18] available at http: /www. copper. org/applications/industrial/PDF_files/sebiloy. PDF.

Google Scholar

[9] Cu-Pb, Cu-Bi Phase Diagrams, ASM Alloy Phase Diagrams Center, P. Villars, editor-in-chief; H. Okamoto and K. Cenzual, section editors; ASM International, Materials Park, OH, 44073, USA.

DOI: 10.1002/adma.19910031215

Google Scholar

[10] Martinez-Hernandez, M. et al., Bismuth segregation and crack formation on a free lead yellow brass tap, Engineering Failure Analysis 28 (2013) 63–68.

DOI: 10.1016/j.engfailanal.2012.10.002

Google Scholar

[11] La Fontaine. A. et al., Compositional distributions in classical and lead-free brasses, Materials Characterization 57 (2006) 424–429.

DOI: 10.1016/j.matchar.2006.02.005

Google Scholar

[12] Atsumi, H. et al., High-strength, lead-free machinable α - β duplex phase brass Cu–40Zn–Cr–Fe–Sn–Bi alloys, Materials Science and Engineering A 529 (2011) 275– 281.

DOI: 10.1016/j.msea.2011.09.029

Google Scholar

[13] S. Li et al., Fabrication and properties of lead-free machinable brass with Ti additive by powder metallurgy, Powder Technology 205 (2011) 242–249.

DOI: 10.1016/j.powtec.2010.09.020

Google Scholar