Influence of Yb2O3 and Y2O3 on the Mechanical Properties of Porous Si3N4 Ceramics

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Using Yb2O3 or Y2O3 as s single sintering additive, the porous Si3N4 ceramics with excellent mechanical properties were successfully fabricated by pressureless sintering. The influence of Y2O3 and Yb2O3 on the microstructure and mechanical properties of porous Si3N4 ceramics was investigated. The results show that both sintering additives can effectively promote α to β phase transformation, and microstructures with elongated β-Si3N4 grains interlocking and superimposing on each other can be obtained. However, sinterability, phase transformation and mechanical properties of the porous Si3N4 ceramics with Yb2O3 were more excellent than the ceramics with Y2O3. The specimens with Yb2O3 had high aspect ratio β-Si3N4 grains, and formed the high melting crystalline Yb4Si2N2O7.

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April 2015

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[1] S. Hampshire, Silicon nitride ceramics-review of structure, processing and properties, J. Achi. Mater. Manu. Eng. 24(2007) 43-50.

Google Scholar

[2] M.H. Bocanegra-Bernala, B. Matovic, Dense and near-net-shape fabrication of Si3N4 ceramics, Mater. Sci. Eng., A. 500 (2009) 130-149.

DOI: 10.1016/j.msea.2008.09.015

Google Scholar

[3] J. Yang, J.F. Yang, S.Y. Shan, J.Q. Gao, Effect of sintering additives on microstructure and mechanical properties of porous silicon nitride ceramics, J. Am. Ceram. Soc. 89(2006) 3843-3845.

DOI: 10.1111/j.1551-2916.2006.01294.x

Google Scholar

[4] H.H. Lu, J.L. Huang, Effect of Y2O3 and Yb2O3 on the microstructure and mechanical properties of silicon nitride, Ceram. Int. 27(2001) 621-628.

DOI: 10.1016/s0272-8842(01)00008-6

Google Scholar

[5] Y.V. Bykov, O.I. Get'man, V.V. Panichkina, I.V. Plotnikov, V.V. Skorokhod, V.V. Kholoptsev, Sintering of Si3N4 ceramics with additives containing yttrium and ytterbium oxides with microwave and traditional heating, Powder Metall. Met. Ceram. 40(2001).

Google Scholar

[6] X. Lu, X.S. Ning, W. Xu, K.X. Chen, H.P. Zhou, Effect of CeO2,Dy2O3,Yb2O3 and Y2O3 additives on thermal conductivity of silicon nitride ceramics, Rare Met. Mater. Eng. 34 (2005) 1112-1114.

Google Scholar

[7] J.F. Tong, L. S Zhong, D.M. Chen, M. F Han, Microstructure and performance of silicon nitride ceramics with Lu2O3 additives, Rare Met. Mater. Eng. 38(2009) 106-109.

Google Scholar

[8] M. Kitayama, K. Hirao, K. Watari, M. Toriyama, S. Kanzaki, Thermal conductivity of beta-Si3N4: III, effect of rare-earth (RE=La, Nd, Cd, Y, Yb, and Sc) oxide additives, J. Am. Ceram. Soc. 84(2001) 353-358.

DOI: 10.1111/j.1151-2916.2001.tb00662.x

Google Scholar

[9] H. Park, H.E. Kim, K. Niihara, Microstructural evolution and mechanical properties of Si3N4 with Yb2O3 as a sintering additive, J. Am. Ceram. Soc. 80(1997) 750-576.

DOI: 10.1002/chin.199725011

Google Scholar

[10] K.M. Lee, W.H. Lee, Y.H. Koh, J.J. Choi, H. E. Kim, S.S. Baek, Microstructural evolution and mechanical properties of gas-pressure-sintered Si3N4 with Yb2O3 as a sintering aid, J. Mater. Res. 14 (1999) 1904-(1909).

DOI: 10.1557/jmr.1999.0255

Google Scholar

[11] T. Nishimura, M. Mitomo, High temperature strength of silicon nitride ceramics with ytterbium silicon oxynitride, J. Mater. Res. 12(1997) 203-209.

DOI: 10.1557/jmr.1997.0027

Google Scholar

[12] J.F. Yang, Z.Y. Deng, T. Ohji, Fabrication and characterization of porous silicon nitride ceramics using Yb2O3 as sintering additive, J. Eur. Ceram. Soc. 23 (2003) 371-378.

DOI: 10.1016/s0955-2219(02)00175-9

Google Scholar

[13] R. L. Coble, W. D. Kingery,  Effect of porosity on physical properties of sintered alumina, J. Am. Ceram. Soc. 39 (1956) 377-385.

DOI: 10.1111/j.1151-2916.1956.tb15608.x

Google Scholar

[14] E. Ryshkewitch, Compression strength of porous sintered alumina and zirconia, J. Am. Ceram. Soc. 36(1953) 65-68.

DOI: 10.1111/j.1151-2916.1953.tb12837.x

Google Scholar

[15] X.W. Zhu, Y. Zhou, K. Hirao, T. Ishigaki, Y. Sakka, Potential use of only Yb2O3 in producing dense Si3N4 ceramics with high thermal conductivity by gas pressure sintering, Sci. Technol. Adv. Mater , 11(2010) 1-11.

DOI: 10.1088/1468-6996/11/6/065001

Google Scholar

[16] W.K. Li, D.Y. Chen, B.L. Zhang, H.R. Zhuang, W.L. Li, Effect of rare-earth oxide additiveson the morphology of combustion synthesized rod-like-Si3N4 crystals, Mater. Lett. 58(2004) 2322-2325.

DOI: 10.1016/j.matlet.2004.02.010

Google Scholar

[17] F.L. Yu, P.P. Yu, J.Z. Wang, J.F. Yang, Effects of sintering additive and β-Si3N4 phase contents on the properties of porous Si3N4 ceramics, J. Synth. Cryst. 40 (2011) 772-779.

Google Scholar