Study and Characterization of Chocolate B Clay on Adsorption of Heavy Metals (Lead and Zinc) in Bath Finite System

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Abstract:

The clays are emerging as excellent alternative materials in the process of removing organic and inorganic contaminants, that due to it's physicochemical characteristics, it’s easy to obtain and also for low cost. The initial objective of this ( study was to characterize the clay Chocolate B by the techniques of X-ray diffraction (XRD) and cation exchange capacity (CEC). In addition, the testing of finite bath under certain conditions (pH, concentration) in order to better evaluate the efficiency of clay in the removal of heavy metals zinc and lead. It was used a factorial design 22 with addition at the central point, being evaluated the percentage removal (% Rem) and the removal capacity (qeq) by Chocolate B Clay. It was observed that the Chocolate B clay belongs to the smectites group. The results have shown promise in the removal process of the metals zinc and lead by Chocolate B clay.

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Materials Science Forum (Volumes 798-799)

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582-587

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June 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] J.D. Mota, Modificação e caracterização de argila esmectita Chocolate B visando seu uso no processo de tratamento de águas contaminadas por metais pesados. Dissertação de Mestrado. Universidade Federal de Campina Grande -PB, 2013. (In Portuguese).

DOI: 10.14393/19834071.2013.24194

Google Scholar

[2] J-Q. Jiang, S.M. Ashekuzzaman, Development of novel inorganic adsorbent for water treatment. Curr. Opin. Chem. Eng. 1 (2012) 192 – 199.

Google Scholar

[3] A. Demirbas, Heavy metal adsorption onto agro-based waste materials: a review. J. Hazard. Mater. 157 (2008) 220 – 229.

DOI: 10.1016/j.jhazmat.2008.01.024

Google Scholar

[4] F. Ayari, E. Srasra and M. Trabelsi-Ayadi, Characterization of bentonitic clays and their use as adsorbent. Desalination, 185 (2005) 391–397.

DOI: 10.1016/j.desal.2005.04.046

Google Scholar

[5] S.E. Bailey, T.J. Olin, R.M. Brika and D.D. Adrian, A review of potentially low-cost sorbents for heavy metals. Water Res. 33 (1999) 2469–2479.

DOI: 10.1016/s0043-1354(98)00475-8

Google Scholar

[6] F. Ayari, E. Srasra and M. Trabelsi-Ayadi, Retention of leed from aqueous solution by use bentonite as adsorbent for reducing leaching from industrial effluents. Desalination, 206 (2006) 270–278.

DOI: 10.1016/j.desal.2006.03.569

Google Scholar

[7] S.A. Khan, R.U. Rehman and M.A. Khan, Sorption of cesium on bentonite. Waste Manage. 14 (1994) 629.

DOI: 10.1016/0956-053x(94)90035-3

Google Scholar

[8] S.F. Abreu, Recursos minerais do Brasil. Edgard Blücher Ltda Ed, São Paulo, 1973, p.324.

Google Scholar

[9] W.S. Lima, Estudo da aplicação de argilas para atenuação de metais pesados destinadas à aplicação em aterro de resíduo industrial. Dissertação de Mestrado em Engenharia Química, Universidade Federal de Campina Grande – PB, 2011. (In Portuguese).

DOI: 10.36229/978-85-7042-207-1

Google Scholar

[10] M.F. Mota, J.A. Silva, M.B. Queiroz, H.M. Laborde, M.G.F. Rodrigues, J. Braz. Organophilic Clay for oil/water separation process by finite bath tests, Petr. G., pp.097-107, (2011).

DOI: 10.5419/bjpg2011-0011

Google Scholar

[11] M.G.F. Rodrigues, Physical and catalytic characterization of smectites from Boa-Vista, Paraíba, Brazil. Cerâmica, 49 (2003) 146 -150.

DOI: 10.1590/s0366-69132003000300007

Google Scholar

[12] D.C. Montgomery, Desing and Analysis of Experiments, Jonh Wiley & Sons, New York, (1996).

Google Scholar

[13] J.H. Choy, S.Y. Kwak, Y.S. Han, B.W. Kim, New organo-montmorillonite complexes with hydrophobic and hydrophilic functions. Mat. Let. 33 (1997) 143-147.

DOI: 10.1016/s0167-577x(97)00092-x

Google Scholar

[14] P. Souza Santos, Ciência e Tecnologia de Argilas. Segunda (Eds). Edgard Blücher Ltda, (1992).

Google Scholar

[15] C.F. Gomes, Argilas: O Que São e Para que Servem, Fundação Calouste Gulbenkian, Lisboa, (1988).

Google Scholar

[16] R.E. Grim, Clay mineralogy (International Series in the Earth and Planetary Sciences). McGraw-Hill, New York, (1968).

Google Scholar

[17] A. Kaya, A.H. Oren, Adsorption of Zinc Aqueous Solutions to Bentonite, J. Hazard. Mater. 125 (2005) 183-189.

Google Scholar