Zeolite Loaded Alginate Membrane for CO2 and CH4 Separation

Syardah U. Adawiyah; Adhitasari Suratman; Endang Tri Wahyuni

doi:10.4028/www.scientific.net/MSF.901.166

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HomeMaterials Science ForumMaterials Science Forum Vol. 901Zeolite Loaded Alginate Membrane for CO2 and CH4...

Zeolite Loaded Alginate Membrane for CO₂ and CH₄ Separation

Abstract:

Natural zeolite-incorporated alginate membranes were subjected for the gas separation of CO₂ and CH₄. High concentration of CO₂ as biogas product can decrease the combution heat. Therefore, the membrane permeability and selectivity of CO₂ and CH₄were investigated. The zeolite-incorporated alginate membranes were prepared using solution technique. The effects of zeolite on the performance and the thickness of membranes for gas separation were analyzed. The membranes were characterized by Fourier Transform Infrared (FTIR), Scanning Electron Microscopy (SEM), Brunaur Emmet Teller (BET) and Barret Joyner Hallenda (BJH).The result of permeability and selectivity show that membrane can flow CO₂ and resist CH₄. CO₂ permeability increased simultaneously with an increase of zeolite content in the polymer matrix. The thickness of membrane influenced the flux of CO₂ gas. CO₂ Permeability increased simultaneously with a decrease of membrane thickness. The membrane containing rasio of mass alginate:zeolite 10:2 and thickness of 0.1267 mm shows the best permeability. According BJH result, pore diameter of membrane is 3.64 Å, while kinetic diameter of CO₂ is 3.30Å and kinetic diameter of CH₄ is 3.80Å. This was explained performance of membrane was molecular sieving.

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Periodical:

Materials Science Forum (Volume 901)

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166-172

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https://doi.org/10.4028/www.scientific.net/MSF.901.166

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Online since:

July 2017

Authors:

Syardah U. Adawiyah, Adhitasari Suratman*, Endang Tri Wahyuni

Keywords:

Alginate, CH₄, CO₂, Separation, Zeolite

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