Dry Aggregate Particle Size Distribution Optimization for Soderberg Anode Paste Production Applied to Aluminum Industry

Abstract:

For a Soderberg Technology, paste production process consists of four basic steps: raw material handling; dry aggregate preparation; mixing; and briquettes loading at electrolytic cells for aluminum production. Dry aggregate is prepared from calcined petroleum coke, where the grains are crushed and separated between 3 different fractions of pre-determined sizing and a dust component. Petroleum pitch blended with the finest particles from dry aggregate forms the binder used for wetting, lubricating and filling open pores of larger coke grains, resulting into a higher anode paste quality with adequate mechanical properties, higher density, oxidation resistance and lower electrical resistivity. Raw materials recent trends showed significant quality degradation and cost raise, pushing up industry to look forward for untraditional suppliers, in addition to process optimization. This paper describes enablers chosen to improve paste properties, through dry aggregate particle size distribution using two of the most traditional particle packing models: Andreasen and Alfred. The formulations developed in this work were compared to the formulation originally used by an industry through measures flowability and apparent baked density. The results have shown that both the equations of Alfred and Andreasen, for distribution coefficient 0.30 and 0.52 respectively, can be applied to the Aluminum Industry, resulting into products significantly different from the point of view of quality.

• Periodical: Materials Science Forum (Volume 802)
• Pages: 291-296
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.802.291
• Online since: December 2014
• Authors: Beatriz Furquim Vry*, Walter Pomarico, Fabio Ferraço, Rodrigo Sampaio Fernandes, Sylma Carvalho Maestrelli
• Keywords: Alfred Packing Model, Aluminium, Andreasen Packing Model, Particle Size Distribution, Petroleum Coke

References

[1] W.K. Fisher: Anodes for the Aluminum Industry. (First ed., R&D Carbon Ltd, 1995).

[2] W.K. Fisher, F. Keller, R.C. Perruchoud: Light Metals (1991), p.681.

[3] I.R. Oliveira, A.R. Studart, R.G. Pileggi, V.C. Pandolfelli, Dispersão e empacotamento de partículas: Princípios e aplicações em processamento cerâmico. Fazendo Arte Editorial, São Paulo, (2000).

[4] J.E. Funk, D.R. Dinger: Interceram Vol. 41 (1992), p.10.

[5] American Society for Testing and Materials (ASTM), Standard Test Method for Apparent Density by Physical Measurements of Manufactured Anode and Cathode Carbon Used by the Aluminum Industry. D5502 – 00, (2010).

DOI: 10.1520/d5502-94r99e01