Assessment of the Structural State of the Amorphous Alloys Thin Surface Layers

Abstract:

The complex approach based on the combination of methods of equilibrium thermodynamics and x-ray electron spectroscopy for layer-by-layer analysis of the composition of surface layers of amorphous alloys is described on the example of Fe-Si-B-Nb-Cu alloy.

• Periodical: Materials Science Forum (Volume 946)
• Pages: 174-180
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.946.174
• Online since: February 2019
• Authors: Olga M. Kanunnikova*, O.Yu. Goncharov, V.I. Lad’yanov
• Keywords: Amorphous Alloys, Concentration Profiles, Surface Layers, Thermodynamic Analysis, X-Ray Photoelectron Spectroscopy

References

[1] V.I. Povstugar, A.A. Shakov, S.S. Mihajlova, E.V. Voronina, E.P. Elsukov, Razlozhenie slozhnyh rentgeno-fotojelektronnyh spektrov s pomoshhju bystrogo diskretnogo preobrazovanija Furye i uluchshennoj proceduroj shodimosti reshenija. Ocenka primenimosti metodiki, J.Analit. Chem. 53, 8(1998) 795-799.

[2] N.A. Vatolin, G.K. Moiseev, B.G. Trusov, Termodinamicheskoe modelirovanie v vysokotemperaturnyh neor-ganicheskih sistemah. Moscow: Metallurgija, (1994).

[3] O.Ju. Goncharov, Termodinamicheskoe modelirovanie vysokotemperaturnogo okislenija splavov Fe-Cr na vozduhe, Neorg. mat. 40, 12 (2004) 1476-1482.

[4] V.A. Volkov, V.I. Ladyanov, V.S. Cepelev, Osobennosti poverhnostnoj i ob#emnoj kristallizacii lent amorfnogo splava Fe76,1Si13,8V6,1Nb3Cu, Metally, 6 (1998) 37-43.

[5] S.F. Lomayeva, O.M. Kanunnikova, V.I. Povstugar, AFM and XPS investigation of surface layers of nanocrystalline FeSiBNbCu, Phys. Low-Dim. Str. 3/4(2001) 271-276.

[6] H.M. Naguib, R.Kelly, Criteria for bombardment-induced structural changes in non-metallic solids, Radiation effects. 25 (1975)1-12.

DOI: 10.1080/00337577508242047

[7] P.H. Holloway, P. Bhattacharia, Limitation of ion etching for interface analysis, Surf. Interface Anal. 3 (1981)118-125.

DOI: 10.1002/sia.740030305

[8] R.Kelly, On the problem of whether mass of chemical bonding is more important to bombardment-induced compositional changes in alloys and oxide, Surf. Sci. 100 (1980) 85-107.

DOI: 10.1016/0039-6028(80)90446-x

[9] G.K. Wolf, Chemical effects of ion bombardment, Instr. Inorg. Chem. 83 (1979)1-34.

[10] S.Hoffmann, Quantitative depth profiling in surface analysis: a review, Surf. Interface Anal., 2, 4 (1988)148-160.

[11] I.L. Lomaev, S.F. Lomaeva, Application of atomic force microscopy and x-ray photoelectron spectroscopy to measuring thickness of surface coating for nanostructured materials, Phys. Low-Dim. Struct., 2/3 (2003) 175-182.

[12] Y.Teraoka, M.Komaki, Surface segregation and surface melting in segregating alloys, Surf. Sci. 439 (1999) 1-13.

DOI: 10.1016/s0039-6028(99)00670-6

[13] F.Z. Gilmutdinov, O.M. Kanunnikova, Prognozirovanie izmenenij sostava poverhnosti mnogokomponent-nyh splavov pri termicheskih vozdejstvijah, FMM. 84, 2 (1997) 78-88.

[14] Diagrammy sostojanija dvojnyh i mnogokomponentnyh sistem na osnove zheleza. Spravochnik. Pod.red. Ban-nyh O.A., Drica M.E. M.: Metallurgija. (1986).

[15] O.Ju.Goncharov, O.M. Kanunnikova, S.F. Lomaeva, A.A. Shakov, Sostav poverhnostnyh sloev, obrazujushhihsja pri poluchenii amorfnogo splava Fe70Cr15B15, FMM. 91, 6 (2001)64-71.

[16] O.M. Kanunnikova, S.F. Lomaeva, F.Z. Gilmutdinov, A comparative analysis of surface layers of amorphous Fe70Cr156B15 alloy by means of atomic force microscopy and x-ray еlectron spectroscopy, Phys. Low-Dim. Struct. 3/ 4 (2001) 333-340.

[17] A.P. Brovko, V.V. Maslo, D.Ju. Paderno, O prirode kristallov na kontaktnoj poverhnosti amorfnyh lent splavov (Fe,Cr)85B15, Metallofizika. 12, 4 (1990)116-119.