Modulated Synthesis of UiO-67 for High Resistance to CH₂Cl₂

Abstract:

UiO-67 has been synthesized by using the acetic acid as a template via conventional electric (CE) heating method. With the same adding of acetic acid, different crystallinity and pore structure are obtained through change the order of addition of acetic acid. The BET surface area and total pore volume are 2861 m² g^-1 and 1.14 cm³ g^-1 for of CE-0-3, and 1650 m² g^-1 and 0.67 m² g^-1 for CE-1-2, respectively. Although CE-0-3 has a better crystallinity, higher BET surface area and total pore volume than those of CE-1-2, CE-1-2 presents a better resistance to CH₂Cl₂ than CE-0-3.

• Periodical: Materials Science Forum (Volume 852)
• Pages: 609-613
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.852.609
• Online since: April 2016
• Authors: Long Yang, Li Xian Sun, Fen Xu, Yong Jin Zou, Hai Liang Chu
• Keywords: Metal-Organic Framework, Modulated Synthesis, UiO-67

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