Influence of Co Moment on Magnetic Properties of Co2Sm2W3O14 Tungstate

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The Co2Sm2W3O14 compound crystallizes in the orthorhombic system, and melts congruently at 1443 K. The magnetic measurements showed that Co2Sm2W3O14 is a paramagnet in the temperature range 4.2-225 K showing both the residual magnetic interactions since the paramagnetic Curie-Weiss temperature   0 and the uncompensated temperature independent contributions of magnetic susceptibility since 0  0. The Brillouin fit of the Landé factor revealed an increase of the orbital contribution to the total magnetic moment of the compound what seems to be responsible for its hard and spontaneous magnetization at low temperatures.

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Solid State Phenomena (Volume 170)

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1-4

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April 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] T. Nakano, Y. Kawakami, K. Uematsu, T. Ishigaki, K. Toda and M. Sato: J. Lumin. Vol. 129 (2009), p.1654.

Google Scholar

[2] F. -S. Wen, X. Zhao, H. Huo, J. -S. Chen, E. Shu-Lin and J. -H. Zhang: Mater. Lett. Vol. 55 (2002), p.152.

Google Scholar

[3] Q. Dai, H. Song, X. Bai, G. Pan, S. Lu, T. Wang, X. Ren and H. Zhao: J. Phys. Chem. C Vol. 111 (2007), p.7586.

Google Scholar

[4] M. Thomas, P. Prabhakar Rao, M. Deepa, M.R. Chandran and P. Koshy: J. Solid State Chem. Vol. 182 (2009), p.203.

Google Scholar

[5] L. -Y. Zhou, J.S. Wei, F.Z. Gong, J. -L. Huang and L. -H. Yi: J. Solid State Chem. Vol. 181 (2008), p.1337.

Google Scholar

[6] A. Earnshaw: Introduction to Magnetochemistry (Academic Press, London, 1968).

Google Scholar

[7] A.H. Morrish: Physical Principles of Magnetism (John Wiley & Sons, Inc., New York, 1965).

Google Scholar

[8] C. Kittel: Introduction to Solid State Physics (John Wiley & Sons, Inc., New York, 1960).

Google Scholar

[9] P. Urbanowicz, E. Tomaszewicz, T. Groń, H. Duda, A.W. Pacyna and T. Mydlarz: Physica B Vol. 404 (2009), p.2213.

DOI: 10.1016/j.physb.2009.04.016

Google Scholar

[10] E. Tomaszewicz: Thermochim. Acta Vol. 447 (2006), p.69.

Google Scholar

[11] T. Groń, E. Malicka and A.W. Pacyna: Physica B Vol. 404 (2009), p.3554.

Google Scholar

[12] L.I. Schiff: Quantum Mechanics (McGraw-Hill Book Company, Inc., New York, 1955).

Google Scholar

[13] S.A. Majetich, J.O. Artman, M.E. McHenry, N.T. Nuhfer and S.W. Stanley: Phys. Rev. B Vol. 48 (1993), p.16845.

Google Scholar